Chapter 16.3, Problem 16.2BFP

(a)

Interpretation Introduction

Interpretation:

The reaction order on each reactant and the overall reaction order have to be predicted.

Concept introduction:

Rate law or rate equation: The relationship between the reactant concentrations and reaction rate is expressed by an equation.

$\begin{array}{l}\text{aA + bB}\to x\text{X}\\ {\text{Rate of reaction = k [A]}}^{\text{m}}{\text{[B]}}^{\text{n}}\\ \text{Total}\text{order}\text{of reaction = }\left(\text{m + n}\right)\end{array}$

Order of a reaction: The order of a reaction with respect to a particular reactant is the exponent of its concentration term in the rate law expression, and the overall reaction order is the sum of the exponents on all concentration terms.

Rate constant, k: It is a proportionality constant that relates rate and concentration at a given temperature.

(b)

Interpretation Introduction

Interpretation:

If $\left[{\text{ClO}}_2\right]$ is halved and $\left[{\text{OH}}^{-}\right]$ is doubled, then the factor that causes the rate change has to be predicted.

Concept introduction:

Rate law or rate equation: The relationship between the reactant concentrations and reaction rate is expressed by an equation.

$\begin{array}{l}\text{aA + bB}\to x\text{X}\\ \\ {\text{Rate of reaction = k [A]}}^{\text{m}}{\text{[B]}}^{\text{n}}\\ \\ \text{Total}\text{order}\text{of reaction = }\left(\text{m + n}\right)\end{array}$

Order of a reaction: The order of a reaction with respect to a particular reactant is the exponent of its concentration term in the rate law expression, and the overall reaction order is the sum of the exponents on all concentration terms.

Rate constant, k: It is a proportionality constant that relates rate and concentration at a given temperature.