ORGANIC CHEMISTRY-ACCESS
6th Edition
ISBN: 9781260475586
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 16.13, Problem 28P
Draw a stepwise mechanism for the following reaction that forms ether D. D can be converted to the antidepressant fluoxetine (trade name Prozac) in a single step.
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2CIO2 + 20H-1 CIO31 + CIO2 + H2O
Experiment
[CIO2], M
[OH-1], M
1
0.0500
0.100
23
2
0.100
0.100
3
0.100
0.0500
Initial Rate, M/s
0.0575
0.230
0.115
...
Given this date, calculate the overall order of this reaction.
2
3
.(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I
Experiment
[1-] M
0.005
[OCI-]
0.005
Initial Rate M/min
0.000275
0.0025
0.005
0.000138
0.0025
0.0025
0.000069
4
0.0025
0.0025
0.000140
Calculate the rate constant of this reaction using the table data.
1
2
3
4
I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq)
Experiment
[I-] M
0.005
[OCI-]
0.005
Initial Rate M/min
0.000275
0.0025
0.005
0.000138
0.0025
0.0025
Calculate the overall order of this reaction using the table data.
0.0025
0.000069
0.0025
0.000140
Chapter 16 Solutions
ORGANIC CHEMISTRY-ACCESS
Ch. 16.1 - Prob. 1PCh. 16.2 - Prob. 2PCh. 16.3 - Prob. 3PCh. 16.4 - Prob. 4PCh. 16.5 - Prob. 5PCh. 16.5 - Prob. 6PCh. 16.5 - Prob. 9PCh. 16.5 - Problem 18.9 Draw the product of each reaction
a....Ch. 16.5 - Prob. 11PCh. 16.5 - Prob. 12P
Ch. 16.5 - Prob. 13PCh. 16.6 - Prob. 14PCh. 16.6 - Problem 18.14 Draw all resonance structures for...Ch. 16.6 - Problem 18.15 Classify each substituent as...Ch. 16.7 - Prob. 17PCh. 16.9 - Prob. 22PCh. 16.10 - Problem 18.20 Draw the products of each...Ch. 16.10 - Prob. 24PCh. 16.11 - Problem 18.22 Draw the products formed when each...Ch. 16.12 - Problem 18.23 Devise a synthesis of each compound...Ch. 16.13 - Problem 18.24 Draw the products of each...Ch. 16.13 - Problem 18.25 Draw a stepwise mechanism for the...Ch. 16.13 - Problem 18.26 Draw the products of each...Ch. 16.13 - Prob. 30PCh. 16 - Prob. 37PCh. 16 - 18.35 What is the major product formed by an...Ch. 16 - 18.36 Draw the products formed when phenol is...Ch. 16 - Problem 18.37 Draw the products formed when each...Ch. 16 - 18.38 Draw the products of each reaction.
a. d....Ch. 16 - 18.39 What products are formed when benzene is...Ch. 16 - Prob. 49PCh. 16 - 18.47 For each of the following substituted...Ch. 16 - 18.48 Consider the tetracyclic aromatic compound...Ch. 16 - 18.49 For each N-substituted benzene, predict...Ch. 16 - Prob. 54PCh. 16 - 18.51 Using resonance structures, explain why a...Ch. 16 - Prob. 56PCh. 16 - 18.53 Rank the aryl halides in each group in order...Ch. 16 - Prob. 64PCh. 16 - Prob. 65PCh. 16 - Prob. 66PCh. 16 - 18.63 Synthesize each compound from benzene and...Ch. 16 - Problem 18.64 Synthesize each compound from...
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- H2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)· ••• Experiment [H2 O2]o (M) [I]o (M) [H+]。 (M) Initial rate (M/s) 1 0.15 0.15 0.05 0.00012 234 0.15 0.3 0.05 0.00024 0.3 0.15 0.05 0.00024 0.15 0.15 0.1 0.00048 Calculate the overall order of this reaction using the table data.arrow_forwardThe U. S. Environmental Protection Agency (EPA) sets limits on healthful levels of air pollutants. The maximum level that the EPA considers safe for lead air pollution is 1.5 μg/m³ Part A If your lungs were filled with air containing this level of lead, how many lead atoms would be in your lungs? (Assume a total lung volume of 5.40 L.) ΜΕ ΑΣΦ = 2.35 1013 ? atoms ! Check your rounding. Your final answer should be rounded to 2 significant figures in the last step. No credit lost. Try again.arrow_forwardY= - 0.039 (14.01) + 0.7949arrow_forward
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