Among three solutions A, B, and C each contain a different cation and the other two solutions Y and Z each containing a different anion. Five unknown solutions are to be stated. Concept introduction: Metal cations have two characteristics that allow them to act as a Lewis acid: (a) Their positive charge that attracts electrons. (b) They have at least one empty orbital that can accommodate an electron pair. Anions can act as a Lewis base because they have a lone pair of the electron that can donate to an empty orbital of Lewis acid and anion can also act as a bronsted base because they can accept a proton from an acid to form the conjugate acid of the ion. A conjugate acid-base pair contains two compounds that differ only by a hydrogen ion and a charge of + 1 . The stronger the acid, the weaker its conjugate base and vice-verca.
Among three solutions A, B, and C each contain a different cation and the other two solutions Y and Z each containing a different anion. Five unknown solutions are to be stated. Concept introduction: Metal cations have two characteristics that allow them to act as a Lewis acid: (a) Their positive charge that attracts electrons. (b) They have at least one empty orbital that can accommodate an electron pair. Anions can act as a Lewis base because they have a lone pair of the electron that can donate to an empty orbital of Lewis acid and anion can also act as a bronsted base because they can accept a proton from an acid to form the conjugate acid of the ion. A conjugate acid-base pair contains two compounds that differ only by a hydrogen ion and a charge of + 1 . The stronger the acid, the weaker its conjugate base and vice-verca.
Solution Summary: The author explains that three solutions A, B, and C each contain different cations and the other two solutions Y and Z each containing a different anion.
Among three solutions A, B, and C each contain a different cation and the other two solutions Y and Z each containing a different anion. Five unknown solutions are to be stated.
Concept introduction:
Metal cations have two characteristics that allow them to act as a Lewis acid:
(a) Their positive charge that attracts electrons.
(b) They have at least one empty orbital that can accommodate an electron pair.
Anions can act as a Lewis base because they have a lone pair of the electron that can donate to an empty orbital of Lewis acid and anion can also act as a bronsted base because they can accept a proton from an acid to form the conjugate acid of the ion.
A conjugate acid-base pair contains two compounds that differ only by a hydrogen ion and a charge of +1.
The stronger the acid, the weaker its conjugate base and vice-verca.
For Raman spectroscopy/imaging, which statement is not true regarding its disadvantages?
a) Limited spatial resolution.
b) Short integration time.
c) A one-dimensional technique.
d) Weak signal, only 1 in 108 incident photons is Raman scattered.
e) Fluorescence interference.
Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40.
a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L)
b) Calculate the molar absorptivity, a, of the 1645 cm-1 band
c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c. (Please provide a full derivation of the equation for x from the equation for I).
d) Calculate x for the 1645 cm-1 band
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