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Chapter 15, Problem 56E
Interpretation Introduction

To determine: Equilibrium concentrations of CO, H2O, H2, and CO2.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
1. Sodium azide (NaN3) is the primary chemical substance used in automobile air bags. Upon impact, the decomposition of sodium azide is initiated to produce sodium metal and nitrogen gas which then inflates the bag. How many liters of nitrogen gas are produced at 1.15 atm and 30.0°C when 145.0 grams of sodium azide decomposes? 2. Calcium carbonate (such as that in limestone) reacts with aqueous hydrochloric acid to produce carbon dioxide, aqueous calcium chloride and water. How many liters of carbon dioxide are produced at 20°C and 745 torr when 3.583 grams of calcium carbonate is dissolved in solution containing 1.550 grams of hydrochloric acid?
Show all work (where appropriate) for full credit. 1. Describe (steps, equipment and quantities) how to accurately prepare 250.0 mL of a 0.0075 M solution of NaCl (aq) from a 500 mL, 0.0500 M stock solution. 2. Describe (steps, equipment and quantities) how to accurately prepare 250.0 mL of a 0.0075 M solution of NaCl (aq) from 100 g of solid NaCl.

Chapter 15 Solutions

Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)

Ch. 15 - Prob. 11SAQCh. 15 - Prob. 12SAQCh. 15 - 1. How does a developing fetus get oxygen in the...Ch. 15 - Prob. 2ECh. 15 - Prob. 3ECh. 15 - Prob. 4ECh. 15 - Prob. 5ECh. 15 - Prob. 6ECh. 15 - Prob. 7ECh. 15 - Prob. 8ECh. 15 - Prob. 9ECh. 15 - Prob. 10ECh. 15 - Prob. 11ECh. 15 - Prob. 12ECh. 15 - Prob. 13ECh. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Prob. 16ECh. 15 - Prob. 17ECh. 15 - Prob. 18ECh. 15 - Prob. 19ECh. 15 - Prob. 20ECh. 15 - Prob. 21ECh. 15 - Prob. 22ECh. 15 - 23. When this reaction comes to equilibrium, will...Ch. 15 - Prob. 24ECh. 15 - 25. H2 and I2 are combined in a flask and allowed...Ch. 15 - Prob. 26ECh. 15 - Prob. 27ECh. 15 - 28. This reaction has an equilibrium constant of...Ch. 15 - 29. Consider the reactions and their respective...Ch. 15 - 30. Use the reactions and their equilibrium...Ch. 15 - Prob. 31ECh. 15 - 32. Calculate Kp for each reaction. a. N2O4(g) 2...Ch. 15 - 33. Write an equilibrium expression for each...Ch. 15 - 34. Find and fix the mistake in the equilibrium...Ch. 15 - Prob. 35ECh. 15 - Prob. 36ECh. 15 - 37. Consider the reaction: N2(g) + 3 H2(g) 2...Ch. 15 - 38. Consider the following reaction: H2(g) + I2(g)...Ch. 15 - 39. Consider the reaction: 2 NO(g) + Br2(g) 2...Ch. 15 - 40. Consider the reaction: SO2Cl2(g) SO2(g) +...Ch. 15 - 41. For the reaction A(g) 2 B(g), a reaction...Ch. 15 - Prob. 42ECh. 15 - 43. Consider the reaction: Fe3+(aq) + SCN–(aq) ...Ch. 15 - 44. Consider the reaction: SO2Cl2(g) SO2(g) +...Ch. 15 - 45. Consider the reaction: H2(g) + I2(g) 2...Ch. 15 - 46. Consider the reaction: CO(g) + 2 H2(g) ...Ch. 15 - 47. Consider the reaction: NH4HS(s) NH3(g) +...Ch. 15 - 48. Consider the reaction: 2 H2S(g) 2 H2(g) +...Ch. 15 - 49. Silver sulfate dissolves in water according to...Ch. 15 - 50. Nitrogen dioxide dimerizes according to the...Ch. 15 - 51. Consider the reaction and the associated...Ch. 15 - 52. Consider the reaction and the associated...Ch. 15 - 53. For the reaction shown here, Kc = 0.513 at 500...Ch. 15 - 54. For the reaction shown here, Kc = 255 at 1000...Ch. 15 - 55. Consider the reaction: NiO(s) + CO(g) Ni(s) +...Ch. 15 - 56. Consider the reaction: CO(g) + H2O(g) CO2(g)...Ch. 15 - 57. Consider the reaction: HC2H3O2(aq) + H2O(l) ...Ch. 15 - 58. Consider the reaction: SO2Cl2(g) SO2(g) +...Ch. 15 - 59. Consider the reaction: Br2(g) + Cl2(g) 2...Ch. 15 - 60. Consider the reaction: CO(g) + H2O(g) CO2(g)...Ch. 15 - Prob. 61ECh. 15 - Prob. 62ECh. 15 - Prob. 63ECh. 15 - 64. Consider this reaction at equilibrium: 2...Ch. 15 - 65. Consider this reaction at equilibrium: 2...Ch. 15 - 66. Consider this reaction at equilibrium: C(s) +...Ch. 15 - 67. Each reaction is allowed to come to...Ch. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - Prob. 70ECh. 15 - Prob. 71ECh. 15 - Prob. 72ECh. 15 - 73. Carbon monoxide replaces oxygen in oxygenated...Ch. 15 - Prob. 74ECh. 15 - Prob. 75ECh. 15 - 76. A mixture of water and graphite is heated to...Ch. 15 - Prob. 77ECh. 15 - 78. A system at equilibrium contains I2(g) at a...Ch. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - Prob. 81ECh. 15 - Prob. 82ECh. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - 85. The system described by the reaction: CO(g) +...Ch. 15 - Prob. 86ECh. 15 - 87. At 70 K, CCl4 decomposes to carbon and...Ch. 15 - Prob. 88ECh. 15 - 89. A sample of CaCO3(s) is introduced into a...Ch. 15 - Prob. 90ECh. 15 - Prob. 91ECh. 15 - Prob. 92ECh. 15 - Prob. 93ECh. 15 - Prob. 94ECh. 15 - Prob. 95ECh. 15 - Prob. 96ECh. 15 - Prob. 97ECh. 15 - Prob. 98ECh. 15 - 99. A sample of SO3 is introduced into an...Ch. 15 - 100. A reaction A(g) B(g) has an equilibrium...Ch. 15 - Prob. 101ECh. 15 - Prob. 102ECh. 15 - Prob. 103ECh. 15 - Prob. 104ECh. 15 - Prob. 105ECh. 15 - Prob. 106QGWCh. 15 - Prob. 107QGWCh. 15 - Prob. 108QGWCh. 15 - Prob. 109QGWCh. 15 - Prob. 110QGWCh. 15 - Prob. 111DIA
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