For the given Diels-Alder reaction, the formed product in the two given regiochemical outcomes should be identified. Concept introduction: Cycloaddition reaction is a concerted addition reaction of two reactants to form a ring; in which two π-bonds are converted to two σ-bonds . Diels-Alder reaction is a [ 4+2 ] cycloaddition reaction, in which a π-system having four atoms (diene) and a π-system having two atoms (dienophile) are undergoing in cycloaddition reaction and producing a substituted cyclohexene . The mechanism of the ring formation in the Diels-Alder reaction is drawn by using three arrows representing the shifting of π-bonds in the two π-systems in a clockwise or counter clockwise fashion, so that the ring formation will take place. The electron-withdrawing substituent such as carbonyl groups activates the dienophile for Diels-Alder reaction by making the dienophiles more electron poor so that more susceptible to diene’s attack. The electron-donating substituent such as methoxy-groups activates the diene for Diels-Alder reaction by making the diene more electron rich to attack dienophile. To identify: the product formed from the two given regiochemical outcomes of given reaction.

Question

Want to see the full answer?

Answer 1

Question

Chapter 16, Problem 74IP

Interpretation Introduction

Interpretation:

For the given Diels-Alder reaction, the formed product in the two given regiochemical outcomes should be identified.

Concept introduction:

Cycloaddition reaction is a concerted addition reaction of two reactants to form a ring; in which two π-bonds are converted to two σ-bonds.

Diels-Alder reaction is a [4+2] cycloaddition reaction, in which a π-system having four atoms (diene) and a π-system having two atoms (dienophile) are undergoing in cycloaddition reaction and producing a substituted cyclohexene.

The mechanism of the ring formation in the Diels-Alder reaction is drawn by using three arrows representing the shifting of π-bonds in the two π-systems in a clockwise or counter clockwise fashion, so that the ring formation will take place.

The electron-withdrawing substituent such as carbonyl groups activates the dienophile for Diels-Alder reaction by making the dienophiles more electron poor so that more susceptible to diene’s attack.

The electron-donating substituent such as methoxy-groups activates the diene for Diels-Alder reaction by making the diene more electron rich to attack dienophile.

To identify: the product formed from the two given regiochemical outcomes of given reaction.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

1. Which one(s) of these can be oxidized with CrO3 ? (could be more than one) a) triphenylmethanol b) 2-pentanol c) Ethyl alcohol d) CH3 2. Write in all the product(s) of this reaction. Label them as "major" or "minor". 2-methyl-2-hexanol H2SO4, heat

3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)

In the decomposition reaction in solution B → C, only species C absorbs UV radiation, but neither B nor the solvent absorbs. If we call At the absorbance measured at any time, A0 the absorbance at the beginning of the reaction, and A∞ the absorbance at the end of the reaction, which of the expressions is valid? We assume that Beer's law is fulfilled.