Chapter 16.16, Problem 36P

5) Using the carbon-containing starting material(s), propose a synthesis based on the following retrosynthetic analysis. Provide structures for all intermediates. The carbon atoms in the product must originate from the starting material(s), but you may use as many equivalents of each starting material as you would like, and any reagent/reaction you know (note: no mechanisms are required). H H =

Calculate the percent ionization for 0.0025 M phenol. Use the assumption to find [H3O+] first. K = 1.0 x 10-10

10:04 AM Tue Mar 25 Sunday 9:30 AM 95% Edit Draw the corresponding structures in each of the boxes below: Ester Name Methyl butyrate (Example) Alcohol Structure H3C-OH Acid Structure Ester Structure Isoamyl acetate Ethyl butyrate Propyl acetate Methyl salicylate Octyl acetate Isobutyl propionate Benzyl butyrate Benzyl acetate Ethyl acetate H₂C OH HC

2) For each of the following reactions: (i) (ii) Fill in the missing reactant, reagent, or product (s), indicating stereochemistry where appropriate using dashed and wedged bonds. If the reaction forms a racemic mixture, draw both structures in the box and write the word "racemic". (a) (b) 1) R₂BH 2) H₂O2, NaOH (aq) HBr Br racemic Br + Br Br racemic

For each of the following reactions:  Fill in the missing reactant, reagent, or product (s), indicating stereochemistry where appropriate using dashed and wedged bonds. If the reaction forms a racemic mixture, draw both structures in the box and write the word “racemic”.

1) Draw the correct chemical structure (using line-angle drawings / "line structures") from their given IUPAC name: a. hept-3-yne b. 5-bromo-1-fluoro-4-methylpent-2-yne

15. How many absorptions are expected in the H-NMR spectra of fee songs? Explain your were a) CH,CH,CCH,CH, O CHUCH CHCH

Firefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.

What is the [OH⁻] of a 1.80 M solution of pyridine (C₅H₅N, Kb = 1.70 × 10⁻⁹)?