FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
15th Edition
ISBN: 9781119797807
Author: Hein
Publisher: WILEY
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Chapter 16, Problem 23RQ
Interpretation Introduction
Interpretation:
Reason for formation of precipitate of
Concept Introduction:
Addition of similar type of ion in partially soluble salt is termed as common ion effect. The common ion present in it decides the shift of equilibrium according to Le Chatelier’s principle. According to this principle with increase in concentration of reactants reaction moves towards forward direction thus this increases concentration of products. Whereas with increase in concentration of product reaction shifts towards reverse direction. This increases the concentration of reactants.
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Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
Chapter 16 Solutions
FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
Ch. 16.1 - Prob. 16.1PCh. 16.2 - Prob. 16.2PCh. 16.3 - Prob. 16.3PCh. 16.3 - Prob. 16.4PCh. 16.3 - Prob. 16.5PCh. 16.3 - Prob. 16.6PCh. 16.4 - Prob. 16.7PCh. 16.4 - Prob. 16.8PCh. 16.5 - Prob. 16.9PCh. 16.5 - Prob. 16.10P
Ch. 16.6 - Prob. 16.11PCh. 16.6 - Prob. 16.12PCh. 16.7 - Prob. 16.13PCh. 16.7 - Prob. 16.14PCh. 16.7 - Prob. 16.15PCh. 16.8 - Prob. 16.16PCh. 16 - Prob. 1RQCh. 16 - Prob. 2RQCh. 16 - Prob. 3RQCh. 16 - Prob. 4RQCh. 16 - Prob. 5RQCh. 16 - Prob. 6RQCh. 16 - Prob. 7RQCh. 16 - Prob. 8RQCh. 16 - Prob. 9RQCh. 16 - Prob. 10RQCh. 16 - Prob. 11RQCh. 16 - Prob. 12RQCh. 16 - Prob. 13RQCh. 16 - Prob. 14RQCh. 16 - Prob. 15RQCh. 16 - Prob. 16RQCh. 16 - Prob. 17RQCh. 16 - Prob. 18RQCh. 16 - Prob. 19RQCh. 16 - Prob. 20RQCh. 16 - Prob. 21RQCh. 16 - Prob. 22RQCh. 16 - Prob. 23RQCh. 16 - Prob. 24RQCh. 16 - Prob. 25RQCh. 16 - Prob. 26RQCh. 16 - Prob. 27RQCh. 16 - Prob. 1PECh. 16 - Prob. 2PECh. 16 - Prob. 3PECh. 16 - Prob. 4PECh. 16 - Prob. 5PECh. 16 - Prob. 6PECh. 16 - Prob. 7PECh. 16 - Prob. 8PECh. 16 - Prob. 9PECh. 16 - Prob. 10PECh. 16 - Prob. 11PECh. 16 - Prob. 12PECh. 16 - Prob. 13PECh. 16 - Prob. 14PECh. 16 - Prob. 15PECh. 16 - Prob. 16PECh. 16 - Prob. 17PECh. 16 - Prob. 18PECh. 16 - Prob. 19PECh. 16 - Prob. 20PECh. 16 - Prob. 21PECh. 16 - Prob. 22PECh. 16 - Prob. 23PECh. 16 - Prob. 24PECh. 16 - Prob. 25PECh. 16 - Prob. 26PECh. 16 - Prob. 27PECh. 16 - Prob. 28PECh. 16 - Prob. 29PECh. 16 - Prob. 30PECh. 16 - Prob. 31PECh. 16 - Prob. 32PECh. 16 - Prob. 33PECh. 16 - Prob. 34PECh. 16 - Prob. 35PECh. 16 - Prob. 36PECh. 16 - Prob. 37PECh. 16 - Prob. 38PECh. 16 - Prob. 39PECh. 16 - Prob. 40PECh. 16 - Prob. 41PECh. 16 - Prob. 42PECh. 16 - Prob. 43PECh. 16 - Prob. 44PECh. 16 - Prob. 45PECh. 16 - Prob. 46PECh. 16 - Prob. 47PECh. 16 - Prob. 48PECh. 16 - Prob. 49AECh. 16 - Prob. 50AECh. 16 - Prob. 51AECh. 16 - Prob. 52AECh. 16 - Prob. 53AECh. 16 - Prob. 54AECh. 16 - Prob. 55AECh. 16 - Prob. 56AECh. 16 - Prob. 57AECh. 16 - Prob. 58AECh. 16 - Prob. 59AECh. 16 - Prob. 60AECh. 16 - Prob. 61AECh. 16 - Prob. 62AECh. 16 - Prob. 63AECh. 16 - Prob. 64AECh. 16 - Prob. 65AECh. 16 - Prob. 66AECh. 16 - Prob. 67AECh. 16 - Prob. 68AECh. 16 - Prob. 69AECh. 16 - Prob. 70AECh. 16 - Prob. 71AECh. 16 - Prob. 72AECh. 16 - Prob. 73AECh. 16 - Prob. 74AECh. 16 - Prob. 75AECh. 16 - Prob. 76AECh. 16 - Prob. 77AECh. 16 - Prob. 78AECh. 16 - Prob. 79AECh. 16 - Prob. 80AECh. 16 - Prob. 81AECh. 16 - Prob. 83AECh. 16 - Prob. 84AECh. 16 - Prob. 85AECh. 16 - Prob. 86CECh. 16 - Prob. 87CECh. 16 - Prob. 88CECh. 16 - Prob. 89CE
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