INTRODUCTION TO CHEMISTRY-CONNECT ACCESS
5th Edition
ISBN: 9781265064570
Author: BAUER
Publisher: MCG
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Textbook Question
Chapter 16, Problem 122QP
Draw the line structures for the ether and two alcohols with the molecular formula
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5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers
OH
CH₂OH
I
-c=0
21108 1101
41745 HOR
CH₂OH
IL
Но
CH₂OH
TIL
a. Compounds I and III have this relationship with each other: enantiomers
b. Compounds II and IV have this relationship with each other:
c. Compounds I and II have this relationship with each other:
d. *Draw one structure that is a stereoisomer of II, but neither a
diastereomer nor an enantiomer. (more than one correct answer)
Chapter 16 Solutions
INTRODUCTION TO CHEMISTRY-CONNECT ACCESS
Ch. 16 - Prob. 1QCCh. 16 - Prob. 2QCCh. 16 - Prob. 3QCCh. 16 - What are cyclic hydrocarbons, and how do they...Ch. 16 - Prob. 5QCCh. 16 - Prob. 6QCCh. 16 - Prob. 7QCCh. 16 - Prob. 8QCCh. 16 - Prob. 9QCCh. 16 - Prob. 1PP
Ch. 16 - Prob. 2PPCh. 16 - Prob. 3PPCh. 16 - Prob. 4PPCh. 16 - Prob. 5PPCh. 16 - Prob. 6PPCh. 16 - Prob. 7PPCh. 16 - Prob. 8PPCh. 16 - Prob. 9PPCh. 16 - Prob. 10PPCh. 16 - Prob. 11PPCh. 16 - Prob. 1QPCh. 16 - Prob. 2QPCh. 16 - Prob. 3QPCh. 16 - Prob. 4QPCh. 16 - Prob. 5QPCh. 16 - Prob. 6QPCh. 16 - Prob. 7QPCh. 16 - Prob. 8QPCh. 16 - Prob. 9QPCh. 16 - Prob. 10QPCh. 16 - Prob. 11QPCh. 16 - Prob. 12QPCh. 16 - Prob. 13QPCh. 16 - Prob. 14QPCh. 16 - Prob. 15QPCh. 16 - Prob. 16QPCh. 16 - Prob. 17QPCh. 16 - Prob. 18QPCh. 16 - Prob. 19QPCh. 16 - Prob. 20QPCh. 16 - Prob. 21QPCh. 16 - Prob. 22QPCh. 16 - Prob. 23QPCh. 16 - Prob. 24QPCh. 16 - Prob. 25QPCh. 16 - Prob. 26QPCh. 16 - Prob. 27QPCh. 16 - Prob. 28QPCh. 16 - Prob. 29QPCh. 16 - Prob. 30QPCh. 16 - Prob. 31QPCh. 16 - Prob. 32QPCh. 16 - Prob. 33QPCh. 16 - Prob. 34QPCh. 16 - Prob. 35QPCh. 16 - Prob. 36QPCh. 16 - Prob. 37QPCh. 16 - Prob. 38QPCh. 16 - Prob. 39QPCh. 16 - Prob. 40QPCh. 16 - Prob. 41QPCh. 16 - Write IUPAC names for the following compounds....Ch. 16 - Prob. 43QPCh. 16 - Prob. 44QPCh. 16 - Prob. 45QPCh. 16 - Prob. 46QPCh. 16 - Prob. 47QPCh. 16 - Prob. 48QPCh. 16 - Prob. 49QPCh. 16 - Prob. 50QPCh. 16 - Prob. 51QPCh. 16 - Prob. 52QPCh. 16 - Prob. 53QPCh. 16 - Prob. 54QPCh. 16 - Prob. 55QPCh. 16 - Prob. 56QPCh. 16 - Prob. 57QPCh. 16 - Prob. 58QPCh. 16 - Prob. 59QPCh. 16 - Prob. 60QPCh. 16 - Prob. 61QPCh. 16 - Prob. 62QPCh. 16 - Prob. 63QPCh. 16 - Prob. 64QPCh. 16 - Prob. 65QPCh. 16 - Prob. 66QPCh. 16 - Prob. 67QPCh. 16 - Prob. 68QPCh. 16 - Prob. 69QPCh. 16 - Prob. 70QPCh. 16 - Prob. 71QPCh. 16 - Prob. 72QPCh. 16 - Prob. 73QPCh. 16 - Prob. 74QPCh. 16 - Prob. 75QPCh. 16 - Prob. 76QPCh. 16 - Prob. 77QPCh. 16 - Prob. 78QPCh. 16 - Prob. 79QPCh. 16 - Prob. 80QPCh. 16 - Prob. 81QPCh. 16 - Prob. 82QPCh. 16 - Prob. 83QPCh. 16 - Prob. 84QPCh. 16 - Prob. 85QPCh. 16 - Prob. 86QPCh. 16 - Prob. 87QPCh. 16 - Prob. 88QPCh. 16 - Predict and explain the relative boiling points of...Ch. 16 - Prob. 90QPCh. 16 - Prob. 91QPCh. 16 - Prob. 92QPCh. 16 - Prob. 93QPCh. 16 - Prob. 94QPCh. 16 - Prob. 95QPCh. 16 - Prob. 96QPCh. 16 - Prob. 97QPCh. 16 - Prob. 98QPCh. 16 - Prob. 99QPCh. 16 - Prob. 100QPCh. 16 - Prob. 101QPCh. 16 - Prob. 102QPCh. 16 - Prob. 103QPCh. 16 - Prob. 104QPCh. 16 - Prob. 105QPCh. 16 - Prob. 106QPCh. 16 - Prob. 107QPCh. 16 - Prob. 108QPCh. 16 - Prob. 109QPCh. 16 - Prob. 110QPCh. 16 - Prob. 111QPCh. 16 - Prob. 112QPCh. 16 - Prob. 113QPCh. 16 - Prob. 114QPCh. 16 - Prob. 115QPCh. 16 - Prob. 116QPCh. 16 - Prob. 117QPCh. 16 - Prob. 118QPCh. 16 - Prob. 119QPCh. 16 - Prob. 120QPCh. 16 - Prob. 121QPCh. 16 - Draw the line structures for the ether and two...Ch. 16 - Prob. 123QPCh. 16 - Prob. 124QPCh. 16 - Prob. 125QPCh. 16 - Prob. 126QPCh. 16 - Write structural formulas for all the isomers of...Ch. 16 - Prob. 128QPCh. 16 - Prob. 129QPCh. 16 - Prob. 130QPCh. 16 - Prob. 131QPCh. 16 - Prob. 132QPCh. 16 - Prob. 133QPCh. 16 - Prob. 134QPCh. 16 - Prob. 135QPCh. 16 - Prob. 136QPCh. 16 - Prob. 137QPCh. 16 - Prob. 138QPCh. 16 - Prob. 139QPCh. 16 - Prob. 140QPCh. 16 - Prob. 141QPCh. 16 - Prob. 142QPCh. 16 - Prob. 143QP
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