EP BASIC CHEMISTRY-MODIFIED MASTERING
EP BASIC CHEMISTRY-MODIFIED MASTERING
6th Edition
ISBN: 9780137452392
Author: Timberlake
Publisher: SAVVAS L
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Chapter 16, Problem 60APP
Interpretation Introduction

Interpretation:

The type of radioactive decay needs to be identified.

Concept introduction:

  • Alpha decay happens when a nucleus emits an alpha particle α24 .
  • Beta decay happens when a nucleus emits a beta particle identical to the electron e-10 .
  • Positron emission happens when a nucleus emits a positron e10 .
  • Gamma decay is a loss of energy by the nucleus it is denotes as γ00 .

Given:

  55127Cs 54127Xe + +10e

  3890Sr3990Y + -10e

  85218At 83214Bi + 24He

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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol). a) Write a balanced net reaction that can occur between species in this solution. b) Calculate deltaG0 and K for the reaction. c) Calculate E and deltaG for the conditions given. Ce4+ + e- = Ce3+  E0= 1.70 V MnO4- + 8H+ + 5e- = Mn2+ + 4H2O   E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in the following reaction. Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is a weak base used to neutralize strong acid (pKa < 0) produced by the reaction. Redraw the product to show the configuration(s) that form at C-2 and C-4. Br2 OH CH2Cl2 Na* HCO3 Br HO OH + Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); H₂O2/HO (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI + enant OH Solvent Reagent(s) Solvent Reagent(s)

Chapter 16 Solutions

EP BASIC CHEMISTRY-MODIFIED MASTERING

Ch. 16.1 - Prob. 11PPCh. 16.1 - Prob. 12PPCh. 16.2 - Prob. 13PPCh. 16.2 - Prob. 14PPCh. 16.2 - Prob. 15PPCh. 16.2 - Prob. 16PPCh. 16.2 - Prob. 17PPCh. 16.2 - Prob. 18PPCh. 16.2 - Prob. 19PPCh. 16.2 - Prob. 20PPCh. 16.2 - Prob. 21PPCh. 16.2 - Prob. 22PPCh. 16.3 - Prob. 23PPCh. 16.3 - Prob. 24PPCh. 16.3 - Prob. 25PPCh. 16.3 - Prob. 26PPCh. 16.3 - Prob. 27PPCh. 16.3 - Prob. 28PPCh. 16.4 - Prob. 29PPCh. 16.4 - Prob. 30PPCh. 16.4 - Prob. 31PPCh. 16.4 - Prob. 32PPCh. 16.4 - Prob. 33PPCh. 16.4 - Prob. 34PPCh. 16.5 - Prob. 35PPCh. 16.5 - Prob. 36PPCh. 16.5 - Prob. 37PPCh. 16.5 - Prob. 38PPCh. 16.5 - Prob. 39PPCh. 16.5 - Prob. 40PPCh. 16.6 - Prob. 41PPCh. 16.6 - Prob. 42PPCh. 16.6 - Prob. 43PPCh. 16.6 - Prob. 44PPCh. 16.6 - Prob. 45PPCh. 16.6 - Prob. 46PPCh. 16.6 - Prob. 47PPCh. 16.6 - Prob. 48PPCh. 16.6 - Prob. 49PPCh. 16.6 - Prob. 50PPCh. 16 - Prob. 51UTCCh. 16 - Prob. 52UTCCh. 16 - The chapter sections to review are shown in...Ch. 16 - Prob. 54UTCCh. 16 - Prob. 55UTCCh. 16 - Prob. 56UTCCh. 16 - Prob. 57APPCh. 16 - Prob. 58APPCh. 16 - Prob. 59APPCh. 16 - Prob. 60APPCh. 16 - Prob. 61APPCh. 16 - Prob. 62APPCh. 16 - Prob. 63APPCh. 16 - Prob. 64APPCh. 16 - Prob. 65APPCh. 16 - Prob. 66APPCh. 16 - Prob. 67APPCh. 16 - Prob. 68APPCh. 16 - Prob. 69APPCh. 16 - Prob. 70APPCh. 16 - Prob. 71APPCh. 16 - Prob. 72APPCh. 16 - Prob. 73APPCh. 16 - Prob. 74APPCh. 16 - Prob. 75APPCh. 16 - Prob. 76APPCh. 16 - Prob. 77APPCh. 16 - Prob. 78APPCh. 16 - Prob. 79CPCh. 16 - Prob. 80CPCh. 16 - Prob. 81CPCh. 16 - Prob. 82CPCh. 16 - Prob. 83CPCh. 16 - Prob. 84CPCh. 16 - Prob. 85CPCh. 16 - Prob. 86CPCh. 16 - Prob. 87CPCh. 16 - Prob. 88CPCh. 16 - Prob. 89CPCh. 16 - Prob. 90CPCh. 16 - Consider the reaction of sodium oxalate (Na2C2O4)...Ch. 16 - Prob. 34CICh. 16 - Prob. 35CICh. 16 - Prob. 36CICh. 16 - Prob. 37CICh. 16 - Prob. 38CICh. 16 - Prob. 39CICh. 16 - Prob. 40CI
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