A chemical equation for the given information has to be written and the conjugate acid, base has to be identified. Concept introduction: Acid: According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid. Base: According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base. Conjugated acid: In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid. Conjugated base: In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

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Answer 1

Question

Chapter 15, Problem 15.109QP

(a)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(a)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Explanation of Solution

The hydrated aluminum ion acts as Bronsted-Lowry acid and it can react with ammonia a Bronsted-Lowry base to produce as mentioned ions in the following reaction.

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

(b)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(b)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Explanation of Solution

Ethanethiol acts as Bronsted-Lowry base and it can react with sulfuric acid a Bronsted-Lowry acid to produce as mentioned ions in the following reaction.

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

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Blocking Group are use to put 2 large sterically repulsive group ortho. Show the correct sequence toconnect the reagent to product with the highest yield possible. * see image **NOTE: The compound on the left is the starting point, and the compound on the right is the final product. Please show the steps in between to get from start to final, please. These are not two different compounds that need to be worked.

I dont understand this.

Can you please explain this prooblem to me, show me how the conjugation is added, did I add them in the correct places and if so please show me. Thanks!

Answer 2

Question

Chapter 15, Problem 15.109QP

(a)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(a)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Explanation of Solution

The hydrated aluminum ion acts as Bronsted-Lowry acid and it can react with ammonia a Bronsted-Lowry base to produce as mentioned ions in the following reaction.

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

(b)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(b)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Explanation of Solution

Ethanethiol acts as Bronsted-Lowry base and it can react with sulfuric acid a Bronsted-Lowry acid to produce as mentioned ions in the following reaction.

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

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Answer 3

Question

Chapter 15, Problem 15.109QP

(a)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(a)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Explanation of Solution

The hydrated aluminum ion acts as Bronsted-Lowry acid and it can react with ammonia a Bronsted-Lowry base to produce as mentioned ions in the following reaction.

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

(b)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(b)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Explanation of Solution

Ethanethiol acts as Bronsted-Lowry base and it can react with sulfuric acid a Bronsted-Lowry acid to produce as mentioned ions in the following reaction.

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

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Answer 4

Question

Chapter 15, Problem 15.109QP

(a)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(a)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Explanation of Solution

The hydrated aluminum ion acts as Bronsted-Lowry acid and it can react with ammonia a Bronsted-Lowry base to produce as mentioned ions in the following reaction.

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

(b)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(b)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Explanation of Solution

Ethanethiol acts as Bronsted-Lowry base and it can react with sulfuric acid a Bronsted-Lowry acid to produce as mentioned ions in the following reaction.

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

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Answer 5

Chapter 15, Problem 15.109QP

(a)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(a)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Explanation of Solution

The hydrated aluminum ion acts as Bronsted-Lowry acid and it can react with ammonia a Bronsted-Lowry base to produce as mentioned ions in the following reaction.

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

(b)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(b)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Explanation of Solution

Ethanethiol acts as Bronsted-Lowry base and it can react with sulfuric acid a Bronsted-Lowry acid to produce as mentioned ions in the following reaction.

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Answer 6

Chapter 15, Problem 15.109QP

(a)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(a)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Explanation of Solution

The hydrated aluminum ion acts as Bronsted-Lowry acid and it can react with ammonia a Bronsted-Lowry base to produce as mentioned ions in the following reaction.

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Answer 7

Chapter 15, Problem 15.109QP

(a)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

Answer 8

(a)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The hydrated aluminum ion acts as Bronsted-Lowry acid and it can react with ammonia a Bronsted-Lowry base to produce as mentioned ions in the following reaction.

$[Al(H2O)6]3+ + NH3 → [Al(H2O)5OH]2+ + NH4+acid base base acid$

The conjugate acid-base pairs are $([Al(H2O)6]3+, [Al(H2O)5OH]2+ ) and (NH4+,NH3)$

Answer 13

(b)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

(b)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Explanation of Solution

Ethanethiol acts as Bronsted-Lowry base and it can react with sulfuric acid a Bronsted-Lowry acid to produce as mentioned ions in the following reaction.

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Answer 14

(b)

Interpretation Introduction

Interpretation:

A chemical equation for the given information has to be written and the conjugate acid, base has to be identified.

Concept introduction:

Acid:

According to Bronsted-Lowry theory, a species which donates a proton in a proton transfer-reaction is said to be an acid.

Base:

According to Bronsted-Lowry theory, a species which accepts a proton in a proton transfer-reaction is said to be base.

Conjugated acid:

In the conjugate acid-base pair, a species which can donates a proton is said to be conjugated acid.

Conjugated base:

In the conjugate acid-base pair, a species which can accepts a proton is said to be conjugated base.

Answer 15

(b)

Expert Solution

Answer to Problem 15.109QP

The chemical equation and its conjugate acid, base is

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$

The conjugate acid-base pairs are $(CH3CH2SH2+, CH3CH2SH) and (H2SO4,HSO4-)$

Answer 16

(b)

Expert Solution

Answer 17

(b)

Expert Solution

Answer 18

Expert Solution

Answer 19

Explanation of Solution

Ethanethiol acts as Bronsted-Lowry base and it can react with sulfuric acid a Bronsted-Lowry acid to produce as mentioned ions in the following reaction.

$CH3CH2SH + H2SO4 → CH3CH2SH2+ + HSO4- base acid acid base$