The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated. Concept introduction: According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

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Answer 1

Question

Chapter 16, Problem 16.34SP

(a)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(b)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(c)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(d)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(e)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 16, Problem 16.34SP

(a)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(b)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(c)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(d)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(e)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

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Answer 3

Question

Chapter 16, Problem 16.34SP

(a)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(b)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(c)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(d)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(e)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

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Answer 4

Question

Chapter 16, Problem 16.34SP

(a)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(b)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(c)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(d)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(e)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

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Answer 5

Chapter 16, Problem 16.34SP

(a)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(b)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(c)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(d)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

(e)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 6

Chapter 16, Problem 16.34SP

(a)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 7

Chapter 16, Problem 16.34SP

(a)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability of the lone pair of electrons is to be stated.

Concept introduction:

According to Lewis acid-base theory, an acid is a species that accepts the lone pair of electrons while a base is a species that donates the lone pair of electrons.

Answer 16

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Answer 19

Ch. 16.2 - Prob. 16.1P Ch. 16.2 - Prob. 16.2P Ch. 16.2 - a. Draw the resonance forms of benzene,...Ch. 16.2 - Show the product of the Diels-Alder dimerization...Ch. 16.4 - Prob. 16.5P Ch. 16.6 - Make a model of cyclooctatetraene in the tub...Ch. 16.6 - Prob. 16.7P Ch. 16.6 - Prob. 16.8P Ch. 16.7 - Prob. 16.9P Ch. 16.8A - a. Draw the molecular orbitals for the...

Solution Summary: The author explains the nature of nitrogen atom in the given heterocyclic compound as strongly basic or weakly basic on the basis of availability.

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