BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
8th Edition
ISBN: 9781337687539
Author: Brown/Iverson/Anslyn/ Foote
Publisher: CENGAGE C
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Chapter 15, Problem 15.15P
Interpretation Introduction

Interpretation:

The product of the given reaction has to be shown.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD), Chapter 15, Problem 15.15P

Addition Reaction:

  • It is a type of reaction in which two reactants adding together to form a single product.
  • It can be said as a reverse reaction of elimination reaction.
  • It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Regiochemistry: if the epoxide is unsymmetrical, the nucleophile attacks at the less hindered position (less substituted).

Stereochemistry: when the attack takes place at the chiral center, inversion of configuration is observed. Only the center being attacked undergoes an inversion of configuration.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

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