Introductory Chemistry, Books a la Carte Edition (6th Edition)
6th Edition
ISBN: 9780134564074
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 15, Problem 5SAQ
Consider the reaction between NO and
a. 11
b. 4.3
c. 6.4
d. 0.22
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO2 (g) = N2O4(g)
AGº = -5.4 kJ
Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system:
Under these conditions, will the pressure of N2O4 tend to rise or fall?
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
'2'
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
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rise
☐ x10
fall
yes
no
☐ atm
G
Ar
1
Why do we analyse salt?
Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
H
H
CH3OH, H+
H
Select to Add Arrows
H°
0:0
'H
+
Q
HH
■ Select to Add Arrows
CH3OH,
H*
H.
H
CH3OH, H+
HH
■ Select to Add Arrows i
Please select a drawing or reagent from the question area
Chapter 15 Solutions
Introductory Chemistry, Books a la Carte Edition (6th Edition)
Ch. 15 - Q1. Which change is likely to increase the rate of...Ch. 15 - The equilibrium constants at a fixed temperature...Ch. 15 - Q3. The concentrations of A,B, and C for the...Ch. 15 - Q4. What is the correct expression for the...Ch. 15 - Q5. Consider the reaction between NO and to form...Ch. 15 - Q6. The equilibrium constant for this reaction is...Ch. 15 - Prob. 7SAQCh. 15 - Q8. The decomposition of is endothermic.
Which...Ch. 15 - Prob. 9SAQCh. 15 - Prob. 10SAQ
Ch. 15 - Prob. 1ECh. 15 - Prob. 2ECh. 15 - 3. Why do chemists seek to control reaction...Ch. 15 - How do most chemical reactions occur?Ch. 15 - What factors influence reaction rates? How?Ch. 15 - Prob. 6ECh. 15 - 7. What is dynamic chemical equilibrium?
Ch. 15 - Prob. 8ECh. 15 - Explain why the concentrations of reactants and...Ch. 15 - Devise your own analogylike the Narnia and Middle...Ch. 15 - Prob. 11ECh. 15 - Write the expression for the equilibrium constant...Ch. 15 - What does a small equilibrium constant tell you...Ch. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Prob. 16ECh. 15 - Prob. 17ECh. 15 - Prob. 18ECh. 15 - What is the effect of decreasing the concentration...Ch. 15 - Prob. 20ECh. 15 - Prob. 21ECh. 15 - What is the effect of increasing the pressure of a...Ch. 15 - Prob. 23ECh. 15 - Prob. 24ECh. 15 - 25. What is the effect of decreasing the pressure...Ch. 15 - 26. What is the effect of increasing the...Ch. 15 - 27. What is the effect of increasing the...Ch. 15 - Prob. 28ECh. 15 - Prob. 29ECh. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - Prob. 33ECh. 15 - Prob. 34ECh. 15 - Does a catalyst affect the value of the...Ch. 15 - Prob. 36ECh. 15 - Prob. 37ECh. 15 - Prob. 38ECh. 15 - The body temperature of cold-blooded animals...Ch. 15 - The rate of a particular reaction doubles when the...Ch. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Prob. 44ECh. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Prob. 47ECh. 15 - Prob. 48ECh. 15 - 49. For each equilibrium constant, indicate if you...Ch. 15 - Prob. 50ECh. 15 - Prob. 51ECh. 15 - 52. Consider the reaction.
An equilibrium mixture...Ch. 15 - Consider the reaction. 2H2S(g)2H2(g)+S2(g) An...Ch. 15 - Prob. 54ECh. 15 - Prob. 55ECh. 15 - Consider the reaction. CaCO3(s)CaCO(s)+CO2(g) An...Ch. 15 - Prob. 57ECh. 15 - Prob. 58ECh. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - Prob. 61ECh. 15 - Prob. 62ECh. 15 - Consider this reaction at equilibrium....Ch. 15 - Prob. 64ECh. 15 - Consider this reaction at equilibrium....Ch. 15 - Prob. 66ECh. 15 - Consider the effect of a volume change on this...Ch. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - Prob. 70ECh. 15 - Prob. 71ECh. 15 - Prob. 72ECh. 15 - Prob. 73ECh. 15 - Prob. 74ECh. 15 - Coal, which is primarily carbon, can be converted...Ch. 15 - 76. Coal can be used to generate hydrogen gas (a...Ch. 15 - 77. For each compound, write an equation showing...Ch. 15 - Prob. 78ECh. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - A saturated solution of MgF2 has [Mg2+]=2.6104M...Ch. 15 - Prob. 82ECh. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - Prob. 85ECh. 15 - Prob. 86ECh. 15 - Prob. 87ECh. 15 - 88. Calculate the molar solubility of .
Ch. 15 - Prob. 89ECh. 15 - Prob. 90ECh. 15 - 91. Consider the reaction.
A solution is made...Ch. 15 - Prob. 92ECh. 15 - Prob. 93ECh. 15 - Prob. 94ECh. 15 - This reaction is exothermic....Ch. 15 - Prob. 96ECh. 15 - 97. Calculate the molar solubility of CuS. How...Ch. 15 - Calculate the molar solubility of FeCO3. How many...Ch. 15 - Prob. 99ECh. 15 - Prob. 100ECh. 15 - Prob. 101ECh. 15 - Prob. 102ECh. 15 - Consider the reaction: CaCO3CaO(s)+CO2(g) A sample...Ch. 15 - Prob. 104ECh. 15 - A 2.55-L solution is 0.115 M in Mg2+. If K2CO3 is...Ch. 15 - Prob. 106ECh. 15 - Prob. 107ECh. 15 - Prob. 108ECh. 15 - One of the main components of hard water is CaCO3....Ch. 15 - Prob. 110ECh. 15 - The reaction A(g)+B(g)2C(g) has an equilibrium...Ch. 15 - Describe three ways a reaction at equilibrium can...Ch. 15 - Solid CaCO3 decomposes into solid CaO and gaseous...
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