Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 16, Problem 16.63SP
The pH of a solution of
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
acids:
0.2 mol of KOH is added to
1.0 L of a 0.5 M HF
solution.
bases:
Х
other: ☐
acids:
0.10 mol of HI is added to
1.0 L of a solution that is
1.4M in both HF and NaF.
bases:
other: ☐
0,0,...
ด
?
18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
무ㅎ
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Chapter 16 Solutions
Chemistry (7th Edition)
Ch. 16 - Prob. 16.1PCh. 16 - APPLY 16.2 Write balanced net ionic equations for...Ch. 16 - PRACTICE 16.3 Calculate the concentrations of all...Ch. 16 - APPLY 16.4 Calculate the pH of a solution prepared...Ch. 16 - Conceptual PRACTICE 16.5 The following pictures...Ch. 16 - Conceptual APPLY 16.6 The following pictures...Ch. 16 - Prob. 16.7PCh. 16 - Prob. 16.8ACh. 16 - Prob. 16.9PCh. 16 - PRACTICE 16.10 Use the Henderson-Hasselbalch...
Ch. 16 - APPLY 16.11 The of the amine group of the amino...Ch. 16 - PRACTICE 16.12 How would you prepare anbuffer...Ch. 16 - APPLY 16.13 Suppose you are performing an...Ch. 16 - Prob. 16.14PCh. 16 - APPLY 16.15 A 40.0 mL volume of 0.100 M NaOH is...Ch. 16 - Prob. 16.16PCh. 16 - Prob. 16.17ACh. 16 - Prob. 16.18PCh. 16 - Prob. 16.19ACh. 16 - PRACTICE 16.20 Write the equilibrium-constant...Ch. 16 - Prob. 16.21ACh. 16 - Prob. 16.22PCh. 16 - Prob. 16.23ACh. 16 - Prob. 16.24PCh. 16 - Prob. 16.25ACh. 16 - Prob. 16.26PCh. 16 - Prob. 16.27ACh. 16 - Prob. 16.28PCh. 16 - Prob. 16.29PCh. 16 - Prob. 16.30ACh. 16 - Prob. 16.31PCh. 16 - Prob. 16.32ACh. 16 - Prob. 16.33PCh. 16 - Prob. 16.34ACh. 16 - PROBLEM 16.35 Determine whether Cd2+ can be...Ch. 16 - Prob. 16.36PCh. 16 - Prob. 16.37PCh. 16 - Prob. 16.38PCh. 16 - Prob. 16.39PCh. 16 - Prob. 16.40CPCh. 16 - The following pictures represent initial...Ch. 16 - Prob. 16.42CPCh. 16 - The following pictures represent solutions at...Ch. 16 - The following pictures represent solutions at...Ch. 16 - Prob. 16.45CPCh. 16 - Prob. 16.46CPCh. 16 - Prob. 16.47CPCh. 16 - Prob. 16.48CPCh. 16 - Prob. 16.49CPCh. 16 - 16.50 Is the pH greater than, equal to, or less...Ch. 16 - Is the pH greater than, equal to, or less than 7...Ch. 16 - Prob. 16.52SPCh. 16 - Prob. 16.53SPCh. 16 - Prob. 16.54SPCh. 16 - Prob. 16.55SPCh. 16 - 16.56 The equilibrium constant for the...Ch. 16 - 16.57 The equilibrium constant for the...Ch. 16 - 16.58 Does the pH increase, decrease, or remain...Ch. 16 - 16.59 Does the pH increase, decrease, or remain...Ch. 16 - 16.60 Calculate the pH of a solution that is 0.25...Ch. 16 - Prob. 16.61SPCh. 16 - Prob. 16.62SPCh. 16 - The pH of a solution of NH3 and NH4Br is 8.90....Ch. 16 - Prob. 16.64SPCh. 16 - Prob. 16.65SPCh. 16 - Prob. 16.66SPCh. 16 - Which of the following gives a buffer solution...Ch. 16 - Prob. 16.68SPCh. 16 - Prob. 16.69SPCh. 16 - Prob. 16.70SPCh. 16 - Prob. 16.71SPCh. 16 - Prob. 16.72SPCh. 16 - Calculate the pH of 0.375 L of a 0.18 M acetic...Ch. 16 - Prob. 16.74SPCh. 16 - Prob. 16.75SPCh. 16 - Prob. 16.76SPCh. 16 - Prob. 16.77SPCh. 16 - Prob. 16.78SPCh. 16 - Prob. 16.79SPCh. 16 - Prob. 16.80SPCh. 16 - Prob. 16.81SPCh. 16 - Prob. 16.82SPCh. 16 - Prob. 16.83SPCh. 16 - Prob. 16.84SPCh. 16 - Prob. 16.85SPCh. 16 - Prob. 16.86SPCh. 16 - Prob. 16.87SPCh. 16 - Prob. 16.88SPCh. 16 - Prob. 16.89SPCh. 16 - Prob. 16.90SPCh. 16 - Prob. 16.91SPCh. 16 - Prob. 16.92SPCh. 16 - Prob. 16.93SPCh. 16 - Prob. 16.94SPCh. 16 - Prob. 16.95SPCh. 16 - Prob. 16.96SPCh. 16 - 16.97 What is the pH at the equivalence point for...Ch. 16 - Prob. 16.98SPCh. 16 - Prob. 16.99SPCh. 16 - Prob. 16.100SPCh. 16 - Prob. 16.101SPCh. 16 - Prob. 16.102SPCh. 16 - Prob. 16.103SPCh. 16 - Prob. 16.104SPCh. 16 - Prob. 16.105SPCh. 16 - Prob. 16.106SPCh. 16 - Prob. 16.107SPCh. 16 - Use Le Châtelier’s principle to explain the...Ch. 16 - Use Le Châtelier’s principle to predict whether...Ch. 16 - Calculate the molar solubility of PbCrO4 in: (a)...Ch. 16 - Prob. 16.111SPCh. 16 - Prob. 16.112SPCh. 16 - Prob. 16.113SPCh. 16 - Prob. 16.114SPCh. 16 - Prob. 16.115SPCh. 16 - Prob. 16.116SPCh. 16 - Dissolution of 5.010-3 mol of CrOH3 in 1.0L of...Ch. 16 - Prob. 16.118SPCh. 16 - Prob. 16.119SPCh. 16 - Prob. 16.120SPCh. 16 - Prob. 16.121SPCh. 16 - Prob. 16.122SPCh. 16 - Prob. 16.123SPCh. 16 - Prob. 16.124SPCh. 16 - Prob. 16.125SPCh. 16 - Prob. 16.126SPCh. 16 - Prob. 16.127SPCh. 16 - Prob. 16.128SPCh. 16 - Prob. 16.129SPCh. 16 - Prob. 16.130SPCh. 16 - Prob. 16.131SPCh. 16 - Prob. 16.132CPCh. 16 - Prob. 16.133CPCh. 16 - Prob. 16.134CPCh. 16 - Prob. 16.135CPCh. 16 - Prob. 16.136CPCh. 16 - Prob. 16.137CPCh. 16 - Prob. 16.138CPCh. 16 - Prob. 16.139CPCh. 16 - Prob. 16.140CPCh. 16 - Prob. 16.141CPCh. 16 - Prob. 16.142CPCh. 16 - Prob. 16.143CPCh. 16 - Prob. 16.144CPCh. 16 - Prob. 16.145CPCh. 16 - Prob. 16.146CPCh. 16 - The acidity of lemon juice is derived primarily...Ch. 16 - Prob. 16.148CPCh. 16 - Prob. 16.149CPCh. 16 - Prob. 16.150CPCh. 16 - Prob. 16.151CPCh. 16 - Prob. 16.152MPCh. 16 - Prob. 16.153MPCh. 16 - Prob. 16.154MPCh. 16 - Prob. 16.155MPCh. 16 - Prob. 16.156MPCh. 16 - Prob. 16.157MPCh. 16 - Prob. 16.158MPCh. 16 - In qualitative analysis, Ca2+ and Ba2+ are...Ch. 16 - Prob. 16.160MPCh. 16 - Prob. 16.161MP
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