Introductory Chemistry, Books a la Carte Edition (6th Edition)
6th Edition
ISBN: 9780134564074
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 15, Problem 24E
Interpretation Introduction
Interpretation: The effect of decrease in pressure of a reaction mixture at equilibrium is to be explained if the reactant side has less number of moles of gas particles than the product side.
Concept Introduction: Le Chatelier’s principle states that every
On decreasing the pressure, the equilibrium shifts in the direction where the concentration is more.
If the reactant side has less number of moles of gas particles than the product side then the equilibrium will shift in forward direction.
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
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1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 15 Solutions
Introductory Chemistry, Books a la Carte Edition (6th Edition)
Ch. 15 - Q1. Which change is likely to increase the rate of...Ch. 15 - The equilibrium constants at a fixed temperature...Ch. 15 - Q3. The concentrations of A,B, and C for the...Ch. 15 - Q4. What is the correct expression for the...Ch. 15 - Q5. Consider the reaction between NO and to form...Ch. 15 - Q6. The equilibrium constant for this reaction is...Ch. 15 - Prob. 7SAQCh. 15 - Q8. The decomposition of is endothermic.
Which...Ch. 15 - Prob. 9SAQCh. 15 - Prob. 10SAQ
Ch. 15 - Prob. 1ECh. 15 - Prob. 2ECh. 15 - 3. Why do chemists seek to control reaction...Ch. 15 - How do most chemical reactions occur?Ch. 15 - What factors influence reaction rates? How?Ch. 15 - Prob. 6ECh. 15 - 7. What is dynamic chemical equilibrium?
Ch. 15 - Prob. 8ECh. 15 - Explain why the concentrations of reactants and...Ch. 15 - Devise your own analogylike the Narnia and Middle...Ch. 15 - Prob. 11ECh. 15 - Write the expression for the equilibrium constant...Ch. 15 - What does a small equilibrium constant tell you...Ch. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Prob. 16ECh. 15 - Prob. 17ECh. 15 - Prob. 18ECh. 15 - What is the effect of decreasing the concentration...Ch. 15 - Prob. 20ECh. 15 - Prob. 21ECh. 15 - What is the effect of increasing the pressure of a...Ch. 15 - Prob. 23ECh. 15 - Prob. 24ECh. 15 - 25. What is the effect of decreasing the pressure...Ch. 15 - 26. What is the effect of increasing the...Ch. 15 - 27. What is the effect of increasing the...Ch. 15 - Prob. 28ECh. 15 - Prob. 29ECh. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - Prob. 33ECh. 15 - Prob. 34ECh. 15 - Does a catalyst affect the value of the...Ch. 15 - Prob. 36ECh. 15 - Prob. 37ECh. 15 - Prob. 38ECh. 15 - The body temperature of cold-blooded animals...Ch. 15 - The rate of a particular reaction doubles when the...Ch. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Prob. 44ECh. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Write an equilibrium expression for each chemical...Ch. 15 - Prob. 47ECh. 15 - Prob. 48ECh. 15 - 49. For each equilibrium constant, indicate if you...Ch. 15 - Prob. 50ECh. 15 - Prob. 51ECh. 15 - 52. Consider the reaction.
An equilibrium mixture...Ch. 15 - Consider the reaction. 2H2S(g)2H2(g)+S2(g) An...Ch. 15 - Prob. 54ECh. 15 - Prob. 55ECh. 15 - Consider the reaction. CaCO3(s)CaCO(s)+CO2(g) An...Ch. 15 - Prob. 57ECh. 15 - Prob. 58ECh. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - Prob. 61ECh. 15 - Prob. 62ECh. 15 - Consider this reaction at equilibrium....Ch. 15 - Prob. 64ECh. 15 - Consider this reaction at equilibrium....Ch. 15 - Prob. 66ECh. 15 - Consider the effect of a volume change on this...Ch. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - Prob. 70ECh. 15 - Prob. 71ECh. 15 - Prob. 72ECh. 15 - Prob. 73ECh. 15 - Prob. 74ECh. 15 - Coal, which is primarily carbon, can be converted...Ch. 15 - 76. Coal can be used to generate hydrogen gas (a...Ch. 15 - 77. For each compound, write an equation showing...Ch. 15 - Prob. 78ECh. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - A saturated solution of MgF2 has [Mg2+]=2.6104M...Ch. 15 - Prob. 82ECh. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - Prob. 85ECh. 15 - Prob. 86ECh. 15 - Prob. 87ECh. 15 - 88. Calculate the molar solubility of .
Ch. 15 - Prob. 89ECh. 15 - Prob. 90ECh. 15 - 91. Consider the reaction.
A solution is made...Ch. 15 - Prob. 92ECh. 15 - Prob. 93ECh. 15 - Prob. 94ECh. 15 - This reaction is exothermic....Ch. 15 - Prob. 96ECh. 15 - 97. Calculate the molar solubility of CuS. How...Ch. 15 - Calculate the molar solubility of FeCO3. How many...Ch. 15 - Prob. 99ECh. 15 - Prob. 100ECh. 15 - Prob. 101ECh. 15 - Prob. 102ECh. 15 - Consider the reaction: CaCO3CaO(s)+CO2(g) A sample...Ch. 15 - Prob. 104ECh. 15 - A 2.55-L solution is 0.115 M in Mg2+. If K2CO3 is...Ch. 15 - Prob. 106ECh. 15 - Prob. 107ECh. 15 - Prob. 108ECh. 15 - One of the main components of hard water is CaCO3....Ch. 15 - Prob. 110ECh. 15 - The reaction A(g)+B(g)2C(g) has an equilibrium...Ch. 15 - Describe three ways a reaction at equilibrium can...Ch. 15 - Solid CaCO3 decomposes into solid CaO and gaseous...
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