Cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C 6 H 8 2- . Whether the reaction will take place readily or not is to be stated. The geometry expected for the cyclooctatetraene dianion is also to be given. Concept introduction: According to Huckel’s Rule a planar, cyclic conjugated system will be aromatic if it contains (4n+2)Ï€ electrons. Systems with 4nÏ€ electrons will be antiaromatic. If the product is more stable than the reactant the reaction will proceed readily. A planar geometry is expected for ions that are aromatic. To state: Whether the reaction in which cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C 6 H 8 2- will take place readily or not. To give: The geometry expected for the cyclooctatetraene dianion.

Question

3. Assign absolute configuration (Rors) to each chirality center. a. H Nitz C. он b. 0 H-C. C H 7 C. ་-4 917-417 refs H 1つ ८ ડુ d. Но f. -2- 01 Ho -OH 2HN

Answer 1

Question

Definition Definition Rule that estimates whether a given organic planar ring structure will show an aromatic property. A cyclic ring molecule is said to follow Hückel’s rule if the л-electrons count in a molecule is [4n+2], where n stands for a positive numerical value. It is also called the [4n+2] rule. Hückel's rule, sometimes referred to as the aromaticity rule, is one but not the only criteria to judge a molecule for aromaticity.

Chapter 15.4, Problem 7P

Interpretation Introduction

Interpretation:

Cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2-. Whether the reaction will take place readily or not is to be stated. The geometry expected for the cyclooctatetraene dianion is also to be given.

Concept introduction:

According to Huckel’s Rule a planar, cyclic conjugated system will be aromatic if it contains (4n+2)Ï€ electrons. Systems with 4nÏ€ electrons will be antiaromatic.

If the product is more stable than the reactant the reaction will proceed readily.

A planar geometry is expected for ions that are aromatic.

To state:

Whether the reaction in which cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2- will take place readily or not.

To give:

The geometry expected for the cyclooctatetraene dianion.

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3. Assign absolute configuration (Rors) to each chirality center. a. H Nitz C. он b. 0 H-C. C H 7 C. ་-4 917-417 refs H 1つ ८ ડુ d. Но f. -2- 01 Ho -OH 2HN

How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom molecule

In the drawing area below, draw the major products of this organic reaction: 1. NaOH ? 2. CH3Br If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area instead. No reaction. Click and drag to start drawing a structure. ☐ : A ค

Answer 2

Question

Definition Definition Rule that estimates whether a given organic planar ring structure will show an aromatic property. A cyclic ring molecule is said to follow Hückel’s rule if the л-electrons count in a molecule is [4n+2], where n stands for a positive numerical value. It is also called the [4n+2] rule. Hückel's rule, sometimes referred to as the aromaticity rule, is one but not the only criteria to judge a molecule for aromaticity.

Chapter 15.4, Problem 7P

Interpretation Introduction

Interpretation:

Cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2-. Whether the reaction will take place readily or not is to be stated. The geometry expected for the cyclooctatetraene dianion is also to be given.

Concept introduction:

According to Huckel’s Rule a planar, cyclic conjugated system will be aromatic if it contains (4n+2)Ï€ electrons. Systems with 4nÏ€ electrons will be antiaromatic.

If the product is more stable than the reactant the reaction will proceed readily.

A planar geometry is expected for ions that are aromatic.

To state:

Whether the reaction in which cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2- will take place readily or not.

To give:

The geometry expected for the cyclooctatetraene dianion.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Definition Definition Rule that estimates whether a given organic planar ring structure will show an aromatic property. A cyclic ring molecule is said to follow Hückel’s rule if the л-electrons count in a molecule is [4n+2], where n stands for a positive numerical value. It is also called the [4n+2] rule. Hückel's rule, sometimes referred to as the aromaticity rule, is one but not the only criteria to judge a molecule for aromaticity.

Chapter 15.4, Problem 7P

Interpretation Introduction

Interpretation:

Cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2-. Whether the reaction will take place readily or not is to be stated. The geometry expected for the cyclooctatetraene dianion is also to be given.

Concept introduction:

According to Huckel’s Rule a planar, cyclic conjugated system will be aromatic if it contains (4n+2)Ï€ electrons. Systems with 4nÏ€ electrons will be antiaromatic.

If the product is more stable than the reactant the reaction will proceed readily.

A planar geometry is expected for ions that are aromatic.

To state:

Whether the reaction in which cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2- will take place readily or not.

To give:

The geometry expected for the cyclooctatetraene dianion.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Rule that estimates whether a given organic planar ring structure will show an aromatic property. A cyclic ring molecule is said to follow Hückel’s rule if the л-electrons count in a molecule is [4n+2], where n stands for a positive numerical value. It is also called the [4n+2] rule. Hückel's rule, sometimes referred to as the aromaticity rule, is one but not the only criteria to judge a molecule for aromaticity.

Chapter 15.4, Problem 7P

Interpretation Introduction