Chemistry: Atoms First V1
1st Edition
ISBN: 9781259383120
Author: Burdge
Publisher: McGraw Hill Custom
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Chapter 1, Problem 1.55QP
Interpretation Introduction
Interpretation:
The unit conversion of days into seconds for the solar year has to be given.
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A cylinder contains 12 L of water vapour at 150˚C and 5 atm. The temperature of the water vapour is raised to 175˚C, and the volume of the cylinder is reduced to 8.5 L. What is the final pressure of the gas in atmospheres?
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On the next page is an LC separation of the parabens found in baby wash. Parabens are
suspected in a link to breast cancer therefore an accurate way to quantitate them is desired.
a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for
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b. Is this a "good" value for a capacity factor? Explain.
c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly
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MAU
| Methyl paraben
40
20
0
-2
Ethyl paraben n-Propyl paraben
n-Butyl paraben
App ID 22925
6
8
min
d. In Figure 4, each stationary phase shows some negative correlation between plate count
and retention factor. In other words, as k' increases, N decreases. Explain this relationship
between k' and N.
Plate Count (N)
4000
3500
2500
2000
1500
1000
Figure 4. Column efficiency (N) vs retention factor (k') for 22
nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000
Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain
k' less than 15, which was achieved for most solutes as follows: FMS
(30/70 A/W), PGC (60/40), COZ (80/20). Slightly different
compositions were used for the most highly retained solutes. All
columns were 50 mm × 4.6 mm id and packed with 5 um particles,
except for COZ, which was packed with 3 um particles. All other
chromatographic conditions were constant: column length 5 cm,
column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C,
and injection volume 0.5 μL
Log(k'x/K'ethylbenzene)
FMS
1.5
1.0
0.5
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ཐྭ ཋ ཤྩ བྷྲ ;
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Chapter 1 Solutions
Chemistry: Atoms First V1
Ch. 1.4 - illustrates conversions between these two...Ch. 1.4 - Prob. 1PPACh. 1.4 - According to the website of the National...Ch. 1.4 - If a single degree on the Celsius scale is...Ch. 1.4 - A body temperature above 39C constitutes a high...Ch. 1.4 - The average temperature at the summit of Mt....Ch. 1.4 - Prob. 2PPBCh. 1.4 - If a single degree on the Fahrenheit scale is...Ch. 1.4 - Prob. 1.3WECh. 1.4 - Given that 20.0 mL of mercury has a mass of 272 g....
Ch. 1.4 - Prob. 3PPBCh. 1.4 - Using the picture of the graduated cylinder and...Ch. 1.4 - Prob. 1.4.1SRCh. 1.4 - Prob. 1.4.2SRCh. 1.4 - Prob. 1.4.3SRCh. 1.4 - Prob. 1.4.4SRCh. 1.5 - Determine the number of significant figures in the...Ch. 1.5 - Determine the number of significant figures in the...Ch. 1.5 - Using scientific notation, express the number one...Ch. 1.5 - Prob. 4PPCCh. 1.5 - Perform the following arithmetic operations and...Ch. 1.5 - Perform the following arithmetic operations, and...Ch. 1.5 - Prob. 5PPBCh. 1.5 - Prob. 5PPCCh. 1.5 - Prob. 1.6WECh. 1.5 - Prob. 6PPACh. 1.5 - Prob. 6PPBCh. 1.5 - Several pieces of aluminum metal with a total mass...Ch. 1.5 - Prob. 1.5.1SRCh. 1.5 - Prob. 1.5.2SRCh. 1.5 - Prob. 1.5.3SRCh. 1.5 - Prob. 1.5.4SRCh. 1.5 - Prob. 1.5.5SRCh. 1.5 - Prob. 1.5.6SRCh. 1.6 - The Food and Drug Administration (FDA) recommends...Ch. 1.6 - The American Heart Association recommends that...Ch. 1.6 - A gold nugget has a mass of 0.9347 oz. What is its...Ch. 1.6 - The diagram contains several objects that are...Ch. 1.6 - Prob. 1.8WECh. 1.6 - Prob. 8PPACh. 1.6 - The density of mercury is 13.6 g/cm3. What is its...Ch. 1.6 - Each diagram [(i) or (ii)] shows the objects...Ch. 1.6 - Prob. 1.6.1SRCh. 1.6 - Prob. 1.6.2SRCh. 1.6 - Prob. 1.6.3SRCh. 1.6 - Prob. 1.6.4SRCh. 1 - Prob. 1.1QPCh. 1 - Explain what is meant by the scientific method.Ch. 1 - What is the difference between a hypothesis and a...Ch. 1 - Classily each of the following statements as a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Prob. 1.6QPCh. 1 - Prob. 1.7QPCh. 1 - Prob. 1.8QPCh. 1 - Classify each of the following as a pure...Ch. 1 - What is the difference between a qualitative...Ch. 1 - Prob. 1.11QPCh. 1 - Prob. 1.12QPCh. 1 - Determine which of the following properties are...Ch. 1 - Determine whether the following statements...Ch. 1 - Prob. 1.15QPCh. 1 - Determine whether each of the following describes...Ch. 1 - Determine whether each of the following describes...Ch. 1 - Name the SI base units that are important in...Ch. 1 - Write the numbers represented by the following...Ch. 1 - What units do chemists normally use for the...Ch. 1 - What is the difference between mass and weight? If...Ch. 1 - Prob. 1.22QPCh. 1 - Prob. 1.23QPCh. 1 - Prob. 1.24QPCh. 1 - Prob. 1.25QPCh. 1 - Prob. 1.26QPCh. 1 - The density of water at 40C is 0.992 g/mL. What is...Ch. 1 - Prob. 1.28QPCh. 1 - Prob. 1.29QPCh. 1 - Prob. 1.30QPCh. 1 - Prob. 1.31QPCh. 1 - Prob. 1.32QPCh. 1 - Indicate which of the following numbers is an...Ch. 1 - Prob. 1.34QPCh. 1 - Distinguish between the terms accuracy and...Ch. 1 - Express the following numbers in scientific...Ch. 1 - Prob. 1.37QPCh. 1 - Prob. 1.38QPCh. 1 - Express the answers to the following calculations...Ch. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 1.41QPCh. 1 - Carry out the following operations as if they were...Ch. 1 - Prob. 1.43QPCh. 1 - Three students (A, B, and C) are asked to...Ch. 1 - Prob. 1.45QPCh. 1 - Prob. 1.46QPCh. 1 - Prob. 1.47QPCh. 1 - The density of the metal bar shown is 8.16 g/cm3....Ch. 1 - The following shows an experiment used to...Ch. 1 - Prob. 1.50QPCh. 1 - Prob. 1.51QPCh. 1 - Prob. 1.52QPCh. 1 - Carry out the following conversions: (a) 1.1 1022...Ch. 1 - The average speed of helium at 25C is 1255 m/s....Ch. 1 - Prob. 1.55QPCh. 1 - Prob. 1.56QPCh. 1 - Prob. 1.57QPCh. 1 - Prob. 1.58QPCh. 1 - Prob. 1.59QPCh. 1 - Prob. 1.60QPCh. 1 - Prob. 1.61QPCh. 1 - Prob. 1.62QPCh. 1 - Prob. 1.63QPCh. 1 - Prob. 1.64QPCh. 1 - The density of ammonia gas under certain...Ch. 1 - Prob. 1.66QPCh. 1 - ADDITIONAL PROBLEMS 1.67 Using the appropriate...Ch. 1 - Prob. 1.68QPCh. 1 - Winch of the following statements describe...Ch. 1 - Prob. 1.70QPCh. 1 - Prob. 1.71QPCh. 1 - In determining the density of a rectangular metal...Ch. 1 - Prob. 1.73QPCh. 1 - Prob. 1.74QPCh. 1 - Prob. 1.75QPCh. 1 - Prob. 1.76QPCh. 1 - Prob. 1.77QPCh. 1 - The experiment described in Problem 1.77 is a...Ch. 1 - Prob. 1.79QPCh. 1 - Lithium has a very low density (density = 0.53...Ch. 1 - Prob. 1.81QPCh. 1 - Vanillin (used to flavor vanilla ice cream and...Ch. 1 - Prob. 1.83QPCh. 1 - Prob. 1.84QPCh. 1 - Prob. 1.85QPCh. 1 - Prob. 1.86QPCh. 1 - Prob. 1.87QPCh. 1 - Magnesium is used in alloys, in batteries, and in...Ch. 1 - Prob. 1.89QPCh. 1 - The surface area and average depth of the Pacific...Ch. 1 - Calculate the percent error for the following...Ch. 1 - Prob. 1.92QPCh. 1 - Chalcopyrite contains 34.63 percent copper by...Ch. 1 - Prob. 1.94QPCh. 1 - One gallon of gasoline in an automobile's engine...Ch. 1 - Prob. 1.96QPCh. 1 - The worlds total petroleum reserve is estimated at...Ch. 1 - Prob. 1.98QPCh. 1 - Prob. 1.99QPCh. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - Prob. 1.103QPCh. 1 - Prob. 1.104QPCh. 1 - Prob. 1.105QPCh. 1 - Prob. 1.106QPCh. 1 - Prob. 1.107QPCh. 1 - Prob. 1.108QPCh. 1 - Prob. 1.109QPCh. 1 - Prob. 1.110QPCh. 1 - In January 2009, the National Aeronautics and...Ch. 1 - Prob. 1.112QPCh. 1 - Prob. 1.113QPCh. 1 - Prob. 1.114QPCh. 1 - Prob. 1.115QPCh. 1 - The composition of pennies has changed over the...
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