Concept explainers
(a)
Interpretation:
To predict the compound formed by the reaction of phosgene with given compound.
Concept introduction:
Carbonyl carbon of phosgene is highly polar in nature because of the presence of electronegative groups attached to it. So phosgene will undergo nucleophilic addition-eliminationreaction. Tetrahedral intermediate is formed when nucleophile is added to the carbonyl carbon of phosgene. The tetrahedral intermediate is unstable therefore chloride ion gets eliminated. The acyl chloride reacts with neutral nucleophile by the following mechanism:
(b)
Interpretation:
To predict the compound formed by the reaction of phosgene with given compound.
Concept introduction:
Carbonyl carbon of phosgene is highly polar in nature because of the presence of electronegative groups attached to it. So phosgene will undergo nucleophilic addition-eliminationreaction. Tetrahedral intermediate is formed when nucleophile is added to the carbonyl carbon of phosgene. The tetrahedral intermediate is unstable therefore chloride ion gets eliminated. The acyl chloride reacts with neutral nucleophile by the following mechanism:
(c)
Interpretation:
To predict the compound formed by the reaction of phosgene with given compound.
Concept introduction:
Carbonyl carbon of phosgene is highly polar in nature because of the presence of electronegative groups attached to it. So phosgene will undergo nucleophilic addition-eliminationreaction. Tetrahedral intermediate is formed when nucleophile is added to the carbonyl carbon of phosgene. The tetrahedral intermediate is unstable therefore chloride ion gets eliminated. The acyl chloride reacts with neutral nucleophile by the following mechanism:
(d)
Interpretation:
To predict the compound formed by the reaction of phosgene with given compound.
Concept introduction:
Carbonyl carbon of phosgene is highly polar in nature because of the presence of electronegative groups attached to it. So phosgene will undergo nucleophilic addition-eliminationreaction. Tetrahedral intermediate is formed when nucleophile is added to the carbonyl carbon of phosgene. The tetrahedral intermediate is unstable therefore chloride ion gets eliminated. The acyl chloride reacts with neutral nucleophile by the following mechanism:
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Student's Study Guide and Solutions Manual for Organic Chemistry
- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Select to Edit Arrows H H Select to Add Arrows > H CFCI: Select to Edit Arrows H Select to Edit Arrowsarrow_forwardShow work with explanation needed. don't give Ai generated solutionarrow_forwardShow work. don't give Ai generated solutionarrow_forward
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