Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393600681
Author: Gilbert
Publisher: W. W. Norton & Company
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Chapter 16, Problem 16.31QA
Interpretation Introduction
To write:
The names of the given complex ions:
a)
b)
c)
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Students have asked these similar questions
Propose syntheses of the following compounds starting with benzene or toluene. Assume ortho and
isomers can be separated.
a.
b.
O₂N-
Cl
COOH
para
0. Propose syntheses to carry out each of the following conversions. Assume ortho and para isomers can
be separated
a.
Br
b.
COOH
CH3
NH₂
PABA
(active ingredient in some sunscreens)
H3C
H
C=C
CH3
H
m-chloroperoxybenzoic acid
CH2Cl2, rt
C-C--.
H3CH2CC
H
H3C CH3
Cl₂
H₂O
NaOH
H₂O
D.
S-
E.
CH3
H₂O₂, H₂O
It
CH₂O Na
+
CHI
F.
HI, H₂O
heat
G.
4
OH
CH3CHCH3 + ICH2CH3
1. NaH
(CH3)3COH
(CH3)3 COCHCH2CH3
2.
CH3
5. Show how the ether below could be prepared from toluene and any other necessary reagents. Show all
reagents and all intermediate structures.
H3C-
H3C-
CI
OCH2CH3
Chapter 16 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 16 - Prob. 16.2VPCh. 16 - Prob. 16.3VPCh. 16 - Prob. 16.4VPCh. 16 - Prob. 16.5VPCh. 16 - Prob. 16.6VPCh. 16 - Prob. 16.7VPCh. 16 - Prob. 16.8VPCh. 16 - Prob. 16.9VPCh. 16 - Prob. 16.10VPCh. 16 - Prob. 16.11QA
Ch. 16 - Prob. 16.12QACh. 16 - Prob. 16.13QACh. 16 - Prob. 16.14QACh. 16 - Prob. 16.16QACh. 16 - Prob. 16.17QACh. 16 - Prob. 16.18QACh. 16 - Prob. 16.19QACh. 16 - Prob. 16.20QACh. 16 - Prob. 16.21QACh. 16 - Prob. 16.22QACh. 16 - Prob. 16.23QACh. 16 - Prob. 16.24QACh. 16 - Prob. 16.25QACh. 16 - Prob. 16.26QACh. 16 - Prob. 16.27QACh. 16 - Prob. 16.28QACh. 16 - Prob. 16.29QACh. 16 - Prob. 16.30QACh. 16 - Prob. 16.31QACh. 16 - Prob. 16.32QACh. 16 - Prob. 16.33QACh. 16 - Prob. 16.34QACh. 16 - Prob. 16.35QACh. 16 - Prob. 16.36QACh. 16 - Prob. 16.37QACh. 16 - Prob. 16.38QACh. 16 - Prob. 16.39QACh. 16 - Prob. 16.40QACh. 16 - Prob. 16.41QACh. 16 - Prob. 16.42QACh. 16 - Prob. 16.43QACh. 16 - Prob. 16.44QACh. 16 - Prob. 16.45QACh. 16 - Prob. 16.46QACh. 16 - Prob. 16.47QACh. 16 - Prob. 16.48QACh. 16 - Prob. 16.49QACh. 16 - Prob. 16.50QACh. 16 - Prob. 16.51QACh. 16 - Prob. 16.52QACh. 16 - Prob. 16.53QACh. 16 - Prob. 16.54QACh. 16 - Prob. 16.55QACh. 16 - Prob. 16.56QACh. 16 - Prob. 16.57QACh. 16 - Prob. 16.58QACh. 16 - Prob. 16.59QACh. 16 - Prob. 16.60QACh. 16 - Prob. 16.61QACh. 16 - Prob. 16.62QACh. 16 - Prob. 16.63QACh. 16 - Prob. 16.64QACh. 16 - Prob. 16.65QACh. 16 - Prob. 16.66QACh. 16 - Prob. 16.67QACh. 16 - Prob. 16.68QACh. 16 - Prob. 16.69QACh. 16 - Prob. 16.70QACh. 16 - Prob. 16.71QACh. 16 - Prob. 16.72QACh. 16 - Prob. 16.73QACh. 16 - Prob. 16.74QACh. 16 - Prob. 16.75QACh. 16 - Prob. 16.76QACh. 16 - Prob. 16.77QACh. 16 - Prob. 16.78QACh. 16 - Prob. 16.79QACh. 16 - Prob. 16.80QACh. 16 - Prob. 16.81QACh. 16 - Prob. 16.82QACh. 16 - Prob. 16.83QACh. 16 - Prob. 16.84QACh. 16 - Prob. 16.85QACh. 16 - Prob. 16.86QACh. 16 - Prob. 16.87QACh. 16 - Prob. 16.88QACh. 16 - Prob. 16.89QACh. 16 - Prob. 16.90QACh. 16 - Prob. 16.91QACh. 16 - Prob. 16.92QACh. 16 - Prob. 16.93QACh. 16 - Prob. 16.94QACh. 16 - Prob. 16.95QACh. 16 - Prob. 16.96QACh. 16 - Prob. 16.97QACh. 16 - Prob. 16.98QACh. 16 - Prob. 16.99QA
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- Given the major organic product(s) of each of the following reactions. If none is predicted, write "N.R." [answer 61 a. b. H3C C. NO₂ CH3CH2CH2Cl AICI 3 1) NaOH CI 2) H3O+ NO₂ 1. SnCl2, H3O+ 2. NaOH 3arrow_forwardPlease correct answer and don't used hand raitingarrow_forwardTo answer the following questions, consider the reaction below: CH3 . CH3 OH a. The best reagents for accomplishing the above transformation are.... a. 1. OsO4, pyridine 2. NaHSO3, H₂O b. 1. Hg(OAc)2, H₂O 1. C. 2. NaBH4 RCO₂H, CH2Cl₂ 2. H₂O* d. 1. BH3, THF 2. H₂O₂, OH b. The alcohol product is classified as a: a. 1° alcohol b. 2° alcohol C. 3° alcohol d. 4° alcohol c. The conversion of an alcohol into an alkyl chloride by reaction with SOCI2 is an example of: a. b. ن نخنه C. d. an El process an Syl process an E2 process an Sy2 processarrow_forward
- Estimation of ash in food Questions: Q1: What does the word ash refer to? Q2: Mention the types of ash in food Q3: Mention the benefit of using a glass dryerarrow_forwardDraw structures corresponding to the names given a. m-fluoronitrobenzene b. p-bromoaniline c. o-chlorophenol d. 3,5-dimethylbenzoic acidarrow_forwardIllustrate the reaction mechanism the following reactionarrow_forward
- Propose a synthesis for the following compound using benzene or toluene and any other reagents necessary. Show all major intermediate compounds that would probably be isolated during the course of your synthesis. on. Harrow_forwardProvide correct IUPAC names for each of the following compounds. NOT a. b. C. 2003 H,N- CH3 NH2 CHarrow_forward. Consider the reaction below to answer the following questions. OH 1. NaH 2. CH3I, ether O-CH3 A. Write the complete stepwise mechanism for the reaction. Show all intermediate structures and all electron flow with arrows. B. Mechanistically, the Williamson ether synthesis outlined above is: ن نخنه a. an El process b. an SN1 process C. an E2 process d. an SN2 process C. Alternatively, cyclopentyl methyl ether may be synthesized from cyclopentene. synthesis of cyclopentyl methyl ether from cyclopentene. Outline aarrow_forward
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