INTRO TO CHEMISTRY EBK ACCESS CARD >I<
5th Edition
ISBN: 9781260916430
Author: BAUER
Publisher: MCG
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Chapter 14, Problem 25QP
Determine the oxidation number of each element in the following compounds.
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It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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Previous Answers
?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
Chapter 14 Solutions
INTRO TO CHEMISTRY EBK ACCESS CARD >I<
Ch. 14 - Prob. 1QCCh. 14 - Prob. 2QCCh. 14 - How do chemical reactions provide electricity in...Ch. 14 - Prob. 4QCCh. 14 - Prob. 5QCCh. 14 - How do oxidation-reduction reactions generate...Ch. 14 - Prob. 7QCCh. 14 - Prob. 1PPCh. 14 - Assign oxidation numbers to each element in the...Ch. 14 - Prob. 3PP
Ch. 14 - Cadmium reacts with nickel(II) nitrate according...Ch. 14 - The reaction that occurs in most camera batteries...Ch. 14 - Prob. 6PPCh. 14 - Balance the following equation that occurs in...Ch. 14 - Prob. 8PPCh. 14 - Prob. 9PPCh. 14 - Prob. 1QPCh. 14 - Prob. 2QPCh. 14 - Prob. 3QPCh. 14 - Why is oxidation always coupled with reduction?Ch. 14 - Prob. 5QPCh. 14 - How do you know when something is reduced?Ch. 14 - When a strip of magnesium metal is placed in an...Ch. 14 - When a strip of nickel metal is placed in an...Ch. 14 - Consider the following reaction:...Ch. 14 - Consider the following reaction:...Ch. 14 - Prob. 11QPCh. 14 - Prob. 12QPCh. 14 - Indicate the oxidation number of each element in...Ch. 14 - Indicate the oxidation number of each element in...Ch. 14 - Prob. 15QPCh. 14 - Prob. 16QPCh. 14 - What is the oxidation number of phosphorus in each...Ch. 14 - Determine the oxidation number of chlorine in each...Ch. 14 - Indicate the oxidation number of phosphorus in...Ch. 14 - Determine the oxidation number of iodine in each...Ch. 14 - The ion shown has a charge of 2. What are the...Ch. 14 - The ion shown has a charge of 1. What are the...Ch. 14 - Prob. 23QPCh. 14 - Indicate the oxidation number of chromium in each...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Prob. 28QPCh. 14 - Prob. 29QPCh. 14 - Prob. 30QPCh. 14 - Under certain conditions, nitrogen gas reacts with...Ch. 14 - Under certain conditions, solid carbon reacts with...Ch. 14 - Consider the following reaction:...Ch. 14 - In the following oxidation-reduction reactions,...Ch. 14 - In the following oxidation-reduction reactions,...Ch. 14 - Draw a diagram of a voltaic cell that corresponds...Ch. 14 - Draw a diagram of a voltaic cell that corresponds...Ch. 14 - The figure shows a molecular-level representation...Ch. 14 - The figure shows a molecular-level representation...Ch. 14 - The reaction that occurs in a lead-acid battery is...Ch. 14 - The reaction that occurs in a lead-acid battery is...Ch. 14 - The nickel-cadmium battery is used in portable...Ch. 14 - The zinc-silver oxide battery, although expensive,...Ch. 14 - Balance the following half-reactions....Ch. 14 - Balance the following half-reactions....Ch. 14 - For each of the following, write balanced...Ch. 14 - For each of the following, write balanced...Ch. 14 - Prob. 49QPCh. 14 - Prob. 50QPCh. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Prob. 55QPCh. 14 - Complete and balance the following...Ch. 14 - Complete and balance the following...Ch. 14 - Complete and balance the following...Ch. 14 - Denitrification occurs when nitrogen in the soil...Ch. 14 - Prob. 60QPCh. 14 - Consider the partially labelled voltaic cell...Ch. 14 - Consider the partially labelled voltaic cell...Ch. 14 - Using the activity series in Figure 14.22, place...Ch. 14 - Using the activity series in Figure 14.22, place...Ch. 14 - What is electrolysis?Ch. 14 - Describe what happens at each electrode during the...Ch. 14 - Prob. 67QPCh. 14 - Prob. 68QPCh. 14 - Prob. 69QPCh. 14 - Prob. 70QPCh. 14 - Prob. 71QPCh. 14 - Prob. 72QPCh. 14 - Prob. 73QPCh. 14 - Prob. 74QPCh. 14 - If the chrome placing on an automobile bumper is...Ch. 14 - Prob. 76QPCh. 14 - Prob. 77QPCh. 14 - Prob. 78QPCh. 14 - Prob. 79QPCh. 14 - Prob. 80QPCh. 14 - Prob. 81QPCh. 14 - Prob. 82QPCh. 14 - Prob. 83QPCh. 14 - Prob. 84QPCh. 14 - Prob. 85QPCh. 14 - Prob. 86QPCh. 14 - Prob. 87QPCh. 14 - Prob. 88QPCh. 14 - Prob. 89QPCh. 14 - Prob. 90QPCh. 14 - Prob. 91QPCh. 14 - Prob. 92QPCh. 14 - Prob. 93QPCh. 14 - Prob. 94QPCh. 14 - Prob. 95QPCh. 14 - Prob. 96QPCh. 14 - Prob. 97QPCh. 14 - Prob. 98QPCh. 14 - Prob. 99QPCh. 14 - Prob. 100QPCh. 14 - Prob. 101QPCh. 14 - Prob. 102QPCh. 14 - Prob. 103QPCh. 14 - Prob. 104QPCh. 14 - Prob. 105QPCh. 14 - Prob. 106QPCh. 14 - Prob. 107QPCh. 14 - Prob. 108QPCh. 14 - Prob. 109QPCh. 14 - Prob. 110QP
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- 5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forwardThe plutonium isotope with 144 neutrons Enter the chemical symbol of the isotope.arrow_forwardThe mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produced 26.1 gg of sodium upon decomposition. How much fluorine was formed?arrow_forward
- 32S 16 Enter your answers numerically separated by a comma. Np. Nn = 跖 ΟΙ ΑΣΦ Submit Request Answer ? protons, neutronsarrow_forward2. Which dimethylcyclohexane compounds shown below exhibit symmetry and therefore are not chiral and would not rotate plane polarized light. 1 CH3 CH CH3 CH3 2 3 CH3arrow_forwardDon't used hand raitingarrow_forward
- Can you please explain why the answer is structures 2 and 3? Please include a detailed explanation and show how the synthesis can be done with those two structures.arrow_forwardCan you please explain why the correct answer to this question is option 2? I am having trouble understanding how and why. Please provide a detailed explanation and a drawing of how the diene and dienophile would create the product in the question.arrow_forwardCan you please explain why the correct answer is molecules 2 and 4? Base your explanation off of the rules for aromaticity and well as the principles of the Huckel rule of aromaticity. Please give a detailed explanation of what Hucekl's rule is.arrow_forward
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