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The enzyme urease catalyzez the reaction of urea,( NH2CONH2), with water to produce carbon dioxide and ammonia. In water,without the enzyme, the reaction proceeds with a first-order rate constant of 4.15*10-5S-1 at 100 °C. in the presence of the enzyme in water, the reaction proceeds with a rate constant of 3.4*104 s-1 at 21 °C. (a) write out the balanced equation for the reaction catalyzed by urease. (b) if the rate of the catalyzed and uncatalyzed reactions? (c) in actuality,what would you expect for the rate of the catalyzed reaction at 100 C as compared to that at 21 °C? (d) on the basis of parts (c) and (d), what can you conclude about the difference in activation energies for the catalyzed and uncatalyzed reactions?
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Chapter 14 Solutions
Chemistry: The Central Science Plus Mastering Chemistry with Pearson eText -- Access Card Package (14th Edition)
- The rate constant for the decay of a radioactive element is 2.28 × 10⁻³ day⁻¹. What is the half-life of this element in days?arrow_forwardHandwritten pleasearrow_forwardChoose the best reagents to complete the following reaction. i H A B 1. CH3CH2Na 2. H3O+ 1. CH3CH2MgBr 2. H3O+ 1. CH3MgBr Q C 2. H3O+ 1. H3O+ D 2. CH3MgBr 00 OH Q E CH³MgBrarrow_forward
- The kinetics of a gas phase reaction of the form A → Products results in a rate constant of 0.00781 M/min. For this reaction, the initial concentration of A is 0.501 M. What is the half-life for this reaction?arrow_forwardChoose the best reagents to complete the following reaction. 1. PhNa A 2. H3O+ 1. PhCH2MgBr B 2. H3O+ хё 1. PhMgBr C 2. H3O+ 00 HO Q E D 1. H3O+ 2. PhMgBr PhMgBrarrow_forwardPlease answer all of the questions and provide detailed explanations and include a drawing to show the different signals on the molecule and include which ones should be highlighted.arrow_forward
- Draw the major product of this reaction. Ignore inorganic byproducts. Incorrect, 1 attempt remaining 1. LiAlH4 2. H3O+ Q OH ☑ Select to Drawarrow_forwardHow should I graph my data for the Absorbance of Pb and Fe for each mushroom? I want to compare the results to the known standard curve. Software: Excel Spreadsheets Link: https://mnscu-my.sharepoint.com/:x:/g/personal/vi2163ss_go_minnstate_edu/Eb2PfHdfEtBJiWh0ipHZ_kkBW4idWWwvpLPPtqoq2WkgbQ?rtime=HxrF0_tR3Ugarrow_forwardProvide the proper IUPAC name only for the following compound. Dashes, commas, and spaces must be used correctly, but do not use italics in Canvas.arrow_forward
- The kinetics of a gas phase reaction of the form A → Products results in a rate constant of 0.00781 M/min. For this reaction, the initial concentration of A is 0.501 M. How many minutes will it take for the concentration of A to reach 0.144 Marrow_forwardWhat is the rate for the second order reaction A → Products when [A] = 0.256 M? (k = 0.761 M⁻¹s⁻¹)arrow_forwardFor reaction N2(g) + O2(g) --> 2NO(g) Write the rate of the reaction in terms of change of NO.arrow_forward
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