
Introductory Chemistry (5th Edition) (Standalone Book)
5th Edition
ISBN: 9780321910295
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 16, Problem 71E
Interpretation Introduction
Interpretation: The metal that has the least tendency to oxidize is to be identified.
Concept introduction:
Metals present at the top of the activity series have a greater tendency to lose electrons while metals present at the bottom of the series have a lower tendency to lose electrons.
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Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
Chapter 16 Solutions
Introductory Chemistry (5th Edition) (Standalone Book)
Ch. 16 - Q1. Which substance is being oxidized in the...Ch. 16 - What always happens to an oxidizing agent during a...Ch. 16 - Q3. What is the oxidation state of carbon in...Ch. 16 - Q4. In which compound does phosphorus have the...Ch. 16 - Sodium reacts with water according to the...Ch. 16 - Q6. How many electrons are exchanged when this...Ch. 16 - Prob. 7SAQCh. 16 - Prob. 8SAQCh. 16 - Prob. 9SAQCh. 16 - Prob. 10SAQ
Ch. 16 - 1. What is a fuel-cell electric vehicle?
Ch. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - 20. Any half-reaction in the activity series will...Ch. 16 - 21. Metals ______ than H2 in the reactivity series...Ch. 16 - What is electrical current? Explain how a simple...Ch. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - 38. For each of the reactions in Problem 36,...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - 47. Assign an oxidation state to each atom in each...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - 59. Use oxidation states to identify the oxidizing...Ch. 16 - Prob. 60ECh. 16 - 61. Balance each redox reaction using the...Ch. 16 - BALANCING REDOX REACTIONS
62. Balance each redox...Ch. 16 - Classify each half-reaction occurring in acidic...Ch. 16 - 64. Classify each half-reaction occurring in...Ch. 16 - BALANCING REDOX REACTIONS Use the half-reaction...Ch. 16 - Use the half-reaction method to balance each redox...Ch. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Balance each redox reaction occurring in basic...Ch. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - 77. Determine whether each redox occurs...Ch. 16 - Prob. 78ECh. 16 - 79. Suppose you wanted to cause ions to come out...Ch. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - 82. Which metal in the activity series is oxidized...Ch. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - The following reaction occurs at the cathode of an...Ch. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Make a sketch of an electrolysis cell that could...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - 95. Determine whether each reaction is a redox...Ch. 16 - Prob. 96ECh. 16 - Consider the unbalanced redox reaction....Ch. 16 - Prob. 98ECh. 16 - Prob. 99ECh. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - 102. A 1.012-mL sample of a salt containing is...Ch. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - Determine whether HI can dissolve each metal...Ch. 16 - 106. Determine whether HI can dissolve each metal...Ch. 16 - Prob. 107ECh. 16 - 108. One graduated cylinder containing 1.00 mL of...Ch. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - 113. Consider the molecular view of an...Ch. 16 - Which of your group’s cells do you think would...
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