Chemistry For Changing Times (14th Edition)
14th Edition
ISBN: 9780321972026
Author: John W. Hill, Terry W. McCreary
Publisher: PEARSON
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Question
Chapter 15, Problem 37P
Interpretation Introduction
Interpretation: Advantages and disadvantages of petroleum as a fuel should be determined.
Concept introduction: Fossils are the remains of the pre-historic animals or plants buried under the earth. Petroleum is known as fossil fuel because they were formed by the decomposition of the remains of the pre-historic plants and animals buried under the earth. Petroleum is dark colored viscous and foul smelling crude oil is a complex mixture of several solids, liquids and gaseous hydrocarbon mixed with water, salt and earth particles.
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 15 Solutions
Chemistry For Changing Times (14th Edition)
Ch. 15 - Prob. 1RQCh. 15 - Prob. 2RQCh. 15 - Prob. 3RQCh. 15 - Prob. 4RQCh. 15 - Prob. 5PCh. 15 - Prob. 6PCh. 15 - Prob. 7PCh. 15 - Prob. 8PCh. 15 - Prob. 9PCh. 15 - Prob. 10P
Ch. 15 - Prob. 11PCh. 15 - Prob. 12PCh. 15 - Prob. 13PCh. 15 - Prob. 14PCh. 15 - Prob. 15PCh. 15 - Prob. 16PCh. 15 - Prob. 17PCh. 15 - Prob. 18PCh. 15 - Prob. 19PCh. 15 - Prob. 20PCh. 15 - Prob. 21PCh. 15 - Prob. 22PCh. 15 - Prob. 23PCh. 15 - Prob. 24PCh. 15 - Prob. 25PCh. 15 - Prob. 26PCh. 15 - Which has higher entropy, potassium in solid...Ch. 15 - Prob. 28PCh. 15 - Prob. 29PCh. 15 - Prob. 30PCh. 15 - Prob. 31PCh. 15 - Prob. 32PCh. 15 - Prob. 33PCh. 15 - Prob. 34PCh. 15 - Prob. 35PCh. 15 - Prob. 36PCh. 15 - Prob. 37PCh. 15 - Prob. 38PCh. 15 - Prob. 39PCh. 15 - Prob. 40PCh. 15 - Prob. 41PCh. 15 - Prob. 42PCh. 15 - Prob. 43PCh. 15 - Prob. 44PCh. 15 - Prob. 45PCh. 15 - Prob. 46PCh. 15 - Prob. 47PCh. 15 - Prob. 48PCh. 15 - Prob. 49PCh. 15 - Prob. 50PCh. 15 - Prob. 51PCh. 15 - Prob. 52PCh. 15 - Prob. 53PCh. 15 - Prob. 54PCh. 15 - Prob. 55PCh. 15 - Prob. 56PCh. 15 - Prob. 57PCh. 15 - What are some problems associated with the use of...Ch. 15 - Prob. 59PCh. 15 - Prob. 60PCh. 15 - Prob. 61PCh. 15 - Prob. 62PCh. 15 - Prob. 63PCh. 15 - Prob. 64PCh. 15 - Prob. 65PCh. 15 - Prob. 66APCh. 15 - Prob. 67APCh. 15 - Prob. 68APCh. 15 - Prob. 69APCh. 15 - Prob. 70APCh. 15 - Both a banana and a hand grenade have about 170...Ch. 15 - Prob. 72APCh. 15 - Prob. 73APCh. 15 - Prob. 74APCh. 15 - Prob. 75APCh. 15 - Prob. 76APCh. 15 - Prob. 77APCh. 15 - Prob. 78APCh. 15 - Production of gasoline from tar sands requires...Ch. 15 - Prob. 80APCh. 15 - Prob. 15.1CTECh. 15 - Prob. 15.2CTECh. 15 - Prob. 15.3CTECh. 15 - Prob. 15.4CTECh. 15 - Prob. 15.5CTECh. 15 - Prob. 15.6CTECh. 15 - Prob. 1CGPCh. 15 - Prepare a PowerPoint, poster, or other...Ch. 15 - Prob. 3CGPCh. 15 - Prob. 4CGPCh. 15 - Prob. 5CGPCh. 15 - Prob. 6CGPCh. 15 - Prob. 7CGPCh. 15 - Prob. 8CGPCh. 15 - Prob. 9CGPCh. 15 - Prob. 1CHQCh. 15 - Prob. 2CHQCh. 15 - Prob. 3CHQCh. 15 - Prob. 4CHQCh. 15 - Prob. 5CHQ
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