
EBK BASIC CHEMISTRY
5th Edition
ISBN: 8220101472335
Author: Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 14.3, Problem 14.17QAP
What is meant by the phrase ”A strong acid as a weak conjugate base”?
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 14 Solutions
EBK BASIC CHEMISTRY
Ch. 14.1 - Indicate whether each of the following statements...Ch. 14.1 - Prob. 14.2QAPCh. 14.1 - Prob. 14.3QAPCh. 14.1 - Name each of the following acids or bases: a....Ch. 14.1 - Write formulas for each of the following acids and...Ch. 14.1 - Write formulas for each of the following acids and...Ch. 14.2 - Identify the reactant that is a Bronsted-Lowry...Ch. 14.2 - Prob. 14.8QAPCh. 14.2 - Prob. 14.9QAPCh. 14.2 - Prob. 14.10QAP
Ch. 14.2 - Prob. 14.11QAPCh. 14.2 - Prob. 14.12QAPCh. 14.2 - Identify the Bronsted-Lowry acid-base pairs in...Ch. 14.2 - Prob. 14.14QAPCh. 14.2 - Prob. 14.15QAPCh. 14.2 - Prob. 14.16QAPCh. 14.3 - What is meant by the phrase ”A strong acid as a...Ch. 14.3 - Prob. 14.18QAPCh. 14.3 - Prob. 14.19QAPCh. 14.3 - Prob. 14.20QAPCh. 14.3 - Prob. 14.21QAPCh. 14.3 - Prob. 14.22QAPCh. 14.3 - Prob. 14.23QAPCh. 14.3 - Prob. 14.24QAPCh. 14.3 - Prob. 14.25QAPCh. 14.3 - Prob. 14.26QAPCh. 14.4 - Answer true or false for each of the following: A...Ch. 14.4 - Prob. 14.28QAPCh. 14.4 - Prob. 14.29QAPCh. 14.4 - Consider the following acids and their...Ch. 14.4 - Prob. 14.31QAPCh. 14.4 - Prob. 14.32QAPCh. 14.5 - Why are the concentrations of H3O+ and OH- equal...Ch. 14.5 - Prob. 14.34QAPCh. 14.5 - Prob. 14.35QAPCh. 14.5 - Prob. 14.36QAPCh. 14.5 - Prob. 14.37QAPCh. 14.5 - Prob. 14.38QAPCh. 14.5 - Prob. 14.39QAPCh. 14.5 - Prob. 14.40QAPCh. 14.5 - 11.41 Calculate the of each aqueous solution with...Ch. 14.5 - Prob. 14.42QAPCh. 14.6 - Prob. 14.43QAPCh. 14.6 - Prob. 14.44QAPCh. 14.6 - State whether each of the following solutions is...Ch. 14.6 - State whether each of the following solutions is...Ch. 14.6 - Prob. 14.47QAPCh. 14.6 - Prob. 14.48QAPCh. 14.6 - Prob. 14.49QAPCh. 14.6 - Prob. 14.50QAPCh. 14.6 - Prob. 14.51QAPCh. 14.6 - Prob. 14.52QAPCh. 14.6 - Prob. 14.53QAPCh. 14.6 - Prob. 14.54QAPCh. 14.7 - Prob. 14.55QAPCh. 14.7 - Complete and balance the equation for each of the...Ch. 14.7 - Prob. 14.57QAPCh. 14.7 - Prob. 14.58QAPCh. 14.7 - Prob. 14.59QAPCh. 14.7 - Prob. 14.60QAPCh. 14.8 - Prob. 14.61QAPCh. 14.8 - Prob. 14.62QAPCh. 14.8 - Prob. 14.63QAPCh. 14.8 - Prob. 14.64QAPCh. 14.8 - Prob. 14.65QAPCh. 14.8 - Prob. 14.66QAPCh. 14.8 - A solution of 0.204 M NaOH is used to titrate 50.0...Ch. 14.8 - Prob. 14.68QAPCh. 14.9 - Which of the following represents a buffer system?...Ch. 14.9 - Prob. 14.70QAPCh. 14.9 - Prob. 14.71QAPCh. 14.9 - Prob. 14.72QAPCh. 14.9 - Prob. 14.73QAPCh. 14.9 - Prob. 14.74QAPCh. 14.9 - Prob. 14.75QAPCh. 14.9 - Prob. 14.76QAPCh. 14.9 - Why would the pH of your blood plasma increase if...Ch. 14.9 - Why would the pH of your blood plasma decrease if...Ch. 14.9 - Prob. 14.79QAPCh. 14.9 - Someone with severe diabetes obtains energy by the...Ch. 14 - Prob. 14.81FUCh. 14 - When food enters the stomach, HCl is released and...Ch. 14 - Prob. 14.83FUCh. 14 - Prob. 14.84FUCh. 14 - Prob. 14.85FUCh. 14 - Prob. 14.86FUCh. 14 - Prob. 14.87FUCh. 14 - Prob. 14.88FUCh. 14 - Prob. 14.89UTCCh. 14 - Prob. 14.90UTCCh. 14 - Prob. 14.91UTCCh. 14 - Prob. 14.92UTCCh. 14 - Prob. 14.93UTCCh. 14 - Prob. 14.94UTCCh. 14 - Prob. 14.95UTCCh. 14 - Prob. 14.96UTCCh. 14 - Prob. 14.97UTCCh. 14 - Prob. 14.98UTCCh. 14 - Identify each of the following as an acid, base,...Ch. 14 - Idenúfy each of the following as an acid, base, or...Ch. 14 - Complete the following table: (11.2) Acid...Ch. 14 - Complete the following table: (11.2) Base...Ch. 14 - Using Table 11.3, identify the stronger acid in...Ch. 14 - Prob. 14.104AQAPCh. 14 - Determine the pH for each of the following...Ch. 14 - Determine the pH for each of the following...Ch. 14 - Prob. 14.107AQAPCh. 14 - Prob. 14.108AQAPCh. 14 - Calculate the [H3O+] and [OH] for a solution with...Ch. 14 - Calculate the [H3O+]and [OH]for a solution with...Ch. 14 - Solution A has a pH of 4.5, and solution B has a...Ch. 14 - Solution X has a pH of 9.5, and solution Y has a...Ch. 14 - What is the pH of a solution prepared by...Ch. 14 - Prob. 14.114AQAPCh. 14 - For each of the following: (11.2, 11.3) 1. H2S a....Ch. 14 - Prob. 14.116CQCh. 14 - Prob. 14.117CQCh. 14 - Prob. 14.118CQCh. 14 - Prob. 14.119CQCh. 14 - Prob. 14.120CQCh. 14 - Prob. 14.121CQCh. 14 - Prob. 14.122CQCh. 14 - Prob. 14.123CQCh. 14 - Prob. 14.124CQCh. 14 - Prob. 14.125CQCh. 14 - Prob. 14.126CQCh. 14 - Prob. 14.127CQCh. 14 - Prob. 14.128CQCh. 14 - Prob. 14.129CQCh. 14 - Prob. 14.130CQCh. 14 - Prob. 21CICh. 14 - Prob. 22CICh. 14 - Prob. 23CICh. 14 - In wine-making, glucose C6H12O6 from grapes...Ch. 14 - Prob. 25CICh. 14 - Prob. 26CICh. 14 - Prob. 27CICh. 14 - In a teaspoon (5.0 mL) of a liquid antacid, there...Ch. 14 - Prob. 29CICh. 14 - Prob. 30CICh. 14 - A volume of 200.0 mL of a carbonic acid buffer for...Ch. 14 - In the kidneys, the ammonia buffer system buffers...
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