The rate-limiting step.

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Answer 1

Question

Chapter 14, Problem 96E

(a)

Interpretation Introduction

To determine: The rate-limiting step.

(b)

Interpretation Introduction

To determine: The order of the reaction.

(c)

Interpretation Introduction

To check: Whether the reaction is exothermic or endothermic.

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a. Determine the electrochemical potential of the following cell using E°Mg2+/Mg = -2.362 V. Mg | Mg2+ (a=104) || H* (a = 4) | H2 (p = 0.5 bar) | Pt b. A galvanic chain consists of Co²+ / Co and Ag+ / Ag half-cells with EºCo²+/Co = -0.282 V and Eº Ag+/Ag = 0.799 V. Determine which half-cell will be reduced and which one will be oxidised. Furthermore, calculate the electrochemical potential as well as the equilibrium constant of the whole cell at i. [Co²+] = 0.1 M and [Ag+] = 0.5 M ii. [Co²+] = 0.001 M and [Ag*] = 1.5 M

The equilibrium voltage of the following cell has been measured at 0.522 V at 25 °C. Pt | H2, g❘ HClaq || AgClaq | Ags State the redox reactions present in this cell. Calculate the pH value of the electrolyte solution with KL, AgCl = 1.96 · 10-10 mol² / L². Assume that the concentrations of H+ and Clare equal.

Here are the energies (in kcal/mol) for staggered and eclipsed interactions for CH, CC, and CBr bonds eclipsed (0°) staggered (60°) bonds CH/CH 1.0 0.0 CH/CC 1.3 0.0 Br: CC/CC 3.0 0.9 Br CH/CBr 1.8 0.0 CC / CBr 3.3 1.0 CBr / CBr 3.7 1.2 a) I've drawn the Newman projection for one of the staggered conformations of the molecule above, looking down the C2-C3 bond. Draw Newman projections for the other two staggered and the three eclipsed conformations (in order). CH₂ H3C. H' H Br b) Calculate the relative energies for each of the conformations and write them below each conformation.

Answer 2

Question

Chapter 14, Problem 96E

(a)

Interpretation Introduction

To determine: The rate-limiting step.

(b)

Interpretation Introduction

To determine: The order of the reaction.

(c)

Interpretation Introduction

To check: Whether the reaction is exothermic or endothermic.

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Answer 3

Question

Chapter 14, Problem 96E

(a)

Interpretation Introduction

To determine: The rate-limiting step.

(b)

Interpretation Introduction

To determine: The order of the reaction.

(c)

Interpretation Introduction

To check: Whether the reaction is exothermic or endothermic.

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Answer 4

Question

Chapter 14, Problem 96E

(a)

Interpretation Introduction

To determine: The rate-limiting step.

(b)

Interpretation Introduction

To determine: The order of the reaction.

(c)

Interpretation Introduction

To check: Whether the reaction is exothermic or endothermic.

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Answer 5

Chapter 14, Problem 96E

(a)

Interpretation Introduction

To determine: The rate-limiting step.

(b)

Interpretation Introduction

To determine: The order of the reaction.

(c)

Interpretation Introduction

To check: Whether the reaction is exothermic or endothermic.

Answer 6

Chapter 14, Problem 96E

(a)

Interpretation Introduction

To determine: The rate-limiting step.

Answer 7

Chapter 14, Problem 96E

(a)

Interpretation Introduction

To determine: The rate-limiting step.

Answer 8

(b)

Interpretation Introduction

To determine: The order of the reaction.

Answer 9

(b)

Interpretation Introduction

To determine: The order of the reaction.

Answer 10

(c)

Interpretation Introduction

To check: Whether the reaction is exothermic or endothermic.

Answer 11

(c)

Interpretation Introduction

To check: Whether the reaction is exothermic or endothermic.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14 - Prob. 1SAQ Ch. 14 - Q2. Dinitrogen monoxide decomposes into nitrogen...Ch. 14 - Q3. This plot shows the rate of the decomposition...Ch. 14 - Q4. For the reaction 2 A + B → C, the initial rate...Ch. 14 - Prob. 5SAQ Ch. 14 - Prob. 6SAQ Ch. 14 - Prob. 7SAQ Ch. 14 - Prob. 8SAQ Ch. 14 - Q9. The rate constant of a reaction is measured at...Ch. 14 - Prob. 10SAQ

The rate-limiting step.

To determine: The rate-limiting step.

To determine: The order of the reaction.

To check: Whether the reaction is exothermic or endothermic.

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Chapter 14 Solutions