Chemistry with Access Code, Hybrid Edition
9th Edition
ISBN: 9781285188492
Author: Steven S. Zumdahl
Publisher: CENGAGE L
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Chapter 15, Problem 6RQ
Instead of the titration of a strong acid by a strong base considered in Question 5, consider the titration of a strong base by a strong acid. Compare and contrast a strong acid–strong base titration with a strong base–strong acid titration.
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Question 46
Which of the following staterments about titration curves is false?
O The equivalence point on a titration curve is the point where chemically equivalence amounts of acid and
base have reacted.
O The equivalence point will be basic when titrating a weak acid with a strong base.
O A titration curve shows how pH changes near the equivalence point.
A titration curve for titrating a strong acid/strong base will always have an equivalence point at pH - 7.0.
all are true
D
Question 47
In the reaction shown below, what species is oxidized?
2Nal + Brz → 2NaBr + 12
Or
O Br
O none of these
O Brz
Na"
In many titrations, you need to add an indicator that changes color when the titration is complete. The titration of sodium oxalate with
potassium permanganate does not use an indicator. However, a pink color does appear to signal the end of the titration.
What causes the color change signaling the completed titration of sodium oxalate with potassium permanganate?
Select one:
Carbon dioxide reacts with excess permanganate, creating a pink complex.
The last oxalate ion creates a pink precipitate when enough permanganate has been added.
The pink color of the reactant permanganate appears in solution after all of the oxalate has reacted.
The manganese product of the reaction has a pink color that only appears after stirring.
11
12
13
14
Questions 11-14 refer to the same strong base/strong acid (SB/SA) titration.
A 15.00 mL solution of 0.100 M sodium hydroxide (NaOH) is being titrated with 0.250 M hydrobromic acid (HBr). What is the solution pH before the titration begins? (Two
decimal places)
Type your answer...
Questions 11-14 refer to the same strong base/strong acid (SB/SA) titration.
A 15.00 mL solution of 0.100 M sodium hydroxide (NaOH) is being titrated with 0.250 M hydrobromic acid (HBr). What is the solution pH when 5.00 mL of HBr have been
added? (Two decimal places)
Type your answer...
Questions 11-14 refer to the same strong base/strong acid (SB/SA) titration.
A 15.00 mL solution of 0.100 M sodium hydroxide (NaOH) is being titrated with 0.250 M hydrobromic acid (HBr). What is the total solution volume (in mL) at the equivalence
point? (Nearest whole number)
Type your answer...
Questions 11-14 refer to the same strong base/strong acid (SB/SA) titration.
4
A 15.00 mL solution of 0.100 M sodium…
Chapter 15 Solutions
Chemistry with Access Code, Hybrid Edition
Ch. 15 - What is meant by the presence of a common ion? How...Ch. 15 - Define a buffer solution. What makes up a buffer...Ch. 15 - One of the most challenging parts of solving...Ch. 15 - A good buffer generally contains relatively equal...Ch. 15 - Draw the general titration curve for a strong acid...Ch. 15 - Instead of the titration of a strong acid by a...Ch. 15 - Sketch the titration curve for a weak acid...Ch. 15 - Sketch the titration curve for a weak base...Ch. 15 - What is an acidbase indicator? Define the...Ch. 15 - Why does an indicator change from its acid color...
Ch. 15 - What are the major species in solution after...Ch. 15 - A friend asks the following: Consider a buffered...Ch. 15 - Mixing together solutions of acetic acid and...Ch. 15 - Could a buffered solution be made by mixing...Ch. 15 - Sketch two pH curves, one for the titration of a...Ch. 15 - Sketch a pH curve for the titration of a weak acid...Ch. 15 - You have a solution of the weak acid HA and add...Ch. 15 - You have a solution of the weak acid HA and add...Ch. 15 - The common ion effect for weak acids is to...Ch. 15 - Prob. 10QCh. 15 - A best buffer has about equal quantities of weak...Ch. 15 - Consider the following pH curves for 100.0 mL of...Ch. 15 - An acid is titrated with NaOH. The following...Ch. 15 - Consider the following four titrations. i. 100.0...Ch. 15 - Figure 14-4 shows the pH curves for the titrations...Ch. 15 - Acidbase indicators mark the end point of...Ch. 15 - How many of the following are buffered solutions?...Ch. 15 - Which of the following can be classified as buffer...Ch. 15 - A certain buffer is made by dissolving NaHCO3 and...Ch. 15 - A buffer is prepared by dissolving HONH2 and...Ch. 15 - Calculate the pH of each of the following...Ch. 15 - Calculate the pH of each of the following...Ch. 15 - Compare the percent dissociation of the acid in...Ch. 15 - Compare the percent ionization of the base in...Ch. 15 - Calculate the pH after 0.020 mole of HCl is added...Ch. 15 - Calculate the pH after 0.020 mole of HCl is added...Ch. 15 - Calculate the pH after 0.020 mole of NaOH is added...Ch. 15 - Calculate the pH after 0.020 mole of NaOH is added...Ch. 15 - Which of the solutions in Exercise 21 shows the...Ch. 15 - Prob. 30ECh. 15 - Calculate the pH of a solution that is 1.00 M HNO2...Ch. 15 - Calculate the pH of a solution that is 0.60 M HF...Ch. 15 - Calculate the pH after 0.10 mole of NaOH is added...Ch. 15 - Calculate the pH after 0.10 mole of NaOH is added...Ch. 15 - Calculate the pH of each of the following buffered...Ch. 15 - Calculate the pH of each of the following buffered...Ch. 15 - Calculate the pH of a buffered solution prepared...Ch. 15 - A buffered solution is made by adding 50.0 g NH4Cl...Ch. 15 - Calculate the pH after 0.010 mole of gaseous HCl...Ch. 15 - An aqueous solution contains dissolved C6H5NH3Cl...Ch. 15 - Calculate the mass of sodium acetate that must be...Ch. 15 - What volumes of 0.50 M HNO2 and 0.50 M NaNO2 must...Ch. 15 - Consider a solution that contains both C5H5N and...Ch. 15 - Calculate the ratio [NH3]/[NH4+] in...Ch. 15 - Carbonate buffers are important in regulating the...Ch. 15 - When a person exercises, muscle contractions...Ch. 15 - Consider the acids in Table 13-2. Which acid would...Ch. 15 - Consider the bases in Table 13-3. Which base would...Ch. 15 - Calculate the pH of a solution that is 0.40 M...Ch. 15 - Calculate the pH of a solution that is 0.20 M HOCl...Ch. 15 - Which of the following mixtures would result in...Ch. 15 - Which of the following mixtures would result in a...Ch. 15 - What quantity (moles) of NaOH must be added to 1.0...Ch. 15 - Calculate the number of moles of HCl(g) that must...Ch. 15 - Consider the titration of a generic weak acid HA...Ch. 15 - Sketch the titration curve for the titration of a...Ch. 15 - Consider the titration of 40.0 mL of 0.200 M HClO4...Ch. 15 - Consider the titration of 80.0 mL of 0.100 M...Ch. 15 - Consider the titration of 100.0 mL of 0.200 M...Ch. 15 - Consider the titration of 100.0 mL of 0.100 M...Ch. 15 - Lactic acid is a common by-product of cellular...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Repeat the procedure in Exercise 61, but for the...Ch. 15 - Calculate the pH at the halfway point and at the...Ch. 15 - In the titration of 50.0 mL of 1.0 M methylamine,...Ch. 15 - You have 75.0 mL of 0.10 M HA. After adding 30.0...Ch. 15 - A student dissolves 0.0100 mole of an unknown weak...Ch. 15 - Two drops of indicator HIn (Ka = 1.0 109), where...Ch. 15 - Methyl red has the following structure: It...Ch. 15 - Potassium hydrogen phthalate, known as KHP (molar...Ch. 15 - A certain indicator HIn has a pKa of 3.00 and a...Ch. 15 - Which of the indicators in Fig. 14-8 could be used...Ch. 15 - Prob. 74ECh. 15 - Which of the indicators in Fig. 14-8 could be used...Ch. 15 - Prob. 76ECh. 15 - Estimate the pH of a solution in which bromcresol...Ch. 15 - Estimate the pH of a solution in which crystal...Ch. 15 - A solution has a pH of 7.0. What would be the...Ch. 15 - A solution has a pH of 4.5. What would be the...Ch. 15 - Derive an equation analogous to the...Ch. 15 - a. Calculate the pH of a buffered solution that is...Ch. 15 - Tris(hydroxymethyl)aminomethane, commonly called...Ch. 15 - You make 1.00 L of a buffered solution (pH = 4.00)...Ch. 15 - You have the following reagents on hand: Solids...Ch. 15 - Prob. 86AECh. 15 - Phosphate buffers are important in regulating the...Ch. 15 - What quantity (moles) of HCl(g) must be added to...Ch. 15 - Prob. 89AECh. 15 - The following plot shows the pH curves for the...Ch. 15 - Calculate the volume of 1.50 102 M NaOH that must...Ch. 15 - Prob. 92AECh. 15 - A certain acetic acid solution has pH = 2.68....Ch. 15 - A 0.210-g sample of an acid (molar mass = 192...Ch. 15 - The active ingredient in aspirin is...Ch. 15 - One method for determining the purity of aspirin...Ch. 15 - A student intends to titrate a solution of a weak...Ch. 15 - A student titrates an unknown weak acid, HA, to a...Ch. 15 - A sample of a certain monoprotic weak acid was...Ch. 15 - Consider 1.0 L of a solution that is 0.85 M HOC6H5...Ch. 15 - What concentration of NH4Cl is necessary to buffer...Ch. 15 - Consider the following acids and bases: HCO2H Ka =...Ch. 15 - Consider a buffered solution containing CH3NH3Cl...Ch. 15 - Consider the titration of 150.0 mL of 0.100 M HI...Ch. 15 - Consider the titration of 100.0 mL of 0.100 M HCN...Ch. 15 - Consider the titration of 100.0 mL of 0.200 M...Ch. 15 - Consider the following four titrations (iiv): i....Ch. 15 - Another way to treat data from a pH titration is...Ch. 15 - A buffer is made using 45.0 mL of 0.750 M HC3H5O2...Ch. 15 - A 0.400-M solution of ammonia was titrated with...Ch. 15 - What volume of 0.0100 M NaOH must be added to 1.00...Ch. 15 - Consider a solution formed by mixing 50.0 mL of...Ch. 15 - When a diprotic acid. H2A. is titrated with NaOH,...Ch. 15 - Prob. 114CPCh. 15 - The titration of Na2CO3 with HCl bas the following...Ch. 15 - Consider the titration curve in Exercise 115 for...Ch. 15 - A few drops of each of the indicators shown in the...Ch. 15 - Malonic acid (HO2CCH2CO2H) is a diprotic acid. In...Ch. 15 - A buffer solution is prepared by mixing 75.0 mL of...Ch. 15 - A 10.00-g sample of the ionic compound NaA, where...Ch. 15 - Calculate the pH of a solution prepared by mixing...Ch. 15 - Consider a solution prepared by mixing the...
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- Consider the nanoscale-level representations for Question 110 of the titration of the aqueous weak acid HX with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: After a very small volume of titrant has been added to the initial HX solution? When enough titrant has been added to take the solution just past the equivalence point? Halfway to the equivalence point? At the equivalence point? Nanoscale representations for Question 110.arrow_forwardConsider the nanoscale-level representations for Question 111 of the titration of the aqueous strong acid HA with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: (a) After a very small volume of titrant has been added to the initial HA solution? (b) Halfway to the equivalence point? (c) When enough titrant has been added to take the solution just past the equivalence point? (d) At the equivalence point? Nanoscale representations for Question 111.arrow_forwardThree students titrate different samples of the same solution of HCI to obtain its molarity. Below are their data. Student A: 20.00mLHCl+20.00mLH2O 0.100 M NaOH used to titrate to the equivalence point Student B: 20.00mLHCl+40.00mLH2O 0.100 M NaOH used to titrate to the equivalence point Student C: 20.00mLHCl+20.00mLH2O 0.100 M Ba(OH)2 used to titrate to the equivalence point. All the students calculated the molarities correctly. Which (if any) of the following statements are true? (a) The molarity calculated by A is half that calculated by B. (b) The molarity calculated by A is equal to that calculated by C. (c) The molarity calculated by B is twice that calculated by C. (d) The molarity calculated by A is twice that calculated by B. (e) The molarity calculated by A is equal to that calculated by B.arrow_forward
- Briefly describe how a buffer solution can control the pH of a solution when strong acid is added and when strong base is added. Use NH3/NH4Cl as an example of a buffer and HCl and NaOH as the strong acid and strong base.arrow_forwardThe three flasks shown below depict the titration of an aqueous NaOH solution with HCl at different points. One represents the titration prior to the equivalence point, another represents the titration at the equivalence point, and the other represents the titration past the equivalence point. (Sodium ions and solvent water molecules have been omitted for clarity.) a Write the balanced chemical equation for the titration. b Label each of the beakers shown to indicate which point in the titration they represent. c For each solution, indicate whether you expect it to be acidic, basic, or neutral.arrow_forwardFollow the directions of Question 64. Consider two beakers: Beaker A has a weak acid(K a=1105). Beaker B has HCI. The volume and molarity of each acid in the beakers are the same. Both acids are to be titrated with a 0.1 M solution of NaOH. (a) Before titration starts (at zero time), the pH of the solution in Beaker A is the pH of the solution in Beaker B. (b) At half-neutralization (halfway to the equivalence point), the pH of the solution in Beaker A the pH of the solution in Beaker B. (c) When each solution has reached its equivalence point, the pH of the solution in Beaker A the pH of the solution in Beaker B. (d) At the equivalence point, the volume of NaOH used to titrate HCI in Beaker B the volume of NaOH used to titrate the weak acid in Beaker A.arrow_forward
- Consider the following two acids: In two separate experiments the pH was measured during the titration of 5.00 mmol of each acid with 0.200 M NaOH. Each experiment showed only one stoichiometric point when the data were plotted. In one experiment the stoichiometric point was at 25.00 mL added NaOH, and in the other experiment the stoichiometric point was at 50.00 mL NaOH. Explain these results. (See Exercise 113.)arrow_forwardWhat is the pH of a buffer that is 0.150 M in a weak acid and 0.150 M in the acids conjugate base? The acids ionization constant is 6.8 106.arrow_forwardConsider all acid-base indicators discussed in this chapter. Which of these indicators would be suitable for the titration of each of these? (a) NaOH with HClO4 (b) acetic acid with KOH (c) NH3 solution with HBr (d) KOH with HNO3 Explain your choices.arrow_forward
- Identify each pair that could form a buffer. (a) NaOH and NaCl (b) NaOH and NH3 (c) Na3PO4 and Na2HPO4arrow_forwardExplain why even though an aqueous acetic acid solution contains acetic acid and acetate ions, it cannot be a buffer.arrow_forwardConsider the titration of HF (K a=6.7104) with NaOH. What is the pH when a third of the acid has been neutralized?arrow_forward
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