EBK STUDENT SOLUTIONS MANUAL TO ACCOMPA
7th Edition
ISBN: 9781119360902
Author: HYSLOP
Publisher: YUZU
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Textbook Question
Chapter 16, Problem 165RQ
Why must the acid used for a buffer have a
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4. Human blood is slightly basic in nature with a normal pH range of 7.35-7.45. The blood pH
is maintained by the carbonic acid-bicarbonate buffer system, shown by the following
equilibrium reaction.
H2CO3 + H2O
H,O* + HCO3
a) If you add a small amount of an acid to this buffer, then which component of the carbonic
acid-bicarbonate buffer will react with the added acid? Explain.
A series of carbonic acid or carbonate buffers regulate pH in blood within the human body. The kidneys and the lungs work together to help maintain a blood pH of 7.4 by affecting the components of the buffers in the blood.
What conjugate acid/base pair is the main component in the buffer? Write out the chemical reaction that the conjugate pair undergoes in water.
What is the ratio of the acid to the base?
What is the ideal pH range for this buffer?
Is the pH of blood within the ideal range of the buffer? If it is not, what is the physiological reason that the body would have for still using a carbonate buffer as opposed to another conjugate pair?
Select the statement or statements that are true about buffer solutions:
Buffer solutions consist of a strong acid and its conjugate base.
The pH of a buffer solution never changes, even when a large amount of strong acid or base is added.
Buffer solutions resist a change in pH by shifting the position of their equilibria to counteract the addition of H3O+ or OH−.
Chapter 16 Solutions
EBK STUDENT SOLUTIONS MANUAL TO ACCOMPA
Ch. 16 - Prob. 1PECh. 16 - Practice Exercise 16.2
An aqueous solution of...Ch. 16 - Practice Exercise 16.3
Water draining from old...Ch. 16 - Because rain washes pollutants out of the air, the...Ch. 16 - Practice Exercise 16.5
Find the values of and ...Ch. 16 - Practice Exercise 16.6
Calculate the . (Hint: is...Ch. 16 - Practice Exercise 16.7
Calculate the , and pH in a...Ch. 16 - For each of the following acids, write the...Ch. 16 - For each of the following acids, write the...Ch. 16 - Practice Exercise 16.10 Use Table 16.2 to find all...
Ch. 16 - Practice Exercise 16.11 Two acids, H A and H B,...Ch. 16 - Practice Exercise 16.12 For each of the following...Ch. 16 - Practice Exercise 16.13 Write the ionization...Ch. 16 - Practice Exercise 16.14 The base methylamine...Ch. 16 - Practice Exercise 16.15
The value of for the
Ch. 16 - Practice Exercise 16.16 Salicylic acid reacts with...Ch. 16 - Practice Exercise 16.17 When butter turns rancid,...Ch. 16 - Practice Exercise 16.18 Few substances are more...Ch. 16 - A student planned an experiment that would use...Ch. 16 - Benzoic acid, HC6H5CO2, is a monoprotic add (only...Ch. 16 - Nicotinic acid, HC6H4NO2, is a B vitamin. It is...Ch. 16 - Aniline, C6H5NH2, is a precursor for many dyes...Ch. 16 - Pyridine, C5H5N, is a bad-smelling liquid for...Ch. 16 - Practice Exercise 16.24
Phenol is an acidic...Ch. 16 - Practice Exercise 16.25
Are solutions of acidic,...Ch. 16 - Are solutions of (a)NaNO3,(b)KF,and(c)NH4NO3...Ch. 16 - Practice Exercise 16.27
What is the pH of a...Ch. 16 - What is the pH of a 0.10 M solution of NaNO2?Ch. 16 - Practice Exercise 16.29
If 500.0 mL of a 0.20 M...Ch. 16 - Practice Exercise 16.30
Will an aqueous solution...Ch. 16 - Will an aqueous solution of ammonium nitrite,...Ch. 16 - Acetic acid, HC2H3O2, and sodium acetate, NaC2H3O2...Ch. 16 - For a buffer composed of NH3 and NH4+ (from...Ch. 16 - Practice Exercise 16.34
Calculate the pH of the...Ch. 16 - One liter of buffer is made by dissolving 100.0...Ch. 16 - Practice Exercise 16.36
From Table 16.2 select an...Ch. 16 - A chemist needed an aqueous buffer with a pH of...Ch. 16 - Practice Exercise 16.38
How much will the pH...Ch. 16 - Practice Exercise 16.39
A buffer is prepared by...Ch. 16 - Write the three ionization steps for phosphoric...Ch. 16 - Ascorbic acid (vitamin C) is a diprotic acid,...Ch. 16 - Sodium bicarbonate gives solutions that are...Ch. 16 - What is the pHofa0.20M solution of Na2SO3at25C?...Ch. 16 - Reasoning by analogy from what you learned about...Ch. 16 - When a weak acid such as acetic acid, HC2H3O2, is...Ch. 16 - Suppose we titrate 20.0 mL of 0.100 MHCHO2 with...Ch. 16 - Practice Exercise 16.47
Suppose 30.0 mL of is...Ch. 16 - Write the chemical equation for (a) the...Ch. 16 - How are acidic, basic, and neutral solutions in...Ch. 16 - At 25C, how are the pHandpOH of a solution related...Ch. 16 - Why do chemists use pH notation instead of the...Ch. 16 - Explain how acids and bases suppress the...Ch. 16 - Prob. 6RQCh. 16 - Could you use the p-notation for the concentration...Ch. 16 - List the strong acids.Ch. 16 - 16.9. What chemical property is central to our...Ch. 16 - 16.10. Explain the difference between strength and...Ch. 16 - How are strong bases identified?Ch. 16 - 16.12. Some strong bases can be used to safely...Ch. 16 - Explain why we can ignore the autoionization of a...Ch. 16 - 16.14 Write the general equation for the...Ch. 16 - Which diagram best represents a weak acid? A...Ch. 16 - Why do we use equilibrium constants, KaandKb, for...Ch. 16 - 16.17 Write the chemical equation for the...Ch. 16 - For each of the acids in Review Question 16.17...Ch. 16 - Write the general equation for the ionization of a...Ch. 16 - 16.20 Write the chemical equation for the...Ch. 16 - 16.21 For each of the bases in Review Question...Ch. 16 - The pKa of HCN is 9.31 and that of HF is 3.46....Ch. 16 - Write the structural formulas for the conjugate...Ch. 16 - 16.24 Write the structural formulas for the...Ch. 16 - 16.25 How is percentage ionization defined? Write...Ch. 16 - What criterion do we use to determine whether or...Ch. 16 - For which of the following are we permitted to...Ch. 16 - What is the quadratic formula? When is it...Ch. 16 - Aspirin is acetylsalicylic acid, a monoprotic acid...Ch. 16 - The Kb value of the oxalate ion,...Ch. 16 - Consider the following compounds and suppose that...Ch. 16 - Will an aqueous solution of AICl3 turn litmus red...Ch. 16 - A solution of hydrazinium acetate is slightly...Ch. 16 - Prob. 34RQCh. 16 - To form a buffer, two substances are needed. How...Ch. 16 - Write ionic equations that illustrate how each...Ch. 16 - 16.37. The hydrogen phosphate ion is able to act...Ch. 16 - 16.38. When sulfur dioxide, an air pollutant from...Ch. 16 - Which diagram best describes a diprotic acid with...Ch. 16 - Citric acid, found in citrus fruits, is a...Ch. 16 - What simplifying assumptions do we usually make in...Ch. 16 - 16.42. Write the equations for the chemical...Ch. 16 - What simplifying assumptions do we usually make in...Ch. 16 - Define the terms equivalence point and end point...Ch. 16 - Will the solution be acidic, neutral, or basic at...Ch. 16 - 16.46. Qualitatively, describe how an acid-base...Ch. 16 - 16.47 If you use methyl orange in the titration of...Ch. 16 - 16.48 Using the list of indicators in Table 16.7,...Ch. 16 - 16.49 Calculate the in each of the following...Ch. 16 - Calculate the [OH-],pH,andpOH for each of the...Ch. 16 - Calculate the molar concentrations of H+andOH- in...Ch. 16 - Calculate the molar concentrations of H+andOH- in...Ch. 16 - Calculate the molar concentrations of H+andOH- in...Ch. 16 - Calculate the molar concentrations of H+andOH- in...Ch. 16 - A certain brand of beer had a H+ concentration...Ch. 16 - A soft drink was put on the market with...Ch. 16 - A sample of Windex had a [OH-]=6.310-5molL-1. What...Ch. 16 - 16.58 Bases tend to be used for cleaning. A...Ch. 16 - Prob. 59RQCh. 16 - At the temperature of the human body, 37C, the...Ch. 16 - 16.61 The interaction of water droplets in rain...Ch. 16 - 16.62 Acid rain forms when rain falls through air...Ch. 16 - 16.63 What is the concentration of ? What is the...Ch. 16 - 16.64 What is the concentration of...Ch. 16 - 16.65 A sodium hydroxide solution is prepared by...Ch. 16 - 16.66 A solution was made by dissolving 0.837 g...Ch. 16 - 16.67 A solution of has a measured pH of 11.60....Ch. 16 - A solution of HCl has a pH of 2.50. How many grams...Ch. 16 - 16.69 In a 0.0020 M solution of , how many moles...Ch. 16 - 16.70 In a certain solution of HCl, the ionization...Ch. 16 - A solution was prepared with 2.64 micrograms of...Ch. 16 - What is the pH of a 3.0107M solution of HCl? What...Ch. 16 - 16.73 Rhododendrons are shrubs that produce...Ch. 16 - 16.74 As eggs age, the pH of the egg white...Ch. 16 - Prob. 75RQCh. 16 - The barbiturate ion, C4H3N2O3,hasKb=1.010-10 What...Ch. 16 - Iodic acid, HIO3, has a pKa of 0.77. (a) What arc...Ch. 16 - Lactic acid HC3H5O3, is responsible for the sour...Ch. 16 - *16.79 A 1.0 M solution of acetic acid has a pH of...Ch. 16 - *16.80 A 0.250 M solution of NH3 has a pH of...Ch. 16 - 16.81 A 0.20 M solution of a weak acid, HA, has a...Ch. 16 - 16.82 A 0.15 M Absolution of an acid found in milk...Ch. 16 - A 0.12 M solution of a weak base is 0.012%...Ch. 16 - 16.84 If a weak base is 0.030% ionized in 0.030...Ch. 16 - Iodic acid, HIO3, is an important oxidizing agent...Ch. 16 - 16.86 Chloroacetic acid, , is a stronger...Ch. 16 - 16.87 Ethylamine, , has a strong, pungent odor...Ch. 16 - Hydroxylamine, HONH2, like ammonia, is a Brnsted...Ch. 16 - *16.89 What are the concentrations of all the...Ch. 16 - What are the concentrations of all the solute...Ch. 16 - 16.91 Codeine, a cough suppressant extracted from...Ch. 16 - Pyridine, C5H5N, is a bad-smelling liquid that is...Ch. 16 - A solution of acetic acid has a pH of 2.54. What...Ch. 16 - How many moles of NH3 must be dissolved in water...Ch. 16 - * 16.95 What is the pH of a 0.0050 M solution of...Ch. 16 - *16.96 What is the pH of a 0.020 M solution of...Ch. 16 - The compound para-aminobenzoic acid (PABA) is a...Ch. 16 - 16.98 Barbituric acid, (which we will abbreviate...Ch. 16 - 16.99 Calculate the pH of . What is the centration...Ch. 16 - Calculate the pH of 0.40MKNO2. What is the...Ch. 16 - Calculate the pH of 0.15MCH3NH3Cl. For...Ch. 16 - Calculate the pH of 0.10 M hydrazinium chloride,...Ch. 16 - A 0.18 M solution of the sodium salt of nicotinic...Ch. 16 - 16.104 A weak base B forms the salt , composed of...Ch. 16 - Liquid chlorine bleach is really nothing more than...Ch. 16 - *16.106 The conjugate acid of a molecular base has...Ch. 16 - 16.107 What is the pH of a solution that contains...Ch. 16 - A buffer is prepared containing...Ch. 16 - Rework Review Problem 16.107 using the Kb for the...Ch. 16 - 16.110 Calculate the pH of the buffer in Review...Ch. 16 - By how much will the pH change if 0.025 mol of HCl...Ch. 16 - 16.112 By how much will the pH change if 25.0 mL...Ch. 16 - Certain proteolytic enzymes react in alkaline...Ch. 16 - *16.114 A hydrolytic enzyme consumes moles of...Ch. 16 - *16.115 What are the initial and final pH values...Ch. 16 - *16.116 What are the initial and final pH values...Ch. 16 - How many grams of sodium acetate, NaC2H3O2, would...Ch. 16 - 16.118 How many grams of sodium formate, , would...Ch. 16 - Suppose 30.00 mL of 0.100 M HCl is added to an...Ch. 16 - 16.120 How many milliliters of 0.15 MHCl would...Ch. 16 - Calculate the concentrations of all the solute...Ch. 16 - *16.122 Tellurium, in the same family as sulfur,...Ch. 16 - Calculate the concentrations of all of the solute...Ch. 16 - What is the pH of a 0.25 M solution of arsenic...Ch. 16 - Phosphorous acid, H3PO3, is actually a diprotic...Ch. 16 - 16.126 What is the pH of a 0.20 M solution of...Ch. 16 - Calculate the pH of 0.24MNa2SO3. What are the...Ch. 16 - *16.128 Calculate the pH of . What are the...Ch. 16 - 16.129 Sodium citrate, , is used as an...Ch. 16 - 16.130 What is the pH of a 0.25 M solution of...Ch. 16 - 16.131 What is the pH of a 0.50 M solution of ? In...Ch. 16 - *16.132 The pH of a solution is adjusted to 12.00...Ch. 16 - What is the pH of a solution prepared by mixing...Ch. 16 - *16.134 What is the pH of a solution prepared by...Ch. 16 - 16.135 When 50.0 mL of 0.050 M formic acid, , is...Ch. 16 - 16.136 When 25 mL of 0.12 M aqueous ammonia is...Ch. 16 - *16.137 For the titration of 75.00 mL of 0.1000 M...Ch. 16 - For the titration of 50.00 mL of 0.1000 M ammonia...Ch. 16 - *16.139 Calculate the percentage ionization of...Ch. 16 - *16.140 What is the pH of a solution that is and...Ch. 16 - A solution is prepared by mixing 325 mL of...Ch. 16 - *16.142 A solution is prepared by dissolving 15.0...Ch. 16 - For an experiment involving what happens to the...Ch. 16 - *16.144 Predict whether the pH of is greater...Ch. 16 - *16.145 What is the pH of a M solution of ammonium...Ch. 16 - How many milliliters of ammonia gas measured at...Ch. 16 - HClO4 is a stronger proton donor than HNO3, but in...Ch. 16 - 16.148 The hydrogen sulfate ion, , is a moderately...Ch. 16 - Some people who take megadoses of ascorbic acid...Ch. 16 - 16.150 For the titration of 25.00 mL of 0. ,...Ch. 16 - Below is a diagram illustrating a mixture HFandF-...Ch. 16 - *16.152 How many milliliters of must be added to...Ch. 16 - Milk of magnesia is a suspension of magnesium...Ch. 16 - 16.154 How many milliliters of are needed to...Ch. 16 - 16.155 It was found that 25.20 mL of an solution...Ch. 16 - Suppose 38.0 mL of 0.000200MHCl is added to 40.0...Ch. 16 - *16.157 Suppose 10.0 mL of gas at and 734 torr...Ch. 16 - *16.158 Suppose the HCl described in the preceding...Ch. 16 - *16.159 What is the approximate freezing point of...Ch. 16 - 16.160 What happens to the pH of a solution as it...Ch. 16 - Can the pH of a solution ever have a negative...Ch. 16 - In simplifying our calculations, we were satisfied...Ch. 16 - In the 1950s it was discovered that lakes in the...Ch. 16 - 16.164 Where are buffers found in everyday...Ch. 16 - Why must the acid used for a buffer have a pKa...Ch. 16 - What conjugate acid-base pairs are used to buffer...Ch. 16 - Your blood at 37C needs to be maintained within a...Ch. 16 - Develop a list of the uses of phosphoric acid in...Ch. 16 - What would our pH scale look like if Arrhenius...
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- Briefly describe how a buffer solution can control the pH of a solution when strong acid is added and when strong base is added. Use NH3/NH4Cl as an example of a buffer and HCl and NaOH as the strong acid and strong base.arrow_forwardIdentify the buffer system(s)the conjugate acidbase pair(s)present in a solution that contains equal molar amounts of the following: a. HF, KC2H3O2, NaC2H3O2, and NaF b. HNO3, NaOH, H3PO4, and NaH2PO4arrow_forwardWhat is the pH of a buffer that is 0.150 M in a weak acid and 0.150 M in the acids conjugate base? The acids ionization constant is 6.8 106.arrow_forward
- Enough water is added to the buffer in Question 29 to make the total volume 10.0 L. Calculate (a) the pH of the buffer. (b) the pH of the buffer after the addition of 0.0500 mol of HCl to 0.600 L of diluted buffer. (c) the pH of the buffer after the addition of 0.0500 mol of NaOH to 0.600 L of diluted buffer. (d) Compare your answers to Question 29(a)-(c) with your answers to (a)-(c) in this problem. (e) Comment on the effect of dilution on the pH of a buffer and on its buffer capacity.arrow_forwardIdentify each pair that could form a buffer. (a) NaOH and NaCl (b) NaOH and NH3 (c) Na3PO4 and Na2HPO4arrow_forwardIdentify each pair that could form a buffer. (a) HCl and CH3COOH (b) NaH2PO4 and Na2HPO4 (c) H2CO3 and NaHCO3arrow_forward
- Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.arrow_forwardMethyl orange, HMO, is a common acid-base indicator. In solution it ionizes according to the equation: HMOaqH+aq+MO-aqredyellow If methyl orange is added to distilled water, the solution turns yellow. If 1 drop or two of 6 M HCl is added to the yellow solution, it turns red. If to that solution one adds a few drops of 6 M NaOH, the color reverts to yellow. a. Why does adding 6 M HCl to the yellow solution of methyl orange tend to cause the color to change to red? Note that in solution HCl exists as H+ and Cl- ions. b. Why does adding 6 M NaOH to the red solution tend to make it turn back to yellow? Note that in solution NaOH exists as Na+ and OH- ions. How does increasing OH- shift Reaction 3 in the discussion section? How would the resulting change in H+ affect the dissociation reaction of HMO?arrow_forwardWrite the chemical equation and the expression for the equilibrium constant, and calculate Kb for the reaction of each of the following ions as a base. (a) sulfate ion (b) citrate ionarrow_forward
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