Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
1st Edition
ISBN: 9780134024516
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 14.5, Problem 14.10.2PE
Interpretation Introduction
Interpretation: The rank of the given reverse reactions from slowest to fastest is to be determined.
Concept Introduction: The activation energy is the minimum energy required to start the given reaction. Higher the activation energy, slow will be the reaction and lower the activation energy, fast will be the reaction.
To determine: The rank of the given reactions from slowest to fastest.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Do you do chemistry assignments
Using the conditions of spontaneity to deduce the signs of AH and AS
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
This reaction is always spontaneous, but
proceeds slower at temperatures above
120. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous except above
117. °C.
AS is
(pick one)
ΔΗ is
(pick one)
This reaction is slower below 20. °C than
C
above.
AS is
|(pick one)
?
18
Ar
1
Calculating the pH at equivalence of a titration
Try Again
Your answer is incorrect.
0/5
a
A chemist titrates 70.0 mL of a 0.7089 M hydrocyanic acid (HCN) solution with 0.4574M KOH solution at 25 °C. Calculate the pH at equivalence. The pK of
hydrocyanic acid is 9.21.
Round your answer to 2 decimal places.
Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added.
pH
=
11.43]
G
00.
18
Ar
B•
Chapter 14 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
Ch. 14.2 - Identify the force present and explain whether...Ch. 14.2 - Identify the force present and explain whether...Ch. 14.2 - Which of the following cannot leave or enter a...Ch. 14.2 - Prob. 14.2.2PECh. 14.2 - According to the first law of thermodynamics, what...Ch. 14.2 - Write an equation that expresses the first law of...Ch. 14.3 - Calculate AB and determine whether the process is...Ch. 14.3 - For the following processes, calculate the change...Ch. 14.3 - A gas is confined to a cylinder fitted with a...Ch. 14.3 - Consider a system consisting of two oppositely...
Ch. 14.3 - Prob. 14.6.1PECh. 14.3 - Indicate which of the following is independent of...Ch. 14.4 - During a normal breath, our lungs expand about...Ch. 14.4 - How much work (in J) is involved in a chemical...Ch. 14.4 - Why is the change in enthalpy usually easier to...Ch. 14.4 - Under what condition will the enthalpy change of a...Ch. 14.4 - Assume that the following reaction occurs at...Ch. 14.4 - Suppose that the gas-phase reaction 2NO(g) + 02(g)...Ch. 14.5 - Which of the following statements is or are true?...Ch. 14.5 - Prob. 14.10.2PECh. 14.5 - In the accompanying cylinder diagram, a chemical...Ch. 14.5 - Prob. 14.11.2PECh. 14.6 - Consider the two diagrams that follow. Based on...Ch. 14.6 - Consider the conversion of compound A into...Ch. 14.6 - What is the electrostatic potential energy (in...Ch. 14.6 - What is the electrostatic potential energy (in...Ch. 14.6 - Prob. 14.14.1PECh. 14.6 - Use the equations given in Problem 5.15 to...Ch. 14.6 - A sodium ion, Na+, with a charge of 1.6 x 10-19 C...Ch. 14.6 - A magnesium ion, Mg2+, with a charge of 3.2 x...Ch. 14 -
5.74 Using values from Appendix C, calculate the...Ch. 14 - Complete combustion of 1 mol of acetone (C2H6O)...Ch. 14 -
5.87 Consider the reaction 2H(g) + O2(g) ...Ch. 14 - The air bags that provide protection in...Ch. 14 -
5.111 From the following data for three...Ch. 14 -
5.123 Consider two solutions, the first being...Ch. 14 -
For each of the following transitions, give the...Ch. 14 - In this chapter, we have learned about the...Ch. 14 -
6.12 State where in the periodic table these...Ch. 14 - Einstein's 1905 paper on the photoelectric effect...Ch. 14 -
5.48 Consider the decomposition of liquid...Ch. 14 - Under constant-volume conditions, the heat of...Ch. 14 - Given the data use Hess's law to calculate H for...Ch. 14 -
5.67
What is meant by the term standard...Ch. 14 - S
5.68
What is the value of the standard enthalpy...Ch. 14 - For each of the following compounds, write a...Ch. 14 - Write balanced equations that describe the...Ch. 14 - The following is known as the thermite reaction:...Ch. 14 - (a) What are the units usually used to express the...Ch. 14 - Using values from Appendix C , calculate the...Ch. 14 -
5.77 Gasoline is composed primarily of...Ch. 14 - Prob. 21ECh. 14 - Ethanol (C2H5OH) is blended with gasoline as an...Ch. 14 -
5.80 Methanol (CH3OH) is used as a fuel in race...Ch. 14 -
5.81 Without doing any calculations, predict the...Ch. 14 -
5.82 Without doing any calculations, predict...Ch. 14 - Use bond enthalpies in Table 5.4 Q to estimate for...Ch. 14 - Use bond enthalpies in Table 5.40 to estimate for...Ch. 14 - Use enthalpies of formation given in Appendix C to...Ch. 14 -
5.86
The nitrogen atoms in an N2 molecule are...Ch. 14 -
5.89
What is meant by the term fuel value?
Which...Ch. 14 -
5.90
Which releases the most energy when...Ch. 14 -
5.91
A serving of a particular ready-to-serve...Ch. 14 -
5.92 A pound of plain M&M® candies contains 96 g...Ch. 14 -
5.93 The heat of combustion of fructose,...Ch. 14 -
5.94 The heat of combustion of ethanol,...Ch. 14 -
5.95 The standard enthalpies of formation of...Ch. 14 -
5.98 It is interesting to compare the ‘fuel...Ch. 14 - At the end of 2012, global population was about...Ch. 14 - Prob. 39ECh. 14 - (a) For a generic second-order reaction, what...Ch. 14 - A sample of gas is contained in a...Ch. 14 - Limestone stalactites and stalagmites are formed...Ch. 14 - Consider the systems shown in Figure 5.10. In one...Ch. 14 -
5.105 A house is designed to have passive solar...Ch. 14 -
5.108 A coffee-cup calorimeter of the type shown...Ch. 14 -
5.107
When a 0.235-9 sample of benzoic acid is...Ch. 14 -
5.108 Meals-ready-to-eat (MREs) are military...Ch. 14 - 5.109 Burning methane in oxygen can produce three...Ch. 14 - Prob. 49ECh. 14 - Ammonia (NH3) boils at -33 °C; at this temperature...Ch. 14 - Prob. 51ECh. 14 - Prob. 52ECh. 14 -
5.116 TheSun supplies about 1.0 kilowatt of...Ch. 14 -
5.117 Itis estimated that the net amount of...Ch. 14 -
5.118 At 20 °C (approximately room temperature)...Ch. 14 - Suppose an Olympic diver who weighs 52.0 kg...Ch. 14 -
5.120 Consider the combustion of a single...Ch. 14 -
5.121 Consider the following unbalanced...Ch. 14 - Consider the following acid-neutralization...Ch. 14 -
5.125 A sample of a hydrocarbon is combusted...Ch. 14 -
5.126 The methane molecule, CH4, has the geometry...Ch. 14 -
5.127 One of the best-selling light, or...Ch. 14 - A source of electromagnetic radiation produces...Ch. 14 - Which type of visible light has a longer...Ch. 14 - Consider the following three statements: For any...Ch. 14 - Prob. 66ECh. 14 - Prob. 67ECh. 14 -
A laser emits light that has a frequency of 4.69...Ch. 14 - Prob. 69ECh. 14 - Calculate the velocity of a neutron whose de...Ch. 14 - An orbital has n = 4 and ml = 0, 1, 2, 3 -3, - 2,...Ch. 14 -
What is the designation for the subshell with = 5...Ch. 14 - How many of the elements in the second row of the...Ch. 14 - Write the electron configuration for silicon,...Ch. 14 - A certain atom has an ns2np2electron configuration...Ch. 14 -
Which group of elements is characterized by an...Ch. 14 -
A certain atom has a [noble gas]5s24d105p4...Ch. 14 - Prob. 78ECh. 14 - Prob. 79ECh. 14 -
6.2 A popular kitchen appliance produces...Ch. 14 - 6.3 The following diagrams represent two...Ch. 14 -
6.4 Stars do not all have the same temperature....Ch. 14 - 6 5 The familiar phenomenon of a rainbow results...Ch. 14 -
6.7 A certain quantum mechanical system has the...Ch. 14 - Consider the three electronic transitions in a...Ch. 14 - Prob. 86ECh. 14 -
6.9 The contour representation of one of the...Ch. 14 -
6.10 The accompanying drawing shows a contour...Ch. 14 -
8.11 Four possible electron configurations for a...Ch. 14 -
6.14
a What is the relationship between the...Ch. 14 - Label each of the following statements as true or...Ch. 14 - Determine which of the following statements are...Ch. 14 - Arrange the following kinds of electromagnetic...Ch. 14 - List the following types of electromagnetic...Ch. 14 - What is the frequency of radiation that has a...Ch. 14 - What is the frequency of radiation whose...Ch. 14 - A laser pointer used in a lecture hall emits light...Ch. 14 - Prob. 98AECh. 14 - If human height were quantized in 1-foot...Ch. 14 - A gas is confined to a cylinder under constant...Ch. 14 - The complete combustion of ethanol, C2H5OH(l), to...Ch. 14 - The decomposition of Ca(OH)2(s) into CaO(s) and...Ch. 14 - Prob. 103AECh. 14 -
5.42 Without referring to tables, predict which...Ch. 14 - Consider the following reaction: 2 Mg(s) + 02(g)2...Ch. 14 -
544 Consider the following reaction:
2...Ch. 14 - When solutions containing silver ions and chloride...Ch. 14 - At one time, a common means of forming small...Ch. 14 - Prob. 109AECh. 14 - 5.49
a What are the units of molar heat...Ch. 14 - Two solid objects, A and B, are placed in boiling...Ch. 14 - What is the specific heat of liquid water? What is...Ch. 14 -
5.52
a. Which substance in Table 5.2 requires...Ch. 14 - The specific heat of octane, C8H18(l), is 2.22...Ch. 14 -
6.54 Consider the data about gold metal in...Ch. 14 - When a 6-50-g sample of solid sodium hydroxide...Ch. 14 -
5.56
a. When a 4 25-g sample of solid ammonium...Ch. 14 - A 2.200-g sample of quinone (C5H402) is burned in...Ch. 14 -
8.68 A 1.800-g sample of phenol (C6H5OH) was...Ch. 14 -
5.60 Under constant-volume conditions, the heat...Ch. 14 -
5.61 Can you use an approach similar to Hess's...Ch. 14 -
5.62 Consider the following hypothetical...Ch. 14 - Calculate the enthalpy change for the reaction...Ch. 14 - From the enthalpies of reaction calculate H for...Ch. 14 - From the enthalpies of reaction Calculate H for...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Biological Macromolecules Naming and drawing the products of aldose oxidation and reduction aw a Fischer projection of the molecule that would produce L-ribonic acid if it were subjected to mildly oxidizing reaction conditions. Click and drag to start drawing a structure. X AP ‡ 1/5 Naor Explanation Check McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Center Accessibilarrow_forward● Biological Macromolecules Identifying the parts of a disaccharide Take a look at this molecule, and then answer the questions in the table below it. CH2OH O H H H OH OH OH H H CH2OH H O OH H OH H H H H OH Is this a reducing sugar? Does this molecule contain a glycosidic bond? If you said this molecule does contain a glycosidic bond, write the symbol describing it. If you said this molecule does contain a glycosidic bond, write the common names (including anomer and enantiomer labels) of the molecules that would be released if that bond were hydrolyzed. If there's more than one molecule, separate each name with a comma. Explanation Check O yes X O no ○ yes O no Uarrow_forwardThe aim of the lab is to measure the sodium content from tomato sauce using the Mohr titration method. There are two groups being: Regular Tomato sauce & Salt Reduced tomato sauce QUESTION: State how you would prepare both Regular & Salt reduced tomato sauce samples for chemical analysis using the Mohr titration methodarrow_forward
- Using the conditions of spontaneity to deduce the signs of AH and AS Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions A The reverse of this reaction is always spontaneous but proceeds faster at temperatures above -48. °C. ΔΗ is (pick one) ✓ AS is (pick one) B This reaction is spontaneous except below 114. °C but proceeds at a slower rate below 135. °C. ΔΗ is (pick one) AS is (pick one) ΔΗ is C This reaction is exothermic and proceeds faster at temperatures above -43. °C. (pick one) AS is (pick one) v Х 5 ? 18 Ararrow_forwardion. A student proposes the following Lewis structure for the perchlorate (CIO) io : :0: : Cl : - - : :0: ك Assign a formal charge to each atom in the student's Lewis structure. atom central O formal charge ☐ top O ☐ right O ☐ bottom O ☐ Cl ☐arrow_forwardDecide whether these proposed Lewis structures are reasonable. proposed Lewis structure Yes. Is the proposed Lewis structure reasonable? Cl- : 2: :Z: :Z: N—N : 0: C C1: O CO No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* ☐ Yes. No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | Yes. No, it has the wrong number of valence electrons. The correct number is: No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "0,0". ☑arrow_forward
- Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions ΔΗ is (pick one) A This reaction is faster above 103. °C than below. AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous only above -9. °C. AS is (pick one) ΔΗ is (pick one) C The reverse of this reaction is always spontaneous. AS is (pick one) 18 Ararrow_forwardUse the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions A The reverse of this reaction is always spontaneous but proceeds slower at temperatures below 41. °C. ΔΗ is (pick one) AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous except above 94. °C. AS is (pick one) This reaction is always spontaneous, but ΔΗ is (pick one) C proceeds slower at temperatures below −14. °C. AS is (pick one) Х 00. 18 Ar 무ㅎ B 1 1arrow_forwardDraw the product of the reaction shown below. Ignore inorganic byproducts. + H CH3CH2OH HCI Drawingarrow_forward
- please explain this in simple termsarrow_forwardK Most Reactive Na (3 pts) Can the metal activity series (shown on the right) or a standard reduction potential table explain why potassium metal can be prepared from the reaction of molten KCI and Na metal but sodium metal is not prepared from the reaction of molten NaCl and K metal? Show how (not). Ca Mg Al с Zn Fe Sn Pb H Cu Ag Au Least Reactivearrow_forward(2 pts) Why is O2 more stable as a diatomic molecule than S2?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY