Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 16, Problem 113E
Write chemical equations and corresponding equilibrium expressions for each of the three ionization steps of phosphoric acid.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
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NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 16 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 16 - In the opening section of this chapter text, we...Ch. 16 - What are the general physical and chemical...Ch. 16 - What is a carboxylic acid? Give an example?Ch. 16 - What is the Arrhenius definition of an acid? Of a...Ch. 16 - What is a hydronium ion? Does H+ exist in solution...Ch. 16 - What is the Bronsted-Lowry definition of an acid?...Ch. 16 - Why is there more than one definition of acid-base...Ch. 16 - Describe amphoteric behavior and give an example.Ch. 16 - What is a conjugate acid-base pair? Provide an...Ch. 16 - Explain the difference between a strong acid and a...
Ch. 16 - For a binary acid, H-Y, which factors affect the...Ch. 16 - Which factors affect the relative acidity of an...Ch. 16 - What are diprotic and triprotic acids? List an...Ch. 16 - Define the acid ionization constant and explain...Ch. 16 - Write an equation for the autoionization of water...Ch. 16 - What happens to the [OH-] of a solution when the...Ch. 16 - Define pH. What pH range is considered acidic?...Ch. 16 - Define pOH. What pOH range is considered acidic?...Ch. 16 - In most solutions containing a strong or weak...Ch. 16 - When calculating [H3O+] for weak acid solutions,...Ch. 16 - What is the percent ionization of an acid? Explain...Ch. 16 - In calculating [H3O+] for a mixture of a strong...Ch. 16 - Write a generic equation showing how a weak base...Ch. 16 - How can you identified if an anion will act as a...Ch. 16 - What is the relationship between the acid...Ch. 16 - What kinds of cations act as weak acids? List some...Ch. 16 - When calculating the [H3O+] for a polyprotic acid,...Ch. 16 - For a weak diprotic acid H2X, what is the...Ch. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Identify each substance as an acid or a base and...Ch. 16 - Identify each substance as an acid or a base and...Ch. 16 - In each reaction, identify the Bronsted-Lowry...Ch. 16 - In each reaction, identify the Bronsted-Lowry...Ch. 16 - Write the formula for the conjugate base of each...Ch. 16 - Write the formula for the conjugate acid of each...Ch. 16 - Both H2O and H2PO4 are amphoteric. Write an...Ch. 16 - Both HCO3 and HS are amphoteric. Write an equation...Ch. 16 - Prob. 39ECh. 16 - Based on molecular structure, arrange the binary...Ch. 16 - Based on their molecular structure, pick the...Ch. 16 - Based on molecular structure, arrange the oxyacids...Ch. 16 - Prob. 43ECh. 16 - Which is a stronger base, PO43 or AsO43 ? Explain.Ch. 16 - Classify each acid as strong or weak. If the acid...Ch. 16 - Classify each acid as strong or weak. If the acid...Ch. 16 - The three diagrams represent three different...Ch. 16 - Rank the solutions in order of decreasing [H3O+] :...Ch. 16 - Calculate [OH-] in each aqueous solution at 25°C,...Ch. 16 - Calculate [H3O+] in each aqueous solution at 25°C,...Ch. 16 - Calculate the pH and pH of each solution....Ch. 16 - Calculate [H3O+] and [OH-] for each solution. pH =...Ch. 16 - Complete the table. (All solutions are at 25°C.)...Ch. 16 - Prob. 54ECh. 16 - all equilibrium constants, the value of Kw depends...Ch. 16 - The value of KWincreases with temperature. Is the...Ch. 16 - Calculate the pH of each acid solution. Explain...Ch. 16 - Find the concentration of H3O+, to the correct...Ch. 16 - For each strong acid solution, determine [H3O+],...Ch. 16 - Prob. 60ECh. 16 - What mass of HI should be present in 0.250 L of...Ch. 16 - Prob. 62ECh. 16 - What is the pH of solution in which 224 mL of...Ch. 16 - What volume of a concentrated HCl solution, which...Ch. 16 - Determine the [H3O+] and pH of a 0.100 M solution...Ch. 16 - Prob. 66ECh. 16 - Determine the pH of an HNO2 solution of each...Ch. 16 - Determine the pH of an HF solution of each...Ch. 16 - If 15.0 mL of glacial acetic acid (pure HC2H3O2)...Ch. 16 - Calculate the pH of a formic acid solution that...Ch. 16 - A 0.185 M solution of a weak acid (HA) has a pH of...Ch. 16 - Prob. 72ECh. 16 - Determine the percent ionization of a 0.125 M HCN...Ch. 16 - Determine the percent ionization of a 0.225 M...Ch. 16 - Calculate the percent ionization of an acetic acid...Ch. 16 - Calculate the percent ionization of a formic acid...Ch. 16 - A 0.148 M solution of a monoprotic acid has a...Ch. 16 - Prob. 78ECh. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Find the pH of each mixture of acids. 0.115 M in...Ch. 16 - Find the pH of each mixture of acids. 0.075 M in...Ch. 16 - For each strong base solution, determine [OH-],...Ch. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Determine the [OH-], pH, and pOH of a 0.15 ammonia...Ch. 16 - Determine the [OH-], pH, and pOH of a solution...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - Determine if each anion is basic or neutral. For...Ch. 16 - Determine whether each anion is basic or neutral....Ch. 16 - Prob. 99ECh. 16 - Determine the [OH-] and pH of a solution is 0.250...Ch. 16 - Determine whether each cation is acidic or...Ch. 16 - Prob. 102ECh. 16 - Determine if each salt will form a solution that...Ch. 16 - Prob. 104ECh. 16 - Prob. 105ECh. 16 - Prob. 106ECh. 16 - Prob. 107ECh. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - Write chemical equations and corresponding...Ch. 16 - Prob. 114ECh. 16 - Prob. 115ECh. 16 - Calculate the [H3O+] and pH of each polyprotic...Ch. 16 - Calculate the concentration of each species in a...Ch. 16 - Calculate the concentration of each species in a...Ch. 16 - Calculate the [H3O+] and pH of each H2S04...Ch. 16 - Consider a 0.10 M solution of a weak polyprotic...Ch. 16 - Classify each species as a Lewis acid or a Lewis...Ch. 16 - Prob. 122ECh. 16 - Prob. 123ECh. 16 - Prob. 124ECh. 16 - Prob. 125ECh. 16 - Based on these molecular views, determine whether...Ch. 16 - The binding of oxygen by hemoglobin in the blood...Ch. 16 - Carbon dioxide dissolves in water according to the...Ch. 16 - People often take Milk of Magnesia to reduce the...Ch. 16 - Lakes that have been acidified by acid rain (which...Ch. 16 - Acid rain over the Great lakes has a pH of about...Ch. 16 - White wines tend to be more acidic than red wines....Ch. 16 - Common aspirin is acetylsalicylic acid, which has...Ch. 16 - The AIDS drug zalcitabine (also known as ddC) is a...Ch. 16 - Determine the pH of each solution. 0.0100MHCIO4...Ch. 16 - Determine the pH of each solution. 0.0650M HNO3...Ch. 16 - Determine the pH of each two-component solution....Ch. 16 - Determine the pH of each two-component solution....Ch. 16 - Write net ionic equations for the reactions that...Ch. 16 - Prob. 140ECh. 16 - The pH of a 1.00 M solution of urea, a weak...Ch. 16 - Prob. 142ECh. 16 - Lactic acid is a weak acid found in milk. Its...Ch. 16 - Prob. 144ECh. 16 - A student mistakenly calculates the pH of a 1.0107...Ch. 16 - When 2.55 g of an unknown weak acid (HA) with a...Ch. 16 - Prob. 147ECh. 16 - To what volume should you dilute 1 L of a solution...Ch. 16 - HA, a weak acid, with Ka=1.0108 , also forms the...Ch. 16 - Prob. 150ECh. 16 - Prob. 151ECh. 16 - To 1.0 L of a 0.30 M solution of HCIO2 is added...Ch. 16 - A mixture of Na2CO3 and NaHCO3 has a mass of 82.2...Ch. 16 - Prob. 154ECh. 16 - Prob. 155ECh. 16 - Prob. 156ECh. 16 - Prob. 157ECh. 16 - Prob. 158ECh. 16 - Without referring to the text, go around your...Ch. 16 - Prob. 160ECh. 16 - Prob. 161ECh. 16 - Prob. 162ECh. 16 - Prob. 163ECh. 16 - Prob. 164ECh. 16 - Identify the conjugate base in the reaction shown...Ch. 16 - Which pair is a Bronsted-Lowry conjugate acid-base...Ch. 16 - Which acid has the largest Ka: HClO2(aq),...Ch. 16 - Consider the given acid ionization constants and...Ch. 16 - What is the OH- concentration in an aqueous...Ch. 16 - An HNO3(aq) solution has a pH of 1.75. What is the...Ch. 16 - Find the pH of a 0.350 M aqueous benzoic acid...Ch. 16 - Find the pH of a 0.155 M HClO2(aq) solution. For...Ch. 16 - 9. Calculate the percent ionization of 1.45 M...Ch. 16 - Consider two aqueous solutions of nitrous acid...Ch. 16 - What is the [OH-] in a 0.200 M solution of...Ch. 16 - Which ion will be basic in aqueous solution? HSO4-...Ch. 16 - Which compound will form an acidic solution when...Ch. 16 - Find the pH of 0.175 M NaCN solution. For HCN,...Ch. 16 - What is the concentration of X2- in a 0.150 M...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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