Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card
Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card
4th Edition
ISBN: 9781260269284
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 14.5, Problem 14.6P
Interpretation Introduction

(a)

Interpretation:

The alkene formed when the given alcohol is treated with H2SO4 should be determined. The major product should be predicted using Zaitsev rule.

  Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card, Chapter 14.5, Problem 14.6P , additional homework tip  1

Concept Introduction:

When H2O is lost from a material it is called dehydration. When an alcohol is treated with a strong acid such as H2SO4, a water molecule is lost by breaking two adjacent bonds C-OH and C-H and forming a new double bond, producing an alkene. This is an elimination reaction.

  Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card, Chapter 14.5, Problem 14.6P , additional homework tip  2

In this reaction more than one type of alkene may produce. But one of them is the major product.

According to Zaitsev rule, the major product alkene formed by elimination, is that which possess more alkyl groups bonded to it

Interpretation Introduction

(b)

Interpretation:

The alkene formed when the given alcohol is treated with H2SO4 should be determined. The major product should be predicted using Zaitsev rule.

  Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card, Chapter 14.5, Problem 14.6P , additional homework tip  3

Concept Introduction:

When H2O is lost from a material it is called dehydration. When an alcohol is treated with a strong acid such as H2SO4, a water molecule is lost by breaking two adjacent bonds C-OH and C-H and forming a new double bond, producing an alkene. This is an elimination reaction.

  Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card, Chapter 14.5, Problem 14.6P , additional homework tip  4

In this reaction more than one type of alkene may produce. But one of them is the major product.

According to Zaitsev rule, the major product alkene formed by elimination, is that which possess more alkyl groups bonded to it

Interpretation Introduction

(c)

Interpretation:

The alkene formed when the given alcohol is treated with H2SO4 should be determined. The major product should be predicted using Zaitsev rule.

  Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card, Chapter 14.5, Problem 14.6P , additional homework tip  5

Concept Introduction:

When H2O is lost from a material it is called dehydration. When an alcohol is treated with a strong acid such as H2SO4, a water molecule is lost by breaking two adjacent bonds C-OH and C-H and forming a new double bond, producing an alkene. This is an elimination reaction.

  Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card, Chapter 14.5, Problem 14.6P , additional homework tip  6

In this reaction more than one type of alkene may produce. But one of them is the major product.

According to Zaitsev rule, the major product alkene formed by elimination, is that which possess more alkyl groups bonded to it

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Chapter 14 Solutions

Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card

Ch. 14.5 - Prob. 14.4PPCh. 14.6 - Prob. 14.8PCh. 14.7 - Prob. 14.9PCh. 14.7 - Prob. 14.5PPCh. 14.7 - Prob. 14.10PCh. 14.7 - Name each ether. CH3OCH2CH2CH2CH3Ch. 14.7 - Prob. 14.11PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.13PCh. 14.9 - Prob. 14.14PCh. 14.9 - Prob. 14.15PCh. 14.9 - Prob. 14.16PCh. 14.9 - Prob. 14.17PCh. 14.9 - Prob. 14.18PCh. 14.9 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.10 - Give the IUPAC name for each thiol.Ch. 14.10 - Prob. 14.21PCh. 14.10 - Prob. 14.22PCh. 14 - Classify each alcohol as 1°, 2°, or 3o a....Ch. 14 - Prob. 24PCh. 14 - Prob. 25PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 27PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Draw the structure of l-propanethiol, a compound...Ch. 14 - Prob. 32PCh. 14 - Prob. 33PCh. 14 - Prob. 34PCh. 14 - Prob. 35PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 37PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 39PCh. 14 - Prob. 40PCh. 14 - Prob. 41PCh. 14 - Prob. 42PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 44PCh. 14 - Prob. 45PCh. 14 - Prob. 46PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 53PCh. 14 - Prob. 54PCh. 14 - Prob. 55PCh. 14 - Prob. 56PCh. 14 - Prob. 57PCh. 14 - Prob. 58PCh. 14 - Prob. 59PCh. 14 - Prob. 60PCh. 14 - Prob. 61PCh. 14 - Prob. 62PCh. 14 - Prob. 63PCh. 14 - Prob. 64PCh. 14 - Prob. 65PCh. 14 - Prob. 66PCh. 14 - Prob. 67PCh. 14 - Prob. 68PCh. 14 - Prob. 69PCh. 14 - Prob. 70PCh. 14 - Prob. 71PCh. 14 - Prob. 72PCh. 14 - Prob. 73PCh. 14 - Prob. 74PCh. 14 - Prob. 75PCh. 14 - Prob. 76PCh. 14 - Prob. 77PCh. 14 - Prob. 78PCh. 14 - Prob. 79PCh. 14 - Prob. 80PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 82PCh. 14 - Prob. 83PCh. 14 - Prob. 84PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 86PCh. 14 - Prob. 87PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 89PCh. 14 - Prob. 90PCh. 14 - Prob. 91PCh. 14 - Prob. 92PCh. 14 - Prob. 93PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 95CPCh. 14 - Dehydration of alcohol C forms two products of...
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