Atkins' Physical chemistry
11th Edition
ISBN: 9780198814740
Author: ATKINS, P. W. (peter William), 1940- (author.)
Publisher: Oxford University Press,
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Question
Chapter 16, Problem 16A.12BE
Interpretation Introduction
Interpretation:
The time required to reduce pressure inside a container from
Concept introduction:
The process of conversion of particles of a substance from a liquid state to gaseous state below the boiling point of the substance is known as evaporation. At a temperature lower than the boiling point of a liquid, the particles are in equilibrium with liquid state and gaseous state. The particles in the gas state exert vapor pressure.
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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression:
AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T
A. Calculate the value of AS for the process.
B. Next, use the Gibbs-Helmholtz equation:
(a(AG/T))
ΔΗ
-
T2
to calculate the value of AH for the process.
None
Chapter 16 Solutions
Atkins' Physical chemistry
Ch. 16 - Prob. 16A.1STCh. 16 - Prob. 16B.1STCh. 16 - Prob. 16C.1STCh. 16 - Prob. 16A.1DQCh. 16 - Prob. 16A.2DQCh. 16 - Prob. 16A.1AECh. 16 - Prob. 16A.1BECh. 16 - Prob. 16A.2AECh. 16 - Prob. 16A.2BECh. 16 - Prob. 16A.3AE
Ch. 16 - Prob. 16A.3BECh. 16 - Prob. 16A.4AECh. 16 - Prob. 16A.4BECh. 16 - Prob. 16A.5AECh. 16 - Prob. 16A.5BECh. 16 - Prob. 16A.6AECh. 16 - Prob. 16A.6BECh. 16 - Prob. 16A.7AECh. 16 - Prob. 16A.7BECh. 16 - Prob. 16A.8AECh. 16 - Prob. 16A.8BECh. 16 - Prob. 16A.9AECh. 16 - Prob. 16A.9BECh. 16 - Prob. 16A.10AECh. 16 - Prob. 16A.10BECh. 16 - Prob. 16A.11AECh. 16 - Prob. 16A.11BECh. 16 - Prob. 16A.12AECh. 16 - Prob. 16A.12BECh. 16 - Prob. 16A.1PCh. 16 - Prob. 16A.5PCh. 16 - Prob. 16A.6PCh. 16 - Prob. 16B.1DQCh. 16 - Prob. 16B.2DQCh. 16 - Prob. 16B.1AECh. 16 - Prob. 16B.1BECh. 16 - Prob. 16B.2AECh. 16 - Prob. 16B.2BECh. 16 - Prob. 16B.3AECh. 16 - Prob. 16B.3BECh. 16 - Prob. 16B.4AECh. 16 - Prob. 16B.4BECh. 16 - Prob. 16B.5AECh. 16 - Prob. 16B.5BECh. 16 - Prob. 16B.6AECh. 16 - Prob. 16B.6BECh. 16 - Prob. 16B.1PCh. 16 - Prob. 16B.3PCh. 16 - Prob. 16B.4PCh. 16 - Prob. 16B.5PCh. 16 - Prob. 16B.6PCh. 16 - Prob. 16B.8PCh. 16 - Prob. 16B.9PCh. 16 - Prob. 16C.1DQCh. 16 - Prob. 16C.2DQCh. 16 - Prob. 16C.1AECh. 16 - Prob. 16C.1BECh. 16 - Prob. 16C.2AECh. 16 - Prob. 16C.2BECh. 16 - Prob. 16C.3AECh. 16 - Prob. 16C.3BECh. 16 - Prob. 16C.4AECh. 16 - Prob. 16C.4BECh. 16 - Prob. 16C.5AECh. 16 - Prob. 16C.5BECh. 16 - Prob. 16C.6AECh. 16 - Prob. 16C.6BECh. 16 - Prob. 16C.7AECh. 16 - Prob. 16C.7BECh. 16 - Prob. 16C.8AECh. 16 - Prob. 16C.8BECh. 16 - Prob. 16C.1PCh. 16 - Prob. 16C.2PCh. 16 - Prob. 16C.3PCh. 16 - Prob. 16C.5PCh. 16 - Prob. 16C.8PCh. 16 - Prob. 16C.10PCh. 16 - Prob. 16.1IA
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