Student Solutions Manual for Ebbing/Gammon's General Chemistry, 11th
11th Edition
ISBN: 9781305673472
Author: Darrell Ebbing, Steven D. Gammon
Publisher: Cengage Learning
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Textbook Question
Chapter 15, Problem 15.38QP
The following shows ball-and-stick models of the reactants in a Lewis acid–base reaction.
Write the complete equation for the reaction, including the product. Identify each reactant as a Lewis acid or a Lewis base.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 15 Solutions
Student Solutions Manual for Ebbing/Gammon's General Chemistry, 11th
Ch. 15.2 - For the reaction H2CO3(aq)+CN(aq)HCN(aq)+HCO3(aq)...Ch. 15.2 - Prob. 15.1CCCh. 15.3 - Identify the Lewis acid and the Lewis base in each...Ch. 15.4 - Prob. 15.3ECh. 15.4 - Prob. 15.2CCCh. 15.5 - Which member of each of the following pairs is the...Ch. 15.7 - A solution of barium hydroxide at 25C is 0.125 M...Ch. 15.7 - Prob. 15.6ECh. 15.7 - Rank the following solutions from most acidic to...Ch. 15.8 - What is the pH of a sample of gastric juice...
Ch. 15.8 - A saturated solution of calcium hydroxide has a...Ch. 15.8 - A brand of carbonated beverage has a pH of 3.16....Ch. 15.8 - A 0.010 M solution of ammonia, NH3, has a pH of...Ch. 15.8 - Prob. 15.4CCCh. 15 - Which of the following are strong acids? Which are...Ch. 15 - Describe any thermochemical (heat of reaction)...Ch. 15 - Prob. 15.3QPCh. 15 - Prob. 15.4QPCh. 15 - Write an equation in which H2PO3 acts as an acid...Ch. 15 - Describe four ways in which the BrnstedLowry...Ch. 15 - Prob. 15.7QPCh. 15 - Explain why an acidbase reaction favors the weaker...Ch. 15 - Give two important factors that determine the...Ch. 15 - Prob. 15.10QPCh. 15 - Prob. 15.11QPCh. 15 - Prob. 15.12QPCh. 15 - Prob. 15.13QPCh. 15 - Prob. 15.14QPCh. 15 - The conjugate base of hydrofluoric acid dissolved...Ch. 15 - In the following reaction, identify the Lewis...Ch. 15 - Calculate the hydronium-ion concentration at 25C...Ch. 15 - The pH of a solution is 9.55 at 25C What is the...Ch. 15 - Acids You make a solution by dissolving 0.0010 mol...Ch. 15 - Strong Acids, Weak Acids, and pH Two 0.10-mol...Ch. 15 - Prob. 15.21QPCh. 15 - Prob. 15.22QPCh. 15 - Prob. 15.23QPCh. 15 - Compare the structures of HNO2 and H2CO3. Which...Ch. 15 - Prob. 15.25QPCh. 15 - Prob. 15.26QPCh. 15 - A strong monoprotic acid, with the molecular...Ch. 15 - A weak acid, HA, is dissolved in water. Which one...Ch. 15 - Write the balanced reaction of hydroxide ion with...Ch. 15 - Write the balanced reaction of hypobromous acid,...Ch. 15 - Give the conjugate base to each of the following...Ch. 15 - Give the conjugate base to each of the following...Ch. 15 - Give the conjugate acid to each of the following...Ch. 15 - Give the conjugate acid to each of the following...Ch. 15 - For the following reactions, label each species as...Ch. 15 - For the following reactions, label each species as...Ch. 15 - The following shows ball-and-stick models of the...Ch. 15 - The following shows ball-and-stick models of the...Ch. 15 - Complete each of the following equations. Then...Ch. 15 - Complete each of the following equations. Then...Ch. 15 - In the following reactions, identify each reactant...Ch. 15 - In the following reactions, label each reactant as...Ch. 15 - Natural gas frequently contains hydrogen sulfide,...Ch. 15 - Coal and other fossil fuels usually contain sulfur...Ch. 15 - Complete the following equation. Using Table 15.2,...Ch. 15 - Complete the following equation. Using Table 15.2,...Ch. 15 - Use Table 15.2 to decide whether the species on...Ch. 15 - Use Table 15.2 to decide whether the species on...Ch. 15 - Prob. 15.49QPCh. 15 - In the following reaction of tetrafluoroboric...Ch. 15 - For each of the following pairs, give the stronger...Ch. 15 - Order each of the following pairs by acid...Ch. 15 - What are the concentrations of H3O+ and OH in each...Ch. 15 - What are the concentrations of H3O+ and OH in each...Ch. 15 - A solution of hydrochloric acid is 0.059 M HCl....Ch. 15 - A solution is 0.030 M HNO3 (nitric acid). What is...Ch. 15 - What are the hydronium-ion and the hydroxide-ion...Ch. 15 - A saturated solution of magnesium hydroxide is 3.2...Ch. 15 - The following are solution concentrations....Ch. 15 - The following are solution concentrations....Ch. 15 - A shampoo solution at 25C has a hydroxide-ion...Ch. 15 - An antiseptic solution at 25C has a hydroxide-ion...Ch. 15 - Which of the following pH values indicate an...Ch. 15 - Which of the following pH values indicate an...Ch. 15 - For each of the following, state whether the...Ch. 15 - Prob. 15.66QPCh. 15 - Obtain the pH corresponding to the following...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - A sample of vinegar has a hydronium-ion...Ch. 15 - Some lemon juice has a hydronium-ion concentration...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - Obtain the pH corresponding to the following...Ch. 15 - A solution of washing soda (sodium carbonate,...Ch. 15 - A solution of lye (sodium hydroxide, NaOH) has a...Ch. 15 - The pH of a cup of coffee (at 25C) was found to be...Ch. 15 - A wine was tested for acidity, and its pH was...Ch. 15 - A detergent solution has a pH of 11.80 at 25C....Ch. 15 - Morphine is a narcotic that is used to relieve...Ch. 15 - A 1.00-L aqueous solution contained 5.80 g of...Ch. 15 - A 1.00-L aqueous solution contained 6.78 g of...Ch. 15 - A certain sample of rainwater gives a yellow color...Ch. 15 - A drop of thymol blue gave a yellow color with a...Ch. 15 - Identify each of the following as an acid or a...Ch. 15 - Which of the following substances are acids in...Ch. 15 - Write a reaction for each of the following in...Ch. 15 - Write a reaction for each of the following in...Ch. 15 - Prob. 15.87QPCh. 15 - Prob. 15.88QPCh. 15 - Prob. 15.89QPCh. 15 - Prob. 15.90QPCh. 15 - Prob. 15.91QPCh. 15 - List the following compounds in order of...Ch. 15 - A solution is 0.18 M KOH. What are the...Ch. 15 - A solution is 0.25 M Sr(OH)2. What are the...Ch. 15 - Prob. 15.95QPCh. 15 - A sample of lemon juice has a hydronium-ion...Ch. 15 - Prob. 15.97QPCh. 15 - A sample of grape juice has a pH of 4.15. What is...Ch. 15 - A 4.640-g sample of a mixture of sodium hydrogen...Ch. 15 - A 2.500-g sample of a mixture of sodium carbonate...Ch. 15 - Prob. 15.101QPCh. 15 - The dihydrogen phosphate ion has the ability to...Ch. 15 - Prob. 15.103QPCh. 15 - Prob. 15.104QPCh. 15 - Prob. 15.105QPCh. 15 - Show how methylamine, CH3NH2, is a BrnstedLowry...Ch. 15 - Prob. 15.107QPCh. 15 - Prob. 15.108QPCh. 15 - Prob. 15.109QPCh. 15 - Prob. 15.110QPCh. 15 - Prob. 15.111QPCh. 15 - Hydrazine, N2H4 (having the structure H2NNH2), and...Ch. 15 - Prob. 15.113QPCh. 15 - Liquid ammonia undergoes autoionization similar to...Ch. 15 - Ethanol (ethyl alcohol), CH3CH2OH, can act as a...Ch. 15 - Ethanol, CH3CH2OH, can undergo auto-ionization....Ch. 15 - Aluminum chloride, AlCl3, reacts with...Ch. 15 - Consider each of the following pairs of compounds,...Ch. 15 - Arrange each of the following in order of...Ch. 15 - The following is a table of some of the oxoacids...Ch. 15 - Suppose you have 557 mL of 0.0300 M HCl, and you...Ch. 15 - Prob. 15.122QPCh. 15 - You want to make up 3.00 L of aqueous hydrochloric...Ch. 15 - Prob. 15.124QPCh. 15 - Prob. 15.125QPCh. 15 - Pure liquid ammonia ionizes in a way similar to...Ch. 15 - A solution contains 4.25g of ammonia per 250.0 mL...Ch. 15 - A solution contains 0.675 g of ethylamine,...Ch. 15 - Prob. 15.129QPCh. 15 - Hypophosphorous acid, H3PO2, and phosphoric acid,...Ch. 15 - Boron trifluoride, BF3, and ammonia, NH3, react to...Ch. 15 - Boron trifluoride, BF3, and diethyl ether,...
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