Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Sketch, qualitatively, the potential energy curves of the N-N bond of N2H4, N2 and N3- graph. Explain why the energy at the minimum of each curve is not the same.
(a) Show that the lattice energies are inversely proportional to the distance between ions in MX (M = alkali metal, X = halide ions) by plotting the lattice energies of KF, KCl, and KI against the internuclear distances, dMX. The lattice energies of KF, KCl, and KI are 826, 717, and 645 kJ/mol, respectively. Does the correlation obtained correlate well? You will need to use a standard graphing program to construct the graph (such as a spreadsheet program). It will generate an equation for the line and calculate a correlation coefficient. (b) Estimate the lattice energy of KBr from your graph. (c) Find an experimental value for the lattice energy of KBr in the literature, and compare this value with the one calculated in (b). Do they agree?
Show the curved arrow mechanism and both products for the reaction between methyl iodide and propoxide.
1st attempt
NV
H
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1
Add the missing curved arrow notation.
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Chapter 16 Solutions
Chemistry: An Atoms-Focused Approach
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Ch. 16 - Prob. 16.12QACh. 16 - Prob. 16.13QACh. 16 - Prob. 16.14QACh. 16 - Prob. 16.16QACh. 16 - Prob. 16.17QACh. 16 - Prob. 16.18QACh. 16 - Prob. 16.19QACh. 16 - Prob. 16.20QACh. 16 - Prob. 16.21QACh. 16 - Prob. 16.22QACh. 16 - Prob. 16.23QACh. 16 - Prob. 16.24QACh. 16 - Prob. 16.25QACh. 16 - Prob. 16.26QACh. 16 - Prob. 16.27QACh. 16 - Prob. 16.28QACh. 16 - Prob. 16.29QACh. 16 - Prob. 16.30QACh. 16 - Prob. 16.31QACh. 16 - Prob. 16.32QACh. 16 - Prob. 16.33QACh. 16 - Prob. 16.34QACh. 16 - Prob. 16.35QACh. 16 - Prob. 16.36QACh. 16 - Prob. 16.37QACh. 16 - Prob. 16.38QACh. 16 - Prob. 16.39QACh. 16 - Prob. 16.40QACh. 16 - Prob. 16.41QACh. 16 - Prob. 16.42QACh. 16 - Prob. 16.43QACh. 16 - Prob. 16.44QACh. 16 - Prob. 16.45QACh. 16 - Prob. 16.46QACh. 16 - Prob. 16.47QACh. 16 - Prob. 16.48QACh. 16 - Prob. 16.49QACh. 16 - Prob. 16.50QACh. 16 - Prob. 16.51QACh. 16 - Prob. 16.52QACh. 16 - Prob. 16.53QACh. 16 - Prob. 16.54QACh. 16 - Prob. 16.55QACh. 16 - Prob. 16.56QACh. 16 - Prob. 16.57QACh. 16 - Prob. 16.58QACh. 16 - Prob. 16.59QACh. 16 - Prob. 16.60QACh. 16 - Prob. 16.61QACh. 16 - Prob. 16.62QACh. 16 - Prob. 16.63QACh. 16 - Prob. 16.64QACh. 16 - Prob. 16.65QACh. 16 - Prob. 16.66QACh. 16 - Prob. 16.67QACh. 16 - Prob. 16.68QACh. 16 - Prob. 16.69QACh. 16 - Prob. 16.70QACh. 16 - Prob. 16.71QACh. 16 - Prob. 16.72QACh. 16 - Prob. 16.73QACh. 16 - Prob. 16.74QACh. 16 - Prob. 16.75QACh. 16 - Prob. 16.76QACh. 16 - Prob. 16.77QACh. 16 - Prob. 16.78QACh. 16 - Prob. 16.79QACh. 16 - Prob. 16.80QACh. 16 - Prob. 16.81QACh. 16 - Prob. 16.82QACh. 16 - Prob. 16.83QACh. 16 - Prob. 16.84QACh. 16 - Prob. 16.85QACh. 16 - Prob. 16.86QACh. 16 - Prob. 16.87QACh. 16 - Prob. 16.88QACh. 16 - Prob. 16.89QACh. 16 - Prob. 16.90QACh. 16 - Prob. 16.91QACh. 16 - Prob. 16.92QACh. 16 - Prob. 16.93QACh. 16 - Prob. 16.94QACh. 16 - Prob. 16.95QACh. 16 - Prob. 16.96QACh. 16 - Prob. 16.97QACh. 16 - Prob. 16.98QACh. 16 - Prob. 16.99QA
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- First I wanted to see if you would mind checking my graphs behind me. (They haven't been coming out right)? Second, could you help me explain if the rate of reaction is proportional to iodide and persulfate of each graph. I highlighted my answer and understanding but I'm not sure if I'm on the right track. Thank you in advance.arrow_forwardThe heat of combustion for ethane, C2H6C2H6 , is 47.8 kJ/g. How much heat is produced if 1.65 moles of ethane undergo complete combustion?arrow_forwardReview of this week's reaction: H2NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H2O ----> H2NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C—N bond shown in creatine structure below can or cannot rotate. (3 pts)arrow_forward
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