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Laboratory Experiments for Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134566207
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus, John H. Nelson, Kenneth C. Kemp
Publisher: PEARSON
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Question
Chapter 16.3, Problem 16.5.1PE
Interpretation Introduction
Interpretation:
The value of
Concept introduction:
The equilibrium constant for the auto-ionization of water is,
The above expression is used to calculate the concentration of
Given:
The concentration of
Expert Solution & Answer
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Students have asked these similar questions
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 16 Solutions
Laboratory Experiments for Chemistry: The Central Science (14th Edition)
Ch. 16.2 - Practice Exercise 1 Consider the following...Ch. 16.2 - Prob. 16.1.2PECh. 16.2 - Prob. 16.2.1PECh. 16.2 - Practice Exercise 2 When lithium oxide (Li2O) is...Ch. 16.2 - Based on information in Figure 16.4, place the...Ch. 16.2 - Practice Exercise 2 For each reaction, use Figure...Ch. 16.3 - Practice Exercise 1 In a certain acidic solution...Ch. 16.3 - Practice Exercise 2 Indicate whether solutions...Ch. 16.3 - Prob. 16.5.1PECh. 16.3 - Prob. 16.5.2PE
Ch. 16.4 - Practice Exercise 1 A solution at 250C has [OH-] =...Ch. 16.4 - Practice Exercise 2 In a sample of lemon juice,...Ch. 16.4 - Practice Exercise 1 A solution at 25° C has pOH =...Ch. 16.4 - Prob. 16.7.2PECh. 16.5 - Practice Exercise 1 Order the following three...Ch. 16.5 - Prob. 16.8.2PECh. 16.5 - Practice Exercise 1 Order the following three...Ch. 16.5 - Prob. 16.9.2PECh. 16.6 - Prob. 16.10.1PECh. 16.6 - Practice Exercise 2 Niacin, one of the B vitamins,...Ch. 16.6 - Prob. 16.11.1PECh. 16.6 - Practice Exercise 2 A 0.020 M solution of niacin...Ch. 16.6 - Practice Exercise 1 What is the pH of a 0.40 M...Ch. 16.6 - Practice Exercise 2 The Ka for niacin (Sample...Ch. 16.6 - Prob. 16.13.1PECh. 16.6 - Prob. 16.13.2PECh. 16.6 - Practice Exercise 1 What is the pH of a 0.28 M...Ch. 16.6 - Practice Exercise 2 Calculate the pH of a 0.020 M...Ch. 16.7 - Prob. 16.15.1PECh. 16.7 - Practice Exercise 2 Which of the following...Ch. 16.7 - Prob. 16.16.1PECh. 16.7 - Practice Exercise 2 What is the morality of an...Ch. 16.8 - Practice Exercise 1 By using information from...Ch. 16.8 - Practice Exercise 2 Based on information in...Ch. 16.9 - Prob. 16.18.1PECh. 16.9 - Prob. 16.18.2PECh. 16.9 - Practice Exercise 1 How many of the following...Ch. 16.9 - Practice Exercise 2 Predict whether the...Ch. 16.10 - Prob. 16.20.1PECh. 16.10 - In each pair, choose the compound that gives the...Ch. 16 - Prob. 1DECh. 16 - a. Identify the Br ted-Lowry acid and base in the...Ch. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - 16.5 The following diagrams represent aqueous...Ch. 16 - Prob. 6ECh. 16 - Which of these statements about how the percent...Ch. 16 - 16.8 Each of the three molecules shown here...Ch. 16 - Prob. 9ECh. 16 - Which of the following diagrams best represent an...Ch. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - 16.14 Which of the following statements is...Ch. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Identify the Bronsted-Lowry acid and the...Ch. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - 16.29 Calcualte [H +] for each of the following...Ch. 16 - Prob. 30ECh. 16 - 16.31 At the freezing point of water (0 o C), K10...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - 16.35 Complete the following table by calculating...Ch. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - 16.38 Carbon dioxide in the atmosphere dissolves...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - write the chemical equation and the Ka expression...Ch. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Calculate the pH of each of the following solution...Ch. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Calculate the percent ionization of hydrazoic acid...Ch. 16 - 16.64 Calculate the percent ionization of...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - 16.68 The hypochlorite ion, CIO- , acts as a weak...Ch. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Calculate the molar concentration of OH- in a...Ch. 16 - 16.72 Calculate the molar concentration of OH- in...Ch. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - a. Given that Ka for acetic acid is 1.8 10-5 and...Ch. 16 - 16.78
a. Given that Kb for ammonia is 1.8 X 10 -5...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Pyridinium bromide (C5H5NHBr) is a strong...Ch. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - 16.86 An unknown salt is either KBr, NH4 C1, KCN,...Ch. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - 16.89 Based on their compositions and structures...Ch. 16 - Prob. 90ECh. 16 - 16.91 Indicate whether each of the following...Ch. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - Prob. 97ECh. 16 - Prob. 98ECh. 16 - Prob. 99AECh. 16 - Prob. 100AECh. 16 - Prob. 101AECh. 16 - Prob. 102AECh. 16 - Prob. 103AECh. 16 - Prob. 104AECh. 16 - Benzoic acid (C6H5COOH) and aniline (C6H5NH2) are...Ch. 16 - Prob. 106AECh. 16 - Prob. 107AECh. 16 - Prob. 108AECh. 16 - Butyric acid is responsible for the foul smell of...Ch. 16 - Prob. 110AECh. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - 1S.113 Many moderately large organic molecules...Ch. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116IECh. 16 - Prob. 117IECh. 16 - Prob. 118IECh. 16 - Prob. 119IECh. 16 - 16.120 At 50 oC, the ion-product constant for H2...Ch. 16 - Prob. 121IECh. 16 - Prob. 122IECh. 16 - Prob. 123IECh. 16 - Prob. 124IECh. 16 - Prob. 125IECh. 16 - Prob. 126IE
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Similar questions
- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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