PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 16, Problem 16.40E
Interpretation Introduction

Interpretation:

Whether the ΔE beween adjacent spin states if the nuclear spin I>12 is the same or different depending on the Ml values involved is to be predicted.

Concept introduction:

Spectroscopy based on the splitting of Ml levels of a nuclei is termed as nuclear magnetic resonance or NMR. The splitting is due to the similar behaviour of nucleus as the electron. Like electrons, nucleus have nonzero spin and a magnetic dipole associated with it. This leads to splitting in an external magnetic field.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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