ATKINS' PHYSICAL CHEMISTRY-ACCESS
11th Edition
ISBN: 9780198834700
Author: ATKINS
Publisher: OXF
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Question
Chapter 16, Problem 16C.7BE
Interpretation Introduction
Interpretation:
The time required by a
Concept introduction:
Viscosity is called the property of a fluid that is “a measure of its resistance to flow”. It is the consequence of a molecular attraction and denotes the internal friction of a moving fluid. A fluid with high viscosity resists motion due to its high molecular interaction. The substances with low intermolecular interaction have lower viscosity.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 16 Solutions
ATKINS' PHYSICAL CHEMISTRY-ACCESS
Ch. 16 - Prob. 16A.1STCh. 16 - Prob. 16B.1STCh. 16 - Prob. 16C.1STCh. 16 - Prob. 16A.1DQCh. 16 - Prob. 16A.2DQCh. 16 - Prob. 16A.1AECh. 16 - Prob. 16A.1BECh. 16 - Prob. 16A.2AECh. 16 - Prob. 16A.2BECh. 16 - Prob. 16A.3AE
Ch. 16 - Prob. 16A.3BECh. 16 - Prob. 16A.4AECh. 16 - Prob. 16A.4BECh. 16 - Prob. 16A.5AECh. 16 - Prob. 16A.5BECh. 16 - Prob. 16A.6AECh. 16 - Prob. 16A.6BECh. 16 - Prob. 16A.7AECh. 16 - Prob. 16A.7BECh. 16 - Prob. 16A.8AECh. 16 - Prob. 16A.8BECh. 16 - Prob. 16A.9AECh. 16 - Prob. 16A.9BECh. 16 - Prob. 16A.10AECh. 16 - Prob. 16A.10BECh. 16 - Prob. 16A.11AECh. 16 - Prob. 16A.11BECh. 16 - Prob. 16A.12AECh. 16 - Prob. 16A.12BECh. 16 - Prob. 16A.1PCh. 16 - Prob. 16A.5PCh. 16 - Prob. 16A.6PCh. 16 - Prob. 16B.1DQCh. 16 - Prob. 16B.2DQCh. 16 - Prob. 16B.1AECh. 16 - Prob. 16B.1BECh. 16 - Prob. 16B.2AECh. 16 - Prob. 16B.2BECh. 16 - Prob. 16B.3AECh. 16 - Prob. 16B.3BECh. 16 - Prob. 16B.4AECh. 16 - Prob. 16B.4BECh. 16 - Prob. 16B.5AECh. 16 - Prob. 16B.5BECh. 16 - Prob. 16B.6AECh. 16 - Prob. 16B.6BECh. 16 - Prob. 16B.1PCh. 16 - Prob. 16B.3PCh. 16 - Prob. 16B.4PCh. 16 - Prob. 16B.5PCh. 16 - Prob. 16B.6PCh. 16 - Prob. 16B.8PCh. 16 - Prob. 16B.9PCh. 16 - Prob. 16C.1DQCh. 16 - Prob. 16C.2DQCh. 16 - Prob. 16C.1AECh. 16 - Prob. 16C.1BECh. 16 - Prob. 16C.2AECh. 16 - Prob. 16C.2BECh. 16 - Prob. 16C.3AECh. 16 - Prob. 16C.3BECh. 16 - Prob. 16C.4AECh. 16 - Prob. 16C.4BECh. 16 - Prob. 16C.5AECh. 16 - Prob. 16C.5BECh. 16 - Prob. 16C.6AECh. 16 - Prob. 16C.6BECh. 16 - Prob. 16C.7AECh. 16 - Prob. 16C.7BECh. 16 - Prob. 16C.8AECh. 16 - Prob. 16C.8BECh. 16 - Prob. 16C.1PCh. 16 - Prob. 16C.2PCh. 16 - Prob. 16C.3PCh. 16 - Prob. 16C.5PCh. 16 - Prob. 16C.8PCh. 16 - Prob. 16C.10PCh. 16 - Prob. 16.1IA
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