Chemistry: An Introduction to General, Organic, and Biological Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (13th Edition)
13th Edition
ISBN: 9780134416793
Author: Karen C Timberlake
Publisher: PEARSON
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Chapter 15.4, Problem 15.29PP
Identify each of the following processes as hydrogenation, hydrolysis, or saponification and give the products:
- The reaction of palm oil with KOH
- The reaction of glycerol trilinoleate from saffflower oil with water and HCl
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 15 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (13th Edition)
Ch. 15.1 - Lipids are not soluble in water. Are lipids polar...Ch. 15.1 - Which of the following solvents might be used to...Ch. 15.1 - Prob. 15.3PPCh. 15.1 - Prob. 15.4PPCh. 15.2 - Describe some similarities and differences in the...Ch. 15.2 - Prob. 15.6PPCh. 15.2 - Prob. 15.7PPCh. 15.2 - Draw the line-angle formula for each of the...Ch. 15.2 - Prob. 15.9PPCh. 15.2 - For each of the following fatty acids, give the...
Ch. 15.2 - Prob. 15.11PPCh. 15.2 - How does the double bond influence the dispersion...Ch. 15.2 - Prob. 15.13PPCh. 15.2 - Prob. 15.14PPCh. 15.2 - Prob. 15.15PPCh. 15.2 - Prob. 15.16PPCh. 15.2 - Prob. 15.17PPCh. 15.2 - Prob. 15.18PPCh. 15.3 - Draw the condensed structural formula for the...Ch. 15.3 - Prob. 15.20PPCh. 15.3 - Prob. 15.21PPCh. 15.3 - Draw the condensed structural formula for a mixed...Ch. 15.3 - Prob. 15.23PPCh. 15.3 - Prob. 15.24PPCh. 15.3 - Prob. 15.25PPCh. 15.3 - Prob. 15.26PPCh. 15.3 - How does the perc entage of monounsaturated and...Ch. 15.3 - Prob. 15.28PPCh. 15.4 - Identify each of the following processes as...Ch. 15.4 - Identify each of the following processes as...Ch. 15.4 - Prob. 15.31PPCh. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Prob. 15.33PPCh. 15.4 - Prob. 15.34PPCh. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Prob. 15.37PPCh. 15.4 - Draw the condensed structural formula for all the...Ch. 15.5 - Prob. 15.39PPCh. 15.5 - Prob. 15.40PPCh. 15.5 - Draw the condensed structural formula for the...Ch. 15.5 - Draw the condensed structural formula for the...Ch. 15.5 - Prob. 15.43PPCh. 15.5 - Prob. 15.44PPCh. 15.5 - Prob. 15.45PPCh. 15.5 - Prob. 15.46PPCh. 15.6 - Draw the structure for the steroid nucleus.Ch. 15.6 - Draw the structure for cholesterol.Ch. 15.6 - Prob. 15.49PPCh. 15.6 - Prob. 15.50PPCh. 15.6 - Prob. 15.51PPCh. 15.6 - Prob. 15.52PPCh. 15.6 - Prob. 15.53PPCh. 15.6 - Prob. 15.54PPCh. 15.6 - Prob. 15.55PPCh. 15.6 - What are the similarities and differences between...Ch. 15.6 - Prob. 15.57PPCh. 15.6 - Prob. 15.58PPCh. 15.7 - What is the function if the lipid by layer in a...Ch. 15.7 - Prob. 15.60PPCh. 15.7 - Prob. 15.61PPCh. 15.7 - How do the unsaturated fatty acids in the...Ch. 15.7 - Prob. 15.63PPCh. 15.7 - Prob. 15.64PPCh. 15.7 - Prob. 15.65PPCh. 15.7 - 15.66 Identify the type of transport described by...Ch. 15.7 - Identify the functional groups in Pravachol.Ch. 15.7 - Identify the functional groups in Tri Cor.Ch. 15.7 - Prob. 15.69PPCh. 15.7 - Prob. 15.70PPCh. 15 - Prob. 15.71UTCCh. 15 - Prob. 15.72UTCCh. 15 - Prob. 15.73UTCCh. 15 - Prob. 15.74UTCCh. 15 - Prob. 15.75APPCh. 15 - Prob. 15.76APPCh. 15 - Prob. 15.77APPCh. 15 - Prob. 15.78APPCh. 15 - Identify each of the following as a fatty acid,...Ch. 15 - Identify each of the following as a fatty acid,...Ch. 15 - 15.81 Identify the components (1 to 6 ) contained...Ch. 15 - Prob. 15.82APPCh. 15 - Which of the following are found in cell...Ch. 15 - Which of the following are found in cell...Ch. 15 - Draw the condensed structural formula for a...Ch. 15 - sunflower seed oil can be used to make margarine....Ch. 15 - Prob. 15.87CPCh. 15 - 15.87 Match the lipoprotein (1 to 4) with its...Ch. 15 - 15.89 A sink drain can become clogged with solid...Ch. 15 - 15.90 One of the triacylglycerols in olive oil is...Ch. 15 - 15.91 1.00 mole of glyceryl trioleate (triolein)...Ch. 15 - The plastic known as PETE...Ch. 15 - Using the Internet, look up the condensed...Ch. 15 - The insect repellent DEET is an amide that can be...Ch. 15 - Glyceryl trimyristate (trimyristin) is found in...Ch. 15 - Prob. 31CICh. 15 - Prob. 32CI
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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