Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 15.3, Problem 15.21PP
Interpretation Introduction
To draw: Condensed structural formula for triacylglycerol containing stearic acid and glycerol
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5. Please draw in the blanks the missing transition states and the correlated products. Explicitly
display relevant absolute stereochemical configuration.
MeOH
I
OMe
H
Endo transition state,
dienophile approaching from the bottom of diene
+
H
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OMe
H
H
OMe
Endo transition state,
dienophile approaching from the top of diene or
from the bottom but horizontally flipped (draw one)
+
Exo transition state,
dienophile approaching from the top of diene or
from the bottom but horizontally flipped (draw one)
Exo transition state,
dienophile approaching from the top of diene or
from the bottom but horizontally flipped (draw one)
MeO H
H
MeO H
MeO H
MeO H
H
H
H
(1)
H
C.
C
C
.H
(2)
(3)
Cl
H
The ideal value for bond angle (1) is (Choose one)
and the ideal value for bond angle (3) is (Choose one)
degrees, the value for bond angle (2) is (Choose one) degrees,
degrees.
Chapter 15 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 15.1 - Lipids are not soluble in water. Are lipids polar...Ch. 15.1 - Which of the following solvents might be used to...Ch. 15.1 - Prob. 15.3PPCh. 15.1 - Prob. 15.4PPCh. 15.2 - Describe some similarities and differences in the...Ch. 15.2 - Prob. 15.6PPCh. 15.2 - Prob. 15.7PPCh. 15.2 - Draw the line-angle formula for each of the...Ch. 15.2 - Prob. 15.9PPCh. 15.2 - For each of the following fatty acids, give the...
Ch. 15.2 - Prob. 15.11PPCh. 15.2 - How does the double bond influence the dispersion...Ch. 15.2 - Prob. 15.13PPCh. 15.2 - Prob. 15.14PPCh. 15.2 - Prob. 15.15PPCh. 15.2 - Prob. 15.16PPCh. 15.2 - Prob. 15.17PPCh. 15.2 - Prob. 15.18PPCh. 15.3 - Draw the condensed structural formula for the...Ch. 15.3 - Prob. 15.20PPCh. 15.3 - Prob. 15.21PPCh. 15.3 - Draw the condensed structural formula for a mixed...Ch. 15.3 - Prob. 15.23PPCh. 15.3 - Prob. 15.24PPCh. 15.3 - Prob. 15.25PPCh. 15.3 - Prob. 15.26PPCh. 15.3 - How does the perc entage of monounsaturated and...Ch. 15.3 - Prob. 15.28PPCh. 15.4 - Identify each of the following processes as...Ch. 15.4 - Identify each of the following processes as...Ch. 15.4 - Prob. 15.31PPCh. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Prob. 15.33PPCh. 15.4 - Prob. 15.34PPCh. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Use condensed structural formulas to write the...Ch. 15.4 - Prob. 15.37PPCh. 15.4 - Draw the condensed structural formula for all the...Ch. 15.5 - Prob. 15.39PPCh. 15.5 - Prob. 15.40PPCh. 15.5 - Draw the condensed structural formula for the...Ch. 15.5 - Draw the condensed structural formula for the...Ch. 15.5 - Prob. 15.43PPCh. 15.5 - Prob. 15.44PPCh. 15.5 - Prob. 15.45PPCh. 15.5 - Prob. 15.46PPCh. 15.6 - Draw the structure for the steroid nucleus.Ch. 15.6 - Draw the structure for cholesterol.Ch. 15.6 - Prob. 15.49PPCh. 15.6 - Prob. 15.50PPCh. 15.6 - Prob. 15.51PPCh. 15.6 - Prob. 15.52PPCh. 15.6 - Prob. 15.53PPCh. 15.6 - Prob. 15.54PPCh. 15.6 - Prob. 15.55PPCh. 15.6 - What are the similarities and differences between...Ch. 15.6 - Prob. 15.57PPCh. 15.6 - Prob. 15.58PPCh. 15.7 - What is the function if the lipid by layer in a...Ch. 15.7 - Prob. 15.60PPCh. 15.7 - Prob. 15.61PPCh. 15.7 - How do the unsaturated fatty acids in the...Ch. 15.7 - Prob. 15.63PPCh. 15.7 - Prob. 15.64PPCh. 15.7 - Prob. 15.65PPCh. 15.7 - 15.66 Identify the type of transport described by...Ch. 15.7 - Identify the functional groups in Pravachol.Ch. 15.7 - Identify the functional groups in Tri Cor.Ch. 15.7 - Prob. 15.69PPCh. 15.7 - Prob. 15.70PPCh. 15 - Prob. 15.71UTCCh. 15 - Prob. 15.72UTCCh. 15 - Prob. 15.73UTCCh. 15 - Prob. 15.74UTCCh. 15 - Prob. 15.75APPCh. 15 - Prob. 15.76APPCh. 15 - Prob. 15.77APPCh. 15 - Prob. 15.78APPCh. 15 - Identify each of the following as a fatty acid,...Ch. 15 - Identify each of the following as a fatty acid,...Ch. 15 - 15.81 Identify the components (1 to 6 ) contained...Ch. 15 - Prob. 15.82APPCh. 15 - Which of the following are found in cell...Ch. 15 - Which of the following are found in cell...Ch. 15 - Draw the condensed structural formula for a...Ch. 15 - sunflower seed oil can be used to make margarine....Ch. 15 - Prob. 15.87CPCh. 15 - 15.87 Match the lipoprotein (1 to 4) with its...Ch. 15 - 15.89 A sink drain can become clogged with solid...Ch. 15 - 15.90 One of the triacylglycerols in olive oil is...Ch. 15 - 15.91 1.00 mole of glyceryl trioleate (triolein)...Ch. 15 - The plastic known as PETE...Ch. 15 - Using the Internet, look up the condensed...Ch. 15 - The insect repellent DEET is an amide that can be...Ch. 15 - Glyceryl trimyristate (trimyristin) is found in...Ch. 15 - Prob. 31CICh. 15 - Prob. 32CI
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