
Chemistry: Atoms First V1
1st Edition
ISBN: 9781259383120
Author: Burdge
Publisher: McGraw Hill Custom
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Question
Chapter 1.5, Problem 1.5.5SR
Interpretation Introduction
Interpretation:
For the given operation the final product should be expressed in correct number of significant figures
Concept introduction:
Significant figures:
The digits having a meaning in a given number are called as significant figures.
Significant figures – calculation rules
- Significant figure is a non-zero number (1443.2 has five significant figures)
- Zeros placement in between non-zero number are significant figures (70005 has five significant figures).
- Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
- Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
- Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures). In this cases use scientific notation to avoid ambiguity.
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1. For each of the reaction "railroads" below, you are either asked to give the structure(s) of the starting
material(s) or product(s), or provide reagents/conditions to accomplish the transformation, as
indicated by the boxes.
a.
NaOMe
H+
.CO,H
HO₂C
MeOH (excess)
MeOH
H3C
Br
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CH3
1. LiAlH4
2. H3O+
3. PBг3
H3C
1. Et-Li
2. H3O+
-CO₂Me
-CO₂Me
OH
CH3
CH3
ল
CH3
Predict the intermediate 1 and final product 2 of this organic reaction:
NaOMe
ག1, ད།་, -
+
H
You can draw 1 and 2 in any arrangement you like.
2
work up
Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge)
bonds at the chiral center.
Explanation
Check
Click and drag to start drawing a structure.
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What is the total energy cost associated with the compound below adopting the shown conformation?
CH3
HH
DH
CH3
Chapter 1 Solutions
Chemistry: Atoms First V1
Ch. 1.4 - illustrates conversions between these two...Ch. 1.4 - Prob. 1PPACh. 1.4 - According to the website of the National...Ch. 1.4 - If a single degree on the Celsius scale is...Ch. 1.4 - A body temperature above 39C constitutes a high...Ch. 1.4 - The average temperature at the summit of Mt....Ch. 1.4 - Prob. 2PPBCh. 1.4 - If a single degree on the Fahrenheit scale is...Ch. 1.4 - Prob. 1.3WECh. 1.4 - Given that 20.0 mL of mercury has a mass of 272 g....
Ch. 1.4 - Prob. 3PPBCh. 1.4 - Using the picture of the graduated cylinder and...Ch. 1.4 - Prob. 1.4.1SRCh. 1.4 - Prob. 1.4.2SRCh. 1.4 - Prob. 1.4.3SRCh. 1.4 - Prob. 1.4.4SRCh. 1.5 - Determine the number of significant figures in the...Ch. 1.5 - Determine the number of significant figures in the...Ch. 1.5 - Using scientific notation, express the number one...Ch. 1.5 - Prob. 4PPCCh. 1.5 - Perform the following arithmetic operations and...Ch. 1.5 - Perform the following arithmetic operations, and...Ch. 1.5 - Prob. 5PPBCh. 1.5 - Prob. 5PPCCh. 1.5 - Prob. 1.6WECh. 1.5 - Prob. 6PPACh. 1.5 - Prob. 6PPBCh. 1.5 - Several pieces of aluminum metal with a total mass...Ch. 1.5 - Prob. 1.5.1SRCh. 1.5 - Prob. 1.5.2SRCh. 1.5 - Prob. 1.5.3SRCh. 1.5 - Prob. 1.5.4SRCh. 1.5 - Prob. 1.5.5SRCh. 1.5 - Prob. 1.5.6SRCh. 1.6 - The Food and Drug Administration (FDA) recommends...Ch. 1.6 - The American Heart Association recommends that...Ch. 1.6 - A gold nugget has a mass of 0.9347 oz. What is its...Ch. 1.6 - The diagram contains several objects that are...Ch. 1.6 - Prob. 1.8WECh. 1.6 - Prob. 8PPACh. 1.6 - The density of mercury is 13.6 g/cm3. What is its...Ch. 1.6 - Each diagram [(i) or (ii)] shows the objects...Ch. 1.6 - Prob. 1.6.1SRCh. 1.6 - Prob. 1.6.2SRCh. 1.6 - Prob. 1.6.3SRCh. 1.6 - Prob. 1.6.4SRCh. 1 - Prob. 1.1QPCh. 1 - Explain what is meant by the scientific method.Ch. 1 - What is the difference between a hypothesis and a...Ch. 1 - Classily each of the following statements as a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Prob. 1.6QPCh. 1 - Prob. 1.7QPCh. 1 - Prob. 1.8QPCh. 1 - Classify each of the following as a pure...Ch. 1 - What is the difference between a qualitative...Ch. 1 - Prob. 1.11QPCh. 1 - Prob. 1.12QPCh. 1 - Determine which of the following properties are...Ch. 1 - Determine whether the following statements...Ch. 1 - Prob. 1.15QPCh. 1 - Determine whether each of the following describes...Ch. 1 - Determine whether each of the following describes...Ch. 1 - Name the SI base units that are important in...Ch. 1 - Write the numbers represented by the following...Ch. 1 - What units do chemists normally use for the...Ch. 1 - What is the difference between mass and weight? If...Ch. 1 - Prob. 1.22QPCh. 1 - Prob. 1.23QPCh. 1 - Prob. 1.24QPCh. 1 - Prob. 1.25QPCh. 1 - Prob. 1.26QPCh. 1 - The density of water at 40C is 0.992 g/mL. What is...Ch. 1 - Prob. 1.28QPCh. 1 - Prob. 1.29QPCh. 1 - Prob. 1.30QPCh. 1 - Prob. 1.31QPCh. 1 - Prob. 1.32QPCh. 1 - Indicate which of the following numbers is an...Ch. 1 - Prob. 1.34QPCh. 1 - Distinguish between the terms accuracy and...Ch. 1 - Express the following numbers in scientific...Ch. 1 - Prob. 1.37QPCh. 1 - Prob. 1.38QPCh. 1 - Express the answers to the following calculations...Ch. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 1.41QPCh. 1 - Carry out the following operations as if they were...Ch. 1 - Prob. 1.43QPCh. 1 - Three students (A, B, and C) are asked to...Ch. 1 - Prob. 1.45QPCh. 1 - Prob. 1.46QPCh. 1 - Prob. 1.47QPCh. 1 - The density of the metal bar shown is 8.16 g/cm3....Ch. 1 - The following shows an experiment used to...Ch. 1 - Prob. 1.50QPCh. 1 - Prob. 1.51QPCh. 1 - Prob. 1.52QPCh. 1 - Carry out the following conversions: (a) 1.1 1022...Ch. 1 - The average speed of helium at 25C is 1255 m/s....Ch. 1 - Prob. 1.55QPCh. 1 - Prob. 1.56QPCh. 1 - Prob. 1.57QPCh. 1 - Prob. 1.58QPCh. 1 - Prob. 1.59QPCh. 1 - Prob. 1.60QPCh. 1 - Prob. 1.61QPCh. 1 - Prob. 1.62QPCh. 1 - Prob. 1.63QPCh. 1 - Prob. 1.64QPCh. 1 - The density of ammonia gas under certain...Ch. 1 - Prob. 1.66QPCh. 1 - ADDITIONAL PROBLEMS 1.67 Using the appropriate...Ch. 1 - Prob. 1.68QPCh. 1 - Winch of the following statements describe...Ch. 1 - Prob. 1.70QPCh. 1 - Prob. 1.71QPCh. 1 - In determining the density of a rectangular metal...Ch. 1 - Prob. 1.73QPCh. 1 - Prob. 1.74QPCh. 1 - Prob. 1.75QPCh. 1 - Prob. 1.76QPCh. 1 - Prob. 1.77QPCh. 1 - The experiment described in Problem 1.77 is a...Ch. 1 - Prob. 1.79QPCh. 1 - Lithium has a very low density (density = 0.53...Ch. 1 - Prob. 1.81QPCh. 1 - Vanillin (used to flavor vanilla ice cream and...Ch. 1 - Prob. 1.83QPCh. 1 - Prob. 1.84QPCh. 1 - Prob. 1.85QPCh. 1 - Prob. 1.86QPCh. 1 - Prob. 1.87QPCh. 1 - Magnesium is used in alloys, in batteries, and in...Ch. 1 - Prob. 1.89QPCh. 1 - The surface area and average depth of the Pacific...Ch. 1 - Calculate the percent error for the following...Ch. 1 - Prob. 1.92QPCh. 1 - Chalcopyrite contains 34.63 percent copper by...Ch. 1 - Prob. 1.94QPCh. 1 - One gallon of gasoline in an automobile's engine...Ch. 1 - Prob. 1.96QPCh. 1 - The worlds total petroleum reserve is estimated at...Ch. 1 - Prob. 1.98QPCh. 1 - Prob. 1.99QPCh. 1 - Chlorine is used to disinfect swimming pools. 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