CONCEPTUAL INTEGRATED SCI W/MOD MASTERIN
3rd Edition
ISBN: 9780135720967
Author: Yeh
Publisher: PEARSON
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Textbook Question
Chapter 14, Problem 6RAT
Alkaloids salts are not very soluble in the organic solvent diethyl ether. What might happen to
the free-base form of caffeine (an alkaloid) dissolved in diethyl ether if gaseous hydrogen chloride, HCl, were bubbled into the solution?
(a) A second layer of water would form.
(b) Nothing; the HCl gas would merely bubble out of solution.
(c) The diethyl ether-insoluble caffeine salt would form as a white pecipitate.
(d) The acid-base reaction would release heat, which would cause the diethyl ether to start evaporating.
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Chapter 14 Solutions
CONCEPTUAL INTEGRATED SCI W/MOD MASTERIN
Ch. 14 - How do two structural isomers differ from each...Ch. 14 - How do two structural isomers similar to each...Ch. 14 - What physical property of hydrocarbons is used in...Ch. 14 - What types of hydrocarbons are more abundant in...Ch. 14 - To how many atoms is a saturated carbon atom...Ch. 14 - What is the difference between a saturated...Ch. 14 - How many multiple bonds must a hydrocarbon have in...Ch. 14 - Aromatic compounds contain what kind of ring?Ch. 14 - What is a heteroatom?Ch. 14 - Why do heteroatoms make such a difference in the...
Ch. 14 - How is a heteroatom related to a functional group?Ch. 14 - Why are low-formula-mass alcohols soluble in...Ch. 14 - What distinguishes an alcohol from a phenol?Ch. 14 - What distinguishes an alcohol from an ether?Ch. 14 - Which hetroatom is characteristic of an amine?Ch. 14 - Do amines tend to be acidic, neutral, or basic?Ch. 14 - Are alkaloids found in nature?Ch. 14 - What are some examples of alkaloids?Ch. 14 - Which elements make up the carbonyl group?Ch. 14 - How are ketones and aldehydes related to each...Ch. 14 - How are amides and carboxylic acids related to...Ch. 14 - From what naturally occurring compound is aspirin...Ch. 14 - What happens to the double bond of a monomer that...Ch. 14 - What is released in the formation of a...Ch. 14 - Why is plastic wrap made of polyvinylidene...Ch. 14 - Prob. 26RCCCh. 14 - In the lock-and-key model, is a drug viewed as the...Ch. 14 - What holds a drug to its receptor site?Ch. 14 - Which fits better into the opioid receptor...Ch. 14 - How does the effect of a drug wear off?Ch. 14 - Prob. 34TCCh. 14 - Rank these hydrocarbons in order of increasing...Ch. 14 - Rank these hydrocarbons in order of increasing...Ch. 14 - Rank the organic molecules in order of increasing...Ch. 14 - Rank the organic molecules in order of increasing...Ch. 14 - Prob. 39TECh. 14 - What property of carbon allows for the formation...Ch. 14 - Prob. 41TECh. 14 - Draw all the structural isomers for hydrocarbons...Ch. 14 - How many structural isomers are shown here? .Ch. 14 - Prob. 44TECh. 14 - How many different conformation are possible for...Ch. 14 - Prob. 46TECh. 14 - The temperatures in a fractionating tower at an...Ch. 14 - There are five atoms in the methane molecule, CH4....Ch. 14 - Compared to lighter hydrocarbons, do heavier...Ch. 14 - What do these two structures have in common?Ch. 14 - With four unpaired valence electrons, how can...Ch. 14 - What do the compounds cyclopropane and propene...Ch. 14 - What are the chemical formula for the following...Ch. 14 - Remember that carbon-carbon single bonds can...Ch. 14 - Which of the structures shown in the previous...Ch. 14 - Why are there so many different organic compounds?Ch. 14 - Identify the following functional groups-amide,...Ch. 14 - What must be added to a double bond to transform...Ch. 14 - What do phenols and carboxylic acids have in...Ch. 14 - What is the difference between a ketone and an...Ch. 14 - Prob. 61TECh. 14 - What do alcohols, phenols, and ethers have in...Ch. 14 - Prob. 63TECh. 14 - What is the percent volume of water in 80- proof...Ch. 14 - One of the skin-irritating components of poison...Ch. 14 - Prob. 66TECh. 14 - Prob. 67TECh. 14 - A common inactive ingredient in products such as...Ch. 14 - A common inactive ingredient in products such as...Ch. 14 - The phosphoric acid salt of caffeine has the...Ch. 14 - Prob. 71TECh. 14 - In water, does the following molecule act as an...Ch. 14 - Prob. 73TECh. 14 - The amino acid lysine is shown here. What...Ch. 14 - Why does the carbon of the carbonyl usually have a...Ch. 14 - Prob. 76TECh. 14 - Suggest an explanation for why aspirin has a sour...Ch. 14 - Benzaldehyde is a fragrant oil. If stored in an...Ch. 14 - What products are formed upon the reaction of...Ch. 14 - The disodium salt of ethylenediaminetetraacetic...Ch. 14 - Prob. 81TECh. 14 - Which is better for you: a drug that is a natural...Ch. 14 - Naloxone is a molecule that binds to the opioid...Ch. 14 - What use might there be for Naloxone?Ch. 14 - Rank the following from least ideal to most ideal...Ch. 14 - Why are plastics generally so inexpensive?Ch. 14 - Would you expect polypropylene to be denser or...Ch. 14 - Hydrocarbons release a lot of energy when ignited....Ch. 14 - The polymer styrene-butadiene rubber SBR, shown...Ch. 14 - Citral and camphor are both 10 carbon odoriferous...Ch. 14 - Many of the natural product molecules synthesized...Ch. 14 - The solvent diethyl ether can be mixed with water...Ch. 14 - Alkaloid salts are not very soluble in the organic...Ch. 14 - Go online and look up the total synthesis of the...Ch. 14 - Medicines, such as pain relievers and...Ch. 14 - Why does the melting point of hydrocarbons get...Ch. 14 - Prob. 2RATCh. 14 - Which contains more hydrogen atoms a five-carbon...Ch. 14 - Prob. 4RATCh. 14 - Why might a high-formula-mass alcohol be insoluble...Ch. 14 - Alkaloids salts are not very soluble in the...Ch. 14 - Explain why caprylic acid, CH3(CH2)6COOH,...Ch. 14 - How many oxygen atoms are bonded to the carbon of...Ch. 14 - Prob. 9RATCh. 14 - Prob. 10RAT
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