INTRO TO CHEMISTRY EBK ACCESS CARD >I<
5th Edition
ISBN: 9781260916430
Author: BAUER
Publisher: MCG
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Chapter 14, Problem 88QP
Interpretation Introduction
Interpretation:
The reasons behind ‘bromide ions can be oxidized but cannot be reduced’ and ‘manganese in permanganate ion can be reduced but not oxidized’ are to be explained.
Concept Introduction:
Oxidation is a process that involves the loss of electrons from an atom, which leads to the formation of a positively charged species.
Reduction is a process that involves the gain of electrons in an atom, which leads to the formation of a negatively charged species.
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LTS
Solid:
AT=Te-Ti
Trial 1
Trial 2
Trial 3
Average
ΔΗ
Mass water, g
24.096
23.976
23.975
Moles of solid, mol
0.01763
001767
0101781
Temp. change, °C
2.9°C
11700
2.0°C
Heat of reaction, J
-292.37J -170.473
-193.26J
AH, kJ/mole
16.58K 9.647 kJ 10.85 kr
16.58K59.64701
KJ
mol
12.35k
Minimum AS,
J/mol K
41.582
mol-k
Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn &
Show your calculations for:
AH in J and then in kJ/mole for Trial 1:
qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J
qsin =
qrxn =
292.35 292.37J
AH in J = 292.375 0.2923kJ
0.01763m01
=1.65×107
AH in kJ/mol =
=
16.58K
0.01763mol
mol
qrx
Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con
Kelvin.)
AS=AHIT
(1.65×10(9.64×103) + (1.0
Jimai
For the compound: C8H17NO2
Use the following information to come up with a plausible structure:
8
This compound has "carboxylic acid amide" and ether functional groups.
The peaks at 1.2ppm are two signals that are overlapping one another.
One of the two signals is a doublet that represents 6 hydrogens; the
other signal is a quartet that represents 3 hydrogens.
Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling
point, choose 2 next to the substance with the next highest boiling point, and so on.
substance
C
D
chemical symbol,
chemical formula
or Lewis structure.
CH,-N-CH,
CH,
H
H 10: H
C-C-H
H H H
Cale
H 10:
H-C-C-N-CH,
Bri
CH,
boiling point
(C)
Сен
(C) B
(Choose
Chapter 14 Solutions
INTRO TO CHEMISTRY EBK ACCESS CARD >I<
Ch. 14 - Prob. 1QCCh. 14 - Prob. 2QCCh. 14 - How do chemical reactions provide electricity in...Ch. 14 - Prob. 4QCCh. 14 - Prob. 5QCCh. 14 - How do oxidation-reduction reactions generate...Ch. 14 - Prob. 7QCCh. 14 - Prob. 1PPCh. 14 - Assign oxidation numbers to each element in the...Ch. 14 - Prob. 3PP
Ch. 14 - Cadmium reacts with nickel(II) nitrate according...Ch. 14 - The reaction that occurs in most camera batteries...Ch. 14 - Prob. 6PPCh. 14 - Balance the following equation that occurs in...Ch. 14 - Prob. 8PPCh. 14 - Prob. 9PPCh. 14 - Prob. 1QPCh. 14 - Prob. 2QPCh. 14 - Prob. 3QPCh. 14 - Why is oxidation always coupled with reduction?Ch. 14 - Prob. 5QPCh. 14 - How do you know when something is reduced?Ch. 14 - When a strip of magnesium metal is placed in an...Ch. 14 - When a strip of nickel metal is placed in an...Ch. 14 - Consider the following reaction:...Ch. 14 - Consider the following reaction:...Ch. 14 - Prob. 11QPCh. 14 - Prob. 12QPCh. 14 - Indicate the oxidation number of each element in...Ch. 14 - Indicate the oxidation number of each element in...Ch. 14 - Prob. 15QPCh. 14 - Prob. 16QPCh. 14 - What is the oxidation number of phosphorus in each...Ch. 14 - Determine the oxidation number of chlorine in each...Ch. 14 - Indicate the oxidation number of phosphorus in...Ch. 14 - Determine the oxidation number of iodine in each...Ch. 14 - The ion shown has a charge of 2. What are the...Ch. 14 - The ion shown has a charge of 1. What are the...Ch. 14 - Prob. 23QPCh. 14 - Indicate the oxidation number of chromium in each...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Prob. 28QPCh. 14 - Prob. 29QPCh. 14 - Prob. 30QPCh. 14 - Under certain conditions, nitrogen gas reacts with...Ch. 14 - Under certain conditions, solid carbon reacts with...Ch. 14 - Consider the following reaction:...Ch. 14 - In the following oxidation-reduction reactions,...Ch. 14 - In the following oxidation-reduction reactions,...Ch. 14 - Draw a diagram of a voltaic cell that corresponds...Ch. 14 - Draw a diagram of a voltaic cell that corresponds...Ch. 14 - The figure shows a molecular-level representation...Ch. 14 - The figure shows a molecular-level representation...Ch. 14 - The reaction that occurs in a lead-acid battery is...Ch. 14 - The reaction that occurs in a lead-acid battery is...Ch. 14 - The nickel-cadmium battery is used in portable...Ch. 14 - The zinc-silver oxide battery, although expensive,...Ch. 14 - Balance the following half-reactions....Ch. 14 - Balance the following half-reactions....Ch. 14 - For each of the following, write balanced...Ch. 14 - For each of the following, write balanced...Ch. 14 - Prob. 49QPCh. 14 - Prob. 50QPCh. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Prob. 55QPCh. 14 - Complete and balance the following...Ch. 14 - Complete and balance the following...Ch. 14 - Complete and balance the following...Ch. 14 - Denitrification occurs when nitrogen in the soil...Ch. 14 - Prob. 60QPCh. 14 - Consider the partially labelled voltaic cell...Ch. 14 - Consider the partially labelled voltaic cell...Ch. 14 - Using the activity series in Figure 14.22, place...Ch. 14 - Using the activity series in Figure 14.22, place...Ch. 14 - What is electrolysis?Ch. 14 - Describe what happens at each electrode during the...Ch. 14 - Prob. 67QPCh. 14 - Prob. 68QPCh. 14 - Prob. 69QPCh. 14 - Prob. 70QPCh. 14 - Prob. 71QPCh. 14 - Prob. 72QPCh. 14 - Prob. 73QPCh. 14 - Prob. 74QPCh. 14 - If the chrome placing on an automobile bumper is...Ch. 14 - Prob. 76QPCh. 14 - Prob. 77QPCh. 14 - Prob. 78QPCh. 14 - Prob. 79QPCh. 14 - Prob. 80QPCh. 14 - Prob. 81QPCh. 14 - Prob. 82QPCh. 14 - Prob. 83QPCh. 14 - Prob. 84QPCh. 14 - Prob. 85QPCh. 14 - Prob. 86QPCh. 14 - Prob. 87QPCh. 14 - Prob. 88QPCh. 14 - Prob. 89QPCh. 14 - Prob. 90QPCh. 14 - Prob. 91QPCh. 14 - Prob. 92QPCh. 14 - Prob. 93QPCh. 14 - Prob. 94QPCh. 14 - Prob. 95QPCh. 14 - Prob. 96QPCh. 14 - Prob. 97QPCh. 14 - Prob. 98QPCh. 14 - Prob. 99QPCh. 14 - Prob. 100QPCh. 14 - Prob. 101QPCh. 14 - Prob. 102QPCh. 14 - Prob. 103QPCh. 14 - Prob. 104QPCh. 14 - Prob. 105QPCh. 14 - Prob. 106QPCh. 14 - Prob. 107QPCh. 14 - Prob. 108QPCh. 14 - Prob. 109QPCh. 14 - Prob. 110QP
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