Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
7th Edition
ISBN: 9780133900811
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 15, Problem 15.45CP
Interpretation:
We are given the reaction of PCl4+ with Cl- as a ball and stick model and are asked to demonstrate this reaction using electron-dot structures. We must also show the arrows that represent the electron flow in the mechanism of the reaction.
Interpretation Introduction
Concept introduction:
- A Bronsted-Lowry is an acid that is a proton, H+, donor while a Bronsted-Lowry base is a proton acceptor.
- A Lewis acid is an electron pair acceptor, while a Lewis base is an electron pair donor.
To classify:
The electron dot diagram for the Lewis acid-base reaction.
Expert Solution & Answer
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Students have asked these similar questions
Arrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5)
Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them.
▸ View Available Hint(s)
Least acidity
NH&F NaBr NaOH
NH,Br NaCIO
Reset
Greatest acidity
1. Consider the following molecular-level diagrams of a titration.
O-HA molecule
-Aion
°°
о
°
(a)
о
(b)
(c)
(d)
a. Which diagram best illustrates the microscopic representation for the
EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium.
hydroxide?
(e)
Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single
file upload below:
Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Chapter 15 Solutions
Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
Ch. 15 - Prob. 15.1PCh. 15 - Prob. 15.2ACh. 15 - Conceptual PRACTICE 15.3 For the following...Ch. 15 - Conceptual APPLY 15.4 For the following reactions...Ch. 15 - Prob. 15.5PCh. 15 - Conceptual APPLY 15.6 The following pictures...Ch. 15 - Prob. 15.7PCh. 15 - Prob. 15.8ACh. 15 - PRACTICE 15.9 The concentration of H3O+ ions in...Ch. 15 - Prob. 15.10A
Ch. 15 - Prob. 15.11PCh. 15 - Prob. 15.12ACh. 15 - Prob. 15.13PCh. 15 - Prob. 15.14ACh. 15 - Prob. 15.15PCh. 15 - Prob. 15.16ACh. 15 - Prob. 15.17PCh. 15 - Prob. 15.18ACh. 15 - Prob. 15.19PCh. 15 - Prob. 15.20ACh. 15 - Prob. 15.21PCh. 15 - APPLY 15.22 Carbonated drinks are prepared by...Ch. 15 - Prob. 15.23PCh. 15 - Prob. 15.24ACh. 15 - Prob. 15.25PCh. 15 - Prob. 15.26ACh. 15 - Prob. 15.27PCh. 15 - Prob. 15.28ACh. 15 - Prob. 15.29PCh. 15 - Prob. 15.30ACh. 15 - Prob. 15.31PCh. 15 - Prob. 15.32PCh. 15 - Prob. 15.33PCh. 15 - Prob. 15.34PCh. 15 - Prob. 15.35PCh. 15 - Prob. 15.36CPCh. 15 - Prob. 15.37CPCh. 15 - Prob. 15.38CPCh. 15 - 15.39 Which of the following pictures best...Ch. 15 - Prob. 15.40CPCh. 15 - Prob. 15.41CPCh. 15 - Prob. 15.42CPCh. 15 - Prob. 15.43CPCh. 15 - Boric acid ( H3BO3 ) is a weakmonoprotic acid that...Ch. 15 - Prob. 15.45CPCh. 15 - Which of the following are Brønsted-Lowry bases...Ch. 15 - Prob. 15.47SPCh. 15 - Prob. 15.48SPCh. 15 - Prob. 15.49SPCh. 15 - Prob. 15.50SPCh. 15 - Prob. 15.51SPCh. 15 - Prob. 15.52SPCh. 15 - Prob. 15.53SPCh. 15 - Prob. 15.54SPCh. 15 - Prob. 15.55SPCh. 15 - Prob. 15.56SPCh. 15 - Prob. 15.57SPCh. 15 - Prob. 15.58SPCh. 15 - Prob. 15.59SPCh. 15 - Prob. 15.60SPCh. 15 - Prob. 15.61SPCh. 15 - Prob. 15.62SPCh. 15 - Prob. 15.63SPCh. 15 - The concentration of OH in a sample of seawater is...Ch. 15 - The concentration of OH in human blood is 2.24X107...Ch. 15 - For each of the following solutions, calculate [...Ch. 15 - For each of the following solutions, calculate [...Ch. 15 - Prob. 15.68SPCh. 15 - Prob. 15.69SPCh. 15 - Prob. 15.70SPCh. 15 - Prob. 15.71SPCh. 15 - Prob. 15.72SPCh. 15 - Prob. 15.73SPCh. 15 - Prob. 15.74SPCh. 15 - Prob. 15.75SPCh. 15 - Prob. 15.76SPCh. 15 - Prob. 15.77SPCh. 15 - 15.78 Calculate the pH of solutions prepared...Ch. 15 -
15.79 Calculate the pH of solutions prepared...Ch. 15 - Prob. 15.80SPCh. 15 - Prob. 15.81SPCh. 15 - Prob. 15.82SPCh. 15 - Prob. 15.83SPCh. 15 - Prob. 15.84SPCh. 15 - Prob. 15.85SPCh. 15 - A vitamin C tablet containing 250 mg of ascorbic...Ch. 15 - Prob. 15.87SPCh. 15 - Acrylic acid ( HC3H3O2) is used in the manufacture...Ch. 15 - Prob. 15.89SPCh. 15 - Prob. 15.90SPCh. 15 - Prob. 15.91SPCh. 15 - Prob. 15.92SPCh. 15 - Prob. 15.93SPCh. 15 - Prob. 15.94SPCh. 15 - Prob. 15.95SPCh. 15 - Prob. 15.96SPCh. 15 - Prob. 15.97SPCh. 15 - Prob. 15.98SPCh. 15 - Prob. 15.99SPCh. 15 - Prob. 15.100SPCh. 15 - Prob. 15.101SPCh. 15 - Prob. 15.102SPCh. 15 - Prob. 15.103SPCh. 15 - Prob. 15.104SPCh. 15 - Prob. 15.105SPCh. 15 - Prob. 15.106SPCh. 15 - Prob. 15.107SPCh. 15 - Prob. 15.108SPCh. 15 - Prob. 15.109SPCh. 15 - Prob. 15.110SPCh. 15 - Prob. 15.111SPCh. 15 - Prob. 15.112SPCh. 15 - Prob. 15.113SPCh. 15 - Prob. 15.114SPCh. 15 - Prob. 15.115SPCh. 15 - Prob. 15.116SPCh. 15 - Prob. 15.117SPCh. 15 - Prob. 15.118SPCh. 15 - Prob. 15.119SPCh. 15 - Prob. 15.120SPCh. 15 - Prob. 15.121SPCh. 15 - Prob. 15.122SPCh. 15 - For each of the Lewis acid—base reactions in...Ch. 15 - Prob. 15.124SPCh. 15 - Prob. 15.125SPCh. 15 - Prob. 15.126CPCh. 15 - Prob. 15.127CPCh. 15 - Prob. 15.128CPCh. 15 - Prob. 15.129CPCh. 15 - Prob. 15.130CPCh. 15 - Use the conjugate acid-base pair HCN and CN to...Ch. 15 - Prob. 15.132CPCh. 15 - Prob. 15.133CPCh. 15 - Prob. 15.134CPCh. 15 - Prob. 15.135CPCh. 15 - Prob. 15.136CPCh. 15 - Prob. 15.137CPCh. 15 - Prob. 15.138CPCh. 15 - Prob. 15.139CPCh. 15 - Prob. 15.140CPCh. 15 - Prob. 15.141CPCh. 15 - Prob. 15.142CPCh. 15 - Prob. 15.143CPCh. 15 - Prob. 15.144CPCh. 15 - Prob. 15.145CPCh. 15 - Prob. 15.146CPCh. 15 - Prob. 15.147CPCh. 15 - Prob. 15.148CPCh. 15 - Prob. 15.149CPCh. 15 - Prob. 15.150MPCh. 15 - Prob. 15.151MPCh. 15 - Prob. 15.152MPCh. 15 - Prob. 15.153MPCh. 15 - Prob. 15.154MPCh. 15 - Prob. 15.155MPCh. 15 - A 1.000 L sample of HF gas at 20.0°C and 0.601 atm...Ch. 15 - Prob. 15.157MPCh. 15 - Prob. 15.158MP
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