EP BASIC CHEMISTRY-MODIFIED MASTERING
6th Edition
ISBN: 9780137452392
Author: Timberlake
Publisher: SAVVAS L
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Question
Chapter 16, Problem 52UTC
Interpretation Introduction
Interpretation:
The nucleus that results in the formation of new nucleus after emission of a beta particle needs to be determined.
Concept introduction:
- Beta decay happens when a nucleus emits a beta particle identical to the electron
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 16 Solutions
EP BASIC CHEMISTRY-MODIFIED MASTERING
Ch. 16.1 - Prob. 1PPCh. 16.1 - Prob. 2PPCh. 16.1 - Naturally occurring potassium consists of three...Ch. 16.1 - Prob. 4PPCh. 16.1 - Prob. 5PPCh. 16.1 - Prob. 6PPCh. 16.1 - Prob. 7PPCh. 16.1 - Prob. 8PPCh. 16.1 - Supply the missing information in the following...Ch. 16.1 - Prob. 10PP
Ch. 16.1 - Prob. 11PPCh. 16.1 - Prob. 12PPCh. 16.2 - Prob. 13PPCh. 16.2 - Prob. 14PPCh. 16.2 - Prob. 15PPCh. 16.2 - Prob. 16PPCh. 16.2 - Prob. 17PPCh. 16.2 - Prob. 18PPCh. 16.2 - Prob. 19PPCh. 16.2 - Prob. 20PPCh. 16.2 - Prob. 21PPCh. 16.2 - Prob. 22PPCh. 16.3 - Prob. 23PPCh. 16.3 - Prob. 24PPCh. 16.3 - Prob. 25PPCh. 16.3 - Prob. 26PPCh. 16.3 - Prob. 27PPCh. 16.3 - Prob. 28PPCh. 16.4 - Prob. 29PPCh. 16.4 - Prob. 30PPCh. 16.4 - Prob. 31PPCh. 16.4 - Prob. 32PPCh. 16.4 - Prob. 33PPCh. 16.4 - Prob. 34PPCh. 16.5 - Prob. 35PPCh. 16.5 - Prob. 36PPCh. 16.5 - Prob. 37PPCh. 16.5 - Prob. 38PPCh. 16.5 - Prob. 39PPCh. 16.5 - Prob. 40PPCh. 16.6 - Prob. 41PPCh. 16.6 - Prob. 42PPCh. 16.6 - Prob. 43PPCh. 16.6 - Prob. 44PPCh. 16.6 - Prob. 45PPCh. 16.6 - Prob. 46PPCh. 16.6 - Prob. 47PPCh. 16.6 - Prob. 48PPCh. 16.6 - Prob. 49PPCh. 16.6 - Prob. 50PPCh. 16 - Prob. 51UTCCh. 16 - Prob. 52UTCCh. 16 - The chapter sections to review are shown in...Ch. 16 - Prob. 54UTCCh. 16 - Prob. 55UTCCh. 16 - Prob. 56UTCCh. 16 - Prob. 57APPCh. 16 - Prob. 58APPCh. 16 - Prob. 59APPCh. 16 - Prob. 60APPCh. 16 - Prob. 61APPCh. 16 - Prob. 62APPCh. 16 - Prob. 63APPCh. 16 - Prob. 64APPCh. 16 - Prob. 65APPCh. 16 - Prob. 66APPCh. 16 - Prob. 67APPCh. 16 - Prob. 68APPCh. 16 - Prob. 69APPCh. 16 - Prob. 70APPCh. 16 - Prob. 71APPCh. 16 - Prob. 72APPCh. 16 - Prob. 73APPCh. 16 - Prob. 74APPCh. 16 - Prob. 75APPCh. 16 - Prob. 76APPCh. 16 - Prob. 77APPCh. 16 - Prob. 78APPCh. 16 - Prob. 79CPCh. 16 - Prob. 80CPCh. 16 - Prob. 81CPCh. 16 - Prob. 82CPCh. 16 - Prob. 83CPCh. 16 - Prob. 84CPCh. 16 - Prob. 85CPCh. 16 - Prob. 86CPCh. 16 - Prob. 87CPCh. 16 - Prob. 88CPCh. 16 - Prob. 89CPCh. 16 - Prob. 90CPCh. 16 - Consider the reaction of sodium oxalate (Na2C2O4)...Ch. 16 - Prob. 34CICh. 16 - Prob. 35CICh. 16 - Prob. 36CICh. 16 - Prob. 37CICh. 16 - Prob. 38CICh. 16 - Prob. 39CICh. 16 - Prob. 40CI
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