(a) Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn. Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are: 1. When the ring is mono-substituted, then there is no need of numbering. 2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number. 3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority. 4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Question

B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

Answer 1

Question

Chapter 15.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;

The highest boiling compound from among the following isA. 2-methylheptane; B. 3-methylheptane; C. 2,2-dimethylhexane;D. octane; E. 2,2,3-trimethylpentane

Answer 2

Question

Chapter 15.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

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Answer 3

Question

Chapter 15.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

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Answer 4

Question

Chapter 15.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

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Answer 5

Chapter 15.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 6

Chapter 15.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 7

Chapter 15.3, Problem 4P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 8

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 9

Interpretation Introduction

(b)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 10

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 11

Interpretation Introduction

(c)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 12

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 13

Interpretation Introduction

(d)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 14

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 15

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 16

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 17

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.

Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:

1. When the ring is mono-substituted, then there is no need of numbering.

2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.

3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.

4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.

Answer 18

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Answer 29

Ch. 15.2 - Prob. 1P Ch. 15.2 - Problem 17.2 What orbitals are used to form the...Ch. 15.3 - Prob. 4P Ch. 15.3 - Problem-17.5 What is the structure of propofol,...Ch. 15.6 - Prob. 7P Ch. 15.8 - Prob. 8P Ch. 15.8 - Prob. 11P Ch. 15.8 - Prob. 12P Ch. 15.8 - Problem 17.16 Rank the following compounds in...Ch. 15.8 - Problem 17.17 Draw the seven resonance structures...

Solution Summary: The author explains that IUPAC nomenclature is a systematic way of naming the organic compounds.

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