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(a)
Interpretation:
The structural formula of missing compound in the given reaction has to be drawn.
Concept Introduction:
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Hemiacetal is an addition product that is obtained by reaction between aldehyde or ketone with alcohol. The general reaction of hemiacetal formation can be given as,
Acetal is formed when the formed hemiacetal reacts with further alcohol molecule so that the hydroxyl group in the hemiacetal is converted into alkoxy group. This can be shown as given below,
(b)
Interpretation:
The structural formula of missing compound in the given reaction has to be drawn.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Hemiacetal is an addition product that is obtained by reaction between aldehyde or ketone with alcohol. The general reaction of hemiacetal formation can be given as,
Acetal is formed when the formed hemiacetal reacts with further alcohol molecule so that the hydroxyl group in the hemiacetal is converted into alkoxy group. This can be shown as given below,
(c)
Interpretation:
The structural formula of missing compound in the given reaction has to be drawn.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Hemiacetal is an addition product that is obtained by reaction between aldehyde or ketone with alcohol. The general reaction of hemiacetal formation can be given as,
Acetal is formed when the formed hemiacetal reacts with further alcohol molecule so that the hydroxyl group in the hemiacetal is converted into alkoxy group. This can be shown as given below,
(d)
Interpretation:
The structural formula of missing compound in the given reaction has to be drawn.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Hemiacetal is an addition product that is obtained by reaction between aldehyde or ketone with alcohol. The general reaction of hemiacetal formation can be given as,
Acetal is formed when the formed hemiacetal reacts with further alcohol molecule so that the hydroxyl group in the hemiacetal is converted into alkoxy group. This can be shown as given below,
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Chapter 15 Solutions
General, Organic, and Biological Chemistry Seventh Edition
- Nonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward
- 6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward
- 4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forward
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