CHEMISTRY THE CENTRAL SCIENCE 14TH EDI
14th Edition
ISBN: 9780134863016
Author: Brown
Publisher: PEARSON
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Textbook Question
Chapter 16, Problem 59E
Calculate the pH of each of the following solution (Ka and Kb values are given in Appendix D):
a. 0.095 M propionic acid (C2H5COOH),
b. 0.100 M hydrogen chromate ion (HCRiO-4),
c. 0.120 M pyridine (C5H5N).
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Students have asked these similar questions
None
3. Consider the compounds below and determine if they are aromatic, antiaromatic, or
non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I
electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly
drawn and you should be able to tell that the bonding electrons and lone pair electrons
should reside in which hybridized atomic orbital 2. You should consider ring strain-
flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti-
aromaticity)
H H
N
N:
NH2
N
Aromaticity
(Circle)
Aromatic Aromatic Aromatic Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic TT
electrons
Me
H
Me
Aromaticity
(Circle)
Aromatic Aromatic Aromatic
Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic πT
electrons
H
HH…
A chemistry graduate student is studying the rate of this reaction:
2 HI (g) →H2(g) +12(g)
She fills a reaction vessel with HI and measures its concentration as the reaction proceeds:
time
(minutes)
[IH]
0
0.800M
1.0
0.301 M
2.0
0.185 M
3.0
0.134M
4.0
0.105 M
Use this data to answer the following questions.
Write the rate law for this reaction.
rate
= 0
Calculate the value of the rate constant k.
k =
Round your answer to 2 significant digits. Also be
sure your answer has the correct unit symbol.
Chapter 16 Solutions
CHEMISTRY THE CENTRAL SCIENCE 14TH EDI
Ch. 16.2 - Practice Exercise 1 Consider the following...Ch. 16.2 - Prob. 16.1.2PECh. 16.2 - Prob. 16.2.1PECh. 16.2 - Practice Exercise 2 When lithium oxide (Li2O) is...Ch. 16.2 - Based on information in Figure 16.4, place the...Ch. 16.2 - Practice Exercise 2 For each reaction, use Figure...Ch. 16.3 - Practice Exercise 1 In a certain acidic solution...Ch. 16.3 - Practice Exercise 2 Indicate whether solutions...Ch. 16.3 - Prob. 16.5.1PECh. 16.3 - Prob. 16.5.2PE
Ch. 16.4 - Practice Exercise 1 A solution at 250C has [OH-] =...Ch. 16.4 - Practice Exercise 2 In a sample of lemon juice,...Ch. 16.4 - Practice Exercise 1 A solution at 25° C has pOH =...Ch. 16.4 - Prob. 16.7.2PECh. 16.5 - Practice Exercise 1 Order the following three...Ch. 16.5 - Prob. 16.8.2PECh. 16.5 - Practice Exercise 1 Order the following three...Ch. 16.5 - Prob. 16.9.2PECh. 16.6 - Prob. 16.10.1PECh. 16.6 - Practice Exercise 2 Niacin, one of the B vitamins,...Ch. 16.6 - Prob. 16.11.1PECh. 16.6 - Practice Exercise 2 A 0.020 M solution of niacin...Ch. 16.6 - Practice Exercise 1 What is the pH of a 0.40 M...Ch. 16.6 - Practice Exercise 2 The Ka for niacin (Sample...Ch. 16.6 - Prob. 16.13.1PECh. 16.6 - Prob. 16.13.2PECh. 16.6 - Practice Exercise 1 What is the pH of a 0.28 M...Ch. 16.6 - Practice Exercise 2 Calculate the pH of a 0.020 M...Ch. 16.7 - Prob. 16.15.1PECh. 16.7 - Practice Exercise 2 Which of the following...Ch. 16.7 - Prob. 16.16.1PECh. 16.7 - Practice Exercise 2 What is the morality of an...Ch. 16.8 - Practice Exercise 1 By using information from...Ch. 16.8 - Practice Exercise 2 Based on information in...Ch. 16.9 - Prob. 16.18.1PECh. 16.9 - Prob. 16.18.2PECh. 16.9 - Practice Exercise 1 How many of the following...Ch. 16.9 - Practice Exercise 2 Predict whether the...Ch. 16.10 - Prob. 16.20.1PECh. 16.10 - In each pair, choose the compound that gives the...Ch. 16 - Prob. 1DECh. 16 - a. Identify the Br ted-Lowry acid and base in the...Ch. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - 16.5 The following diagrams represent aqueous...Ch. 16 - Prob. 6ECh. 16 - Which of these statements about how the percent...Ch. 16 - 16.8 Each of the three molecules shown here...Ch. 16 - Prob. 9ECh. 16 - Which of the following diagrams best represent an...Ch. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - 16.14 Which of the following statements is...Ch. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Identify the Bronsted-Lowry acid and the...Ch. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - 16.29 Calcualte [H +] for each of the following...Ch. 16 - Prob. 30ECh. 16 - 16.31 At the freezing point of water (0 o C), K10...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - 16.35 Complete the following table by calculating...Ch. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - 16.38 Carbon dioxide in the atmosphere dissolves...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - write the chemical equation and the Ka expression...Ch. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Calculate the pH of each of the following solution...Ch. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Calculate the percent ionization of hydrazoic acid...Ch. 16 - 16.64 Calculate the percent ionization of...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - 16.68 The hypochlorite ion, CIO- , acts as a weak...Ch. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Calculate the molar concentration of OH- in a...Ch. 16 - 16.72 Calculate the molar concentration of OH- in...Ch. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - a. Given that Ka for acetic acid is 1.8 10-5 and...Ch. 16 - 16.78
a. Given that Kb for ammonia is 1.8 X 10 -5...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Pyridinium bromide (C5H5NHBr) is a strong...Ch. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - 16.86 An unknown salt is either KBr, NH4 C1, KCN,...Ch. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - 16.89 Based on their compositions and structures...Ch. 16 - Prob. 90ECh. 16 - 16.91 Indicate whether each of the following...Ch. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - Prob. 97ECh. 16 - Prob. 98ECh. 16 - Prob. 99AECh. 16 - Prob. 100AECh. 16 - Prob. 101AECh. 16 - Prob. 102AECh. 16 - Prob. 103AECh. 16 - Prob. 104AECh. 16 - Benzoic acid (C6H5COOH) and aniline (C6H5NH2) are...Ch. 16 - Prob. 106AECh. 16 - Prob. 107AECh. 16 - Prob. 108AECh. 16 - Butyric acid is responsible for the foul smell of...Ch. 16 - Prob. 110AECh. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - 1S.113 Many moderately large organic molecules...Ch. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116IECh. 16 - Prob. 117IECh. 16 - Prob. 118IECh. 16 - Prob. 119IECh. 16 - 16.120 At 50 oC, the ion-product constant for H2...Ch. 16 - Prob. 121IECh. 16 - Prob. 122IECh. 16 - Prob. 123IECh. 16 - Prob. 124IECh. 16 - Prob. 125IECh. 16 - Prob. 126IE
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