(a) Interpretation: The given compounds are to be arranged in order of increasing reactivity in electrophilic aromatic substitution. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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Answer 1

Question

Chapter 16, Problem 49P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing reactivity in electrophilic aromatic substitution.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Interpretation Introduction

(b)

Interpretation: An explanation corresponding to the statement that given reaction will not lead to the formation of product is to be stated and the synthesis of A from Benzene and B from phenol is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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5. Use the MS data to answer the questions on the next page. 14.0 1.4 15.0 8.1 100- MS-IW-5644 26.0 2.8 27.0 6.7 28.0 1.8 29.0 80 4.4 38.0 1.0 39.0 1.5 41.0 1.2 42.0 11.2 43.0 100.0 44.0 4.3 79.0 1.9 80.0 2.6 Relative Intensity 40 81.0 1.9 82.0 2.5 93.0 8.7 20- 95.0 8.2 121.0 2.0 123.0 2.0 136.0 11.8 0 138.0 11.5 20 40 8. 60 a. Br - 0 80 100 120 140 160 180 200 220 m/z Identify the m/z of the base peak and molecular ion. 2 b. Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0, 95.0, 136.0, and 138.0 m/z. C. Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to fragment 43.0 m/z. Be sure to include all electrons and formal charges. 6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium ion (CsH6N) and show your work.

None

Stereochemistry: Three possible answers- diastereomers, enantiomers OH CH₂OH I -c=0 21108 1101 41745 HOR CH₂OH IL Но CH₂OH TIL a. Compounds I and III have this relationship with each other: enantiomers b. Compounds II and IV have this relationship with each other: c. Compounds I and II have this relationship with each other: d. *Draw one structure that is a stereoisomer of II, but neither a diastereomer nor an enantiomer. (more than one correct answer)

Answer 2

Question

Chapter 16, Problem 49P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing reactivity in electrophilic aromatic substitution.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Interpretation Introduction

(b)

Interpretation: An explanation corresponding to the statement that given reaction will not lead to the formation of product is to be stated and the synthesis of A from Benzene and B from phenol is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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Answer 3

Question

Chapter 16, Problem 49P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing reactivity in electrophilic aromatic substitution.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Interpretation Introduction

(b)

Interpretation: An explanation corresponding to the statement that given reaction will not lead to the formation of product is to be stated and the synthesis of A from Benzene and B from phenol is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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Answer 4

Question

Chapter 16, Problem 49P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing reactivity in electrophilic aromatic substitution.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Interpretation Introduction

(b)

Interpretation: An explanation corresponding to the statement that given reaction will not lead to the formation of product is to be stated and the synthesis of A from Benzene and B from phenol is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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Answer 5

Chapter 16, Problem 49P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing reactivity in electrophilic aromatic substitution.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Interpretation Introduction

(b)

Interpretation: An explanation corresponding to the statement that given reaction will not lead to the formation of product is to be stated and the synthesis of A from Benzene and B from phenol is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 6

Chapter 16, Problem 49P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing reactivity in electrophilic aromatic substitution.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 7

Chapter 16, Problem 49P

Interpretation Introduction

(a)

Interpretation: The given compounds are to be arranged in order of increasing reactivity in electrophilic aromatic substitution.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 8

Interpretation Introduction

(b)

Interpretation: An explanation corresponding to the statement that given reaction will not lead to the formation of product is to be stated and the synthesis of A from Benzene and B from phenol is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 9

Interpretation Introduction

(b)

Interpretation: An explanation corresponding to the statement that given reaction will not lead to the formation of product is to be stated and the synthesis of A from Benzene and B from phenol is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16.1 - Prob. 1P Ch. 16.2 - Prob. 2P Ch. 16.3 - Prob. 3P Ch. 16.4 - Prob. 4P Ch. 16.5 - Prob. 5P Ch. 16.5 - Prob. 6P Ch. 16.5 - Prob. 9P Ch. 16.5 - Problem 18.9 Draw the product of each reaction a....Ch. 16.5 - Prob. 11P Ch. 16.5 - Prob. 12P

Solution Summary: The author explains the order of increasing reactivity in electrophilic aromatic substitution.

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