
Chemistry: The Central Science, Books a la Carte Edition & Modified Mastering Chemistry with Pearson eText -- ValuePack Access Card Package
1st Edition
ISBN: 9780133910919
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 15, Problem 15E
(a)
Interpretation Introduction
To determine: The possible values of
(b)
Interpretation Introduction
To determine: The possible values of
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 15 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Modified Mastering Chemistry with Pearson eText -- ValuePack Access Card Package
Ch. 15.2 - Molybdenum metal must absorb radiation with a...Ch. 15.2 - Titanium metal requires a photon with a minimum...Ch. 15.2 - Prob. 15.2.1PECh. 15.2 - Classify each of the following statements as...Ch. 15.3 - Prob. 15.3.1PECh. 15.3 -
6 38 Indicate whether energy is emitted or...Ch. 15.3 - Using Equation 6.5. calculate the energy of an...Ch. 15.3 - Prob. 15.4.2PECh. 15.4 - The visible emission lines observed by Balmer all...Ch. 15.4 - Prob. 15.5.2PE
Ch. 15.4 - Prob. 15.6.1PECh. 15.4 - The hydrogen atom can absorb light of wavelength...Ch. 15.5 - Prob. 15.7.1PECh. 15.5 - Prob. 15.7.2PECh. 15.5 - Use the de Brogue relationship to determine the...Ch. 15.5 - Prob. 15.8.2PECh. 15.6 - Neutron diffraction is an important technique for...Ch. 15.6 - The electron microscope has been widely used to...Ch. 15.6 - Prob. 15.10.1PECh. 15.6 - An AM radio station broadcasts at 1010 kHz, and...Ch. 15.6 - One type of sunburn occurs on exposure to UV light...Ch. 15.6 - Prob. 15.11.2PECh. 15.7 - Prob. 15.12.1PECh. 15.7 - A stellar object is emitting radiation at 3.55 mm....Ch. 15 - Prob. 1DECh. 15 - Prob. 1ECh. 15 - Identify the group of elements that corresponds to...Ch. 15 - Prob. 3ECh. 15 - Using the periodic table as a guide, write the...Ch. 15 -
Arrange Be, C, K, and Ca in order of increasing...Ch. 15 - Prob. 6ECh. 15 - Prob. 7ECh. 15 - Prob. 8ECh. 15 - Consider the isoelectronic ions F- and Na+. (a)...Ch. 15 - Prob. 10ECh. 15 - Prob. 11ECh. 15 - Prob. 12ECh. 15 - Give the values for n, I,and mlfor each orbital in...Ch. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Which of the following represent impossible...Ch. 15 - For the table that follows, write which orbital...Ch. 15 - Sketch the shape and orientation of the following...Ch. 15 - Prob. 19ECh. 15 - Prob. 20ECh. 15 - Two possible electron configurations for an Li...Ch. 15 -
6.70 An experiment called the Stern—Gerlach...Ch. 15 - Prob. 23ECh. 15 - Prob. 24ECh. 15 - What are "valence electrons"? What are "core...Ch. 15 - For each element, indicate the number of valence...Ch. 15 - Write the condensed electron configurations for...Ch. 15 - Write the condensed electron configurations for...Ch. 15 - Identify the specific element that corresponds to...Ch. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - Prob. 33ECh. 15 - Prob. 34ECh. 15 - Prob. 35ECh. 15 - Prob. 36ECh. 15 - Prob. 37ECh. 15 - In an experiment to study the photoelectric...Ch. 15 - Prob. 39ECh. 15 - Prob. 40ECh. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 43ECh. 15 - Prob. 44ECh. 15 - Prob. 45ECh. 15 - Prob. 46ECh. 15 - Prob. 47ECh. 15 - [6.100] The Chemistry and Life box in Section 6.7...Ch. 15 - Prob. 49ECh. 15 - [6.104] In the experiment shown schematically...Ch. 15 - Microwave ovens use microwave radiation to heat...Ch. 15 - Prob. 52ECh. 15 - The discovery of hafnium, element number 72,...Ch. 15 - Account for formation of the following series of...Ch. 15 - Prob. 55ECh. 15 - The two most common isotopes of uranium are 235U...Ch. 15 - Hypothetical elements X and Y form a molecule XY2,...Ch. 15 - Prob. 58ECh. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - Prob. 61ECh. 15 - Prob. 62ECh. 15 - Prob. 63ECh. 15 - Prob. 64ECh. 15 - Consider the following statements about first...Ch. 15 - Prob. 66ECh. 15 - Prob. 67ECh. 15 -
Write the electron configurations for (a) Ga3+...Ch. 15 - Prob. 69AECh. 15 - Prob. 70AECh. 15 - Prob. 71AECh. 15 - Prob. 72AECh. 15 - Prob. 73AECh. 15 - Prob. 74AECh. 15 - Consider the hypothetical reaction A(g) 2B(g). A...Ch. 15 - 15.76 As shown in Table 15.2, the equilibrium...Ch. 15 - Prob. 77AECh. 15 - Prob. 78AECh. 15 - Prob. 79AECh. 15 - Prob. 80AECh. 15 - Prob. 81AECh. 15 - Prob. 82AECh. 15 - Prob. 83AECh. 15 - Prob. 84AECh. 15 - Prob. 85AECh. 15 - Prob. 86AECh. 15 - Prob. 87AECh. 15 - Prob. 88AECh. 15 - Prob. 89AECh. 15 - Prob. 90AECh. 15 - Prob. 91AECh. 15 - Prob. 92AECh. 15 - Prob. 93IECh. 15 - Prob. 94IECh. 15 - Prob. 95IECh. 15 - Prob. 96IECh. 15 - Write the equilibrium-constant expression for the...Ch. 15 - In Section 11.5, we defined the vapor pressure of...Ch. 15 - Prob. 99IECh. 15 - Prob. 100IE
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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