Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134112831
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 15, Problem 4E
Interpretation Introduction
To explain: The significance of the equilibrium constant.
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Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
Chapter 15 Solutions
Chemistry: A Molecular Approach (4th Edition)
Ch. 15 - Prob. 1SAQCh. 15 - Q2. The equilibrium constant for the reaction...Ch. 15 - Q3. Use the data shown here to find the...Ch. 15 - Prob. 4SAQCh. 15 - Prob. 5SAQCh. 15 - Q6. For the reaction 2 A(g) B(g), the equilibrium...Ch. 15 - Q7. Consider the reaction between iodine gas and...Ch. 15 - Prob. 8SAQCh. 15 - Prob. 9SAQCh. 15 - Prob. 10SAQ
Ch. 15 - Prob. 11SAQCh. 15 - Prob. 12SAQCh. 15 - 1. How does a developing fetus get oxygen in the...Ch. 15 - Prob. 2ECh. 15 - Prob. 3ECh. 15 - Prob. 4ECh. 15 - Prob. 5ECh. 15 - Prob. 6ECh. 15 - Prob. 7ECh. 15 - Prob. 8ECh. 15 - Prob. 9ECh. 15 - Prob. 10ECh. 15 - Prob. 11ECh. 15 - Prob. 12ECh. 15 - Prob. 13ECh. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Prob. 16ECh. 15 - Prob. 17ECh. 15 - Prob. 18ECh. 15 - Prob. 19ECh. 15 - Prob. 20ECh. 15 - Prob. 21ECh. 15 - Prob. 22ECh. 15 - 23. When this reaction comes to equilibrium, will...Ch. 15 - Prob. 24ECh. 15 - 25. H2 and I2 are combined in a flask and allowed...Ch. 15 - Prob. 26ECh. 15 - Prob. 27ECh. 15 - 28. This reaction has an equilibrium constant of...Ch. 15 - 29. Consider the reactions and their respective...Ch. 15 - 30. Use the reactions and their equilibrium...Ch. 15 - Prob. 31ECh. 15 - 32. Calculate Kp for each reaction.
a. N2O4(g) 2...Ch. 15 - 33. Write an equilibrium expression for each...Ch. 15 - 34. Find and fix the mistake in the equilibrium...Ch. 15 - Prob. 35ECh. 15 - Prob. 36ECh. 15 - 37. Consider the reaction:
N2(g) + 3 H2(g) 2...Ch. 15 - 38. Consider the following reaction:
H2(g) + I2(g)...Ch. 15 - 39. Consider the reaction:
2 NO(g) + Br2(g) 2...Ch. 15 - 40. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 15 - 41. For the reaction A(g) 2 B(g), a reaction...Ch. 15 - Prob. 42ECh. 15 - 43. Consider the reaction:
Fe3+(aq) + SCN–(aq) ...Ch. 15 - 44. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 15 - 45. Consider the reaction:
H2(g) + I2(g) 2...Ch. 15 - 46. Consider the reaction:
CO(g) + 2 H2(g) ...Ch. 15 - 47. Consider the reaction:
NH4HS(s) NH3(g) +...Ch. 15 - 48. Consider the reaction:
2 H2S(g) 2 H2(g) +...Ch. 15 - 49. Silver sulfate dissolves in water according to...Ch. 15 - 50. Nitrogen dioxide dimerizes according to the...Ch. 15 - 51. Consider the reaction and the associated...Ch. 15 - 52. Consider the reaction and the associated...Ch. 15 - 53. For the reaction shown here, Kc = 0.513 at 500...Ch. 15 - 54. For the reaction shown here, Kc = 255 at 1000...Ch. 15 - 55. Consider the reaction:
NiO(s) + CO(g) Ni(s) +...Ch. 15 - 56. Consider the reaction:
CO(g) + H2O(g) CO2(g)...Ch. 15 - 57. Consider the reaction:
HC2H3O2(aq) + H2O(l) ...Ch. 15 - 58. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 15 - 59. Consider the reaction:
Br2(g) + Cl2(g) 2...Ch. 15 - 60. Consider the reaction:
CO(g) + H2O(g) CO2(g)...Ch. 15 - Prob. 61ECh. 15 - Prob. 62ECh. 15 - Prob. 63ECh. 15 - 64. Consider this reaction at equilibrium:
2...Ch. 15 - 65. Consider this reaction at equilibrium:
2...Ch. 15 - 66. Consider this reaction at equilibrium:
C(s) +...Ch. 15 - 67. Each reaction is allowed to come to...Ch. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - Prob. 70ECh. 15 - Prob. 71ECh. 15 - Prob. 72ECh. 15 - 73. Carbon monoxide replaces oxygen in oxygenated...Ch. 15 - Prob. 74ECh. 15 - Prob. 75ECh. 15 - 76. A mixture of water and graphite is heated to...Ch. 15 - Prob. 77ECh. 15 - 78. A system at equilibrium contains I2(g) at a...Ch. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - Prob. 81ECh. 15 - Prob. 82ECh. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - 85. The system described by the reaction: CO(g) +...Ch. 15 - Prob. 86ECh. 15 - 87. At 70 K, CCl4 decomposes to carbon and...Ch. 15 - Prob. 88ECh. 15 - 89. A sample of CaCO3(s) is introduced into a...Ch. 15 - Prob. 90ECh. 15 - Prob. 91ECh. 15 - Prob. 92ECh. 15 - Prob. 93ECh. 15 - Prob. 94ECh. 15 - Prob. 95ECh. 15 - Prob. 96ECh. 15 - Prob. 97ECh. 15 - Prob. 98ECh. 15 - 99. A sample of SO3 is introduced into an...Ch. 15 - 100. A reaction A(g) B(g) has an equilibrium...Ch. 15 - Prob. 101ECh. 15 - Prob. 102ECh. 15 - Prob. 103ECh. 15 - Prob. 104ECh. 15 - Prob. 105ECh. 15 - Prob. 106QGWCh. 15 - Prob. 107QGWCh. 15 - Prob. 108QGWCh. 15 - Prob. 109QGWCh. 15 - Prob. 110QGWCh. 15 - Prob. 111DIA
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