GENERAL ORGANIC+BIOCHEM.-ACCESS>CUSTOM<
10th Edition
ISBN: 9781265799274
Author: Denniston
Publisher: MCG CUSTOM
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Chapter 14.1, Problem 14.3Q
Interpretation Introduction
Interpretation:
The reason why carboxylic acids are more polar and have higher boiling point than an aldehyde has to be predicted.
Concept Introduction:
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Use solubility rules to provide balance molecular equation, total, and net ionic equation
Br
HO
?
HO
✓
OH
Use the literature Ka value of the acetic acid, and the data below to answer these questions. Note: You will not use the experimental titration graphs to answer the questions that follow.
Group #1:
Buffer pH = 4.35
Group #2:
Buffer pH = 4.70
Group #3:
Buffer pH = 5.00
Group #4:
Buffer pH = 5.30
Use the Henderson-Hasselbalch equation, the buffer pH provided and the literature pKa value of acetic acid to perform the following:
a) calculate the ratios of [acetate]/[acetic acid] for each of the 4 groups buffer solutions above.
b) using the calculated ratios, which group solution will provide the best optimal buffer (Hint: what [acetate]/[acetic acid] ratio value is expected for an optimal buffer?)
c) explain your choice
Chapter 14 Solutions
GENERAL ORGANIC+BIOCHEM.-ACCESS>CUSTOM<
Ch. 14.1 - Assuming that each of the following pairs of...Ch. 14.1 - Assuming that each of the following pairs of...Ch. 14.1 - Prob. 14.3QCh. 14.1 - Why would you predict that a carboxylic acid would...Ch. 14.1 - Prob. 14.1PPCh. 14.1 - Prob. 14.5QCh. 14.1 - Prob. 14.6QCh. 14.1 - Prob. 14.2PPCh. 14.1 - Prob. 14.3PPCh. 14.1 - Prob. 14.4PP
Ch. 14.1 - Prob. 14.5PPCh. 14.1 - Prob. 14.6PPCh. 14.2 - Prob. 14.7PPCh. 14.2 - Prob. 14.8PPCh. 14.2 - Prob. 14.9PPCh. 14.2 - Prob. 14.7QCh. 14.2 - Prob. 14.8QCh. 14.3 - Prob. 14.10PPCh. 14.3 - Write the common and IUPAC names for each of the...Ch. 14.3 - Prob. 14.9QCh. 14.3 - Prob. 14.10QCh. 14 - Prob. 14.11QPCh. 14 - Prob. 14.12QPCh. 14 - Prob. 14.13QPCh. 14 - Prob. 14.14QPCh. 14 - Prob. 14.15QPCh. 14 - Prob. 14.16QPCh. 14 - Prob. 14.17QPCh. 14 - Which member in each of the following pairs is...Ch. 14 - Prob. 14.19QPCh. 14 - Prob. 14.20QPCh. 14 - Prob. 14.21QPCh. 14 - Prob. 14.22QPCh. 14 - Prob. 14.23QPCh. 14 - Prob. 14.24QPCh. 14 - Prob. 14.25QPCh. 14 - Prob. 14.26QPCh. 14 - Prob. 14.27QPCh. 14 - Prob. 14.28QPCh. 14 - Prob. 14.29QPCh. 14 - Prob. 14.30QPCh. 14 - Prob. 14.31QPCh. 14 - Prob. 14.32QPCh. 14 - Prob. 14.33QPCh. 14 - Prob. 14.34QPCh. 14 - Prob. 14.35QPCh. 14 - Prob. 14.36QPCh. 14 - Prob. 14.37QPCh. 14 - Prob. 14.38QPCh. 14 - Prob. 14.39QPCh. 14 - Prob. 14.40QPCh. 14 - Prob. 14.41QPCh. 14 - Prob. 14.42QPCh. 14 - Prob. 14.43QPCh. 14 - Prob. 14.44QPCh. 14 - Prob. 14.45QPCh. 14 - Prob. 14.46QPCh. 14 - Prob. 14.47QPCh. 14 - Prob. 14.48QPCh. 14 - Write an equation representing the oxidation of...Ch. 14 - Prob. 14.50QPCh. 14 - Prob. 14.51QPCh. 14 - Prob. 14.52QPCh. 14 - Prob. 14.54QPCh. 14 - Write an equation representing the neutralization...Ch. 14 - Prob. 14.56QPCh. 14 - Prob. 14.57QPCh. 14 - Prob. 14.58QPCh. 14 - Prob. 14.59QPCh. 14 - Prob. 14.60QPCh. 14 - Prob. 14.61QPCh. 14 - Prob. 14.62QPCh. 14 - Prob. 14.63QPCh. 14 - Draw condensed formulas for each of the following...Ch. 14 - Prob. 14.65QPCh. 14 - Prob. 14.66QPCh. 14 - Prob. 14.67QPCh. 14 - Prob. 14.68QPCh. 14 - Prob. 14.69QPCh. 14 - Prob. 14.70QPCh. 14 - Prob. 14.71QPCh. 14 - Prob. 14.72QPCh. 14 - Prob. 14.73QPCh. 14 - Prob. 14.74QPCh. 14 - Prob. 14.75QPCh. 14 - Prob. 14.76QPCh. 14 - Prob. 14.77QPCh. 14 - Prob. 14.78QPCh. 14 - Prob. 14.79QPCh. 14 - Prob. 14.80QPCh. 14 - Prob. 14.81QPCh. 14 - Prob. 14.82QPCh. 14 - Prob. 14.83QPCh. 14 - Prob. 14.84QPCh. 14 - Prob. 14.85QPCh. 14 - Prob. 14.86QPCh. 14 - Prob. 14.87QPCh. 14 - Prob. 14.88QPCh. 14 - Prob. 14.89QPCh. 14 - Prob. 14.90QPCh. 14 - Prob. 14.91QPCh. 14 - Prob. 14.92QPCh. 14 - Prob. 14.93QPCh. 14 - Prob. 14.94QPCh. 14 - Prob. 14.95QPCh. 14 - Prob. 14.96QPCh. 14 - Prob. 14.97QPCh. 14 - What is meant by a phosphoanhydride bond?
Ch. 14 - Prob. 14.99QPCh. 14 - Prob. 14.100QPCh. 14 - Prob. 14.101QPCh. 14 - Prob. 14.102QPCh. 14 - Prob. 14.103QPCh. 14 - Prob. 2MCPCh. 14 - Consider the Chapter Map, and explain the...Ch. 14 - Prob. 4MCPCh. 14 - Prob. 6MCPCh. 14 - Triglycerides are the major lipid storage form in...Ch. 14 - Prob. 10MCPCh. 14 - Acetyl coenzyme A (acetyl CoA) can serve as a...Ch. 14 - Prob. 12MCP
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